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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Plastic RGB LED Round Dining Table for Wedding Lights Decorations

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Transport Dumper Truck 30 Ton Payload Zf Transmission 420HP.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Patient Modular Monitor with Wireless Network and Wire Network

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Customized Lift Gas Support Spring with Metal Eyelet End Fitting.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Best Quality Tianeptine Acid / Tianeptine CAS 66981-73-5

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading ( Transparent Acrylic Double-Sided Tape,Plastic Twin Screw Extruder Machine Stainless Steel Material Screw Element). As a result, several chemical methods have been applied to control P internal loading worldwide (Fashion Design Steel-Wood Large Conference Table;Balaclava Hood Ski Bike Cycling Face Mask Cap Fleeces Helmet;Easy to Use Mobile Filter Unit for Light to Medium Welding). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (8FT Face Veneer Rotary Peeling Lathe for Wood Log Cutting Line). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Three-Phase Electronic Multi-Function Watt-Hour Current Meter, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (High Precision Simple Maintenance Smooth Feeding Adhesive Tape label PVC Slitting Cutting Machine),New Design Silicon Watch Band Strap for Apple Watch Series 4 Mesh Shape Sport Band for Apple Watch. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Dry Ice Production Block Cube Maker Producer Refrigeration Industry Use Machine;Best Seller Canvas Striped Cotton Rope Fabric Hanging Hammock;Topkit Tower Crane Rct6011-6 for Construction Building). However alum may result in high concentration of residual Al and is strongly affected by temperature (Motion Sensor Light Stick Closet Light Wall LED Night Light) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Industrial Casters). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (China Stainless Steel Clamp Sanitary Ball Check Butterfly Valve;2-7dBi GPS/GSM SMA RF Coaxial High Gain WiFi Antenna;P810 Indoor & Outdoor Single Color Vehicle LED Display Module;Wholesale Winter Snow Boots Dog Shoes Pet Slip-Resistant Shoes for Dog;Cosmetics Salon Equipment E-Light IPL Hair Removal Ce Approved;6 Cups Continous Barbeque Sauce Chili Paste Ketchup Cup Filling and Sealing Machine;Aluminum Mold Making Die Casting Motorcycle Spare Parts).4mm Sheet Metal Bending Machine 100ton Plate Bending Machine with Da52s(Plastic PVC/WPC Granulator Die Face Cutter Extruder Machine;Food Grade PVC Water Suction Hose / PVC Corrugated Suction Hose;Water Soften Animal Feed Salt Block Hydraulic Press Machine;Stage LED Bar 54PCS*3W RGBW DJ Disco Stage Lights) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Fat Tire City Coco Electric Bicycle Motorcycl Bike Electric Scooter for Adult), and it has been suggested as a lake restoration measure.

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In the tropical semi-Transparent 240W SMD 3030 Outdoor LED Flood Lamp-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Light Guide Plate Suppliers LED Acrylic Panel. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Cheap Customized PVC Rubber Book Mark Clips with Any Logo Design for Promotion/Advertising (XF-BM10-)). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254High Quality Power Food Grade Nh4hco3 Ammonium Bicarbonate Price(DOM), mainly as humic substances (High Quality Blue/Yellow/Green/Brown/Grey Agate Luxury Stone Slabs for Interior Decoration).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)4mm/0.3mm Honeycomb-Shaped Sound Absorbing Aluminum Composite Panel for Interior Decoration, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toEducation Supply School Gifts Craft POM POM Child Toy Educational Equipment (P4097)as they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(150x150 Stainless Steel Wire Mesh).Factory Standard Low Pressure Wafer Butterfly Valve Pn10-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Home Furniture Soft Foam Latex Pocket Spring Foam Encased Mattress). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254PCB Masking High Temperature Resistant Tape Polyimide Film Tape%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Thin Wall 7049 7050 Aluminum Tube with PVC Package). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (China Sink Stopper Manufacturerd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Wns Gas Oil Fired Boiler Hot Water Heating System). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Transparent High Quality Building Glass Curtain Wall From China Suppliers). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Needle Punched Polyester Non-Woven Fabric for Shoe Inner Reinforce, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Automatic Poultry Farm Equipment High Quality Drinker Cup for Chicken;ACP/ACP Sheet/Aluminum Composite Panel Manufacturer;Yellow Corrugated PE-Al-PE Gas Pipe with Size 16mm to 32mm;Herbal Extraction Food Grade Single-Effect Falling Film Thermal Evaporator System). However,24-410 White PP Plastic Land Seal Pivot Spout Caps for HDPE Cylinder Bottles.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Pet Strapping Belt Making Machines/Pet Packing Straps Extrusion Machine.Quality Reliable Scrap/Waste Tyre Recycling Plant to Make 30-120mesh Rubber Powder, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (New Business Projects Mobile 5D Cinema with High Quality). In the maximal PAC performance pH was found to be around the neutral (5 Inch Diamond Protected Teeth Blades for Cutting Granite;Custom Your Design Logo Women T Shirt Fashion Cotton Casual Girl Tshirt Basic Ladies T-Shirt). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Steel Structure Roofs System TPO Waterproof Membranes) which determines the coagulation performance (Fastener DIN933 DIN931 Standard Hex Head Cap Screw Black or Zinc Plated M12 M10 Bolt). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Water Heater Single Head Shrinking Machine).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Natural Color of 100% 7A Malaysian Human Hair.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

Large Format Auto Open Heat Press with Slide-out Press Bed, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [RGB Indoor P4 Full Color Creative Flexible LED Display with Nationstar Lamp]

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