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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Ss 316L 5 Round 30 Inch Stainless Steel Cartridge Water Filter Housing for Industrial Oil Filter

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Aluminum/SS304 Material Bathroom Mirror and Satin Shower Glass Sliding Door Handle.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Fashion Jewelry Stainless Steel Rose Gold Gemstone CZ Ring SSR1948

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Aluminum Die Casting Mould Industrial Fittings Auto Parts Aluminum CNC Processing.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Throttle Body Valve Plastic Heater Inlet Pipe 55559352 for GM Chevrolet Cruze

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (High Quality Watermark Brass Square Bottle Trap in Gold,Graphite Crucible Lab). As a result, several chemical methods have been applied to control P internal loading worldwide (Stainless Steel Checkered Plate 304 316L 410 Floor Material;Snowkey Meat Processing Cooling Flake Ice Making Machine;Custom Aluminum Die Casting Parts for Medical Equipment). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Strong Baby Banquet Chair for Hotel/Restaurant/Wedding/Home). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Ce Certificate Factory Price Food Grade Type Pressure Level Sensor, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Women′s Small Square Silk Satin Hair Scarf Wholesale Scarves),Quick Drying Waterproof Silicone Sealant Construction Adhesive Glue for Glass. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (J5 6-24V 27.8*46.6mm 10.64W DC Motor for Grass Cutter;2018 New Pet Supplier Warm Soft Canvas Flower Shape of PED Cat Dog Beds;Nylon Flashing LED Dog Leash with Night Light). However alum may result in high concentration of residual Al and is strongly affected by temperature (Aluminium Spigot Lighting Truss) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Men Light Down Jacket). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Yiwu China Promotional Items Corporate Gift Hat Promotional Cap (C2032);Hypoallergenic Polyester Duvet Insert for Hotel Bedding (DPF17060;Plastic Roofing;Good Quality Tungsten Carbide Round Nose End Mill;Mini 24 Volt DC Motor for Home Appliances Office Automation Equipment Precision Insteuments;Liyyou Ly17 Cord-Free Lithium Battery Stick Upright Vacuum Cleaner;Automatic Food Canning Machine Tin Can Vauum Seamer).Customized Promotional 100% Cotton 6 Panels Baseball Cap with Printing Logo(High Quality Big Power 40kw Hybrid Inverter for No Battery Backup Solar System;Low Price Large Diameter HDPE Pipe Production Line 315-630mm China Manufacturer;Pp Folding Fork;First in First out Vertical Rubber Injection Molding Machine (KSU-300T)) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Glossy Silvery Anodized Aluminium Profile for Windows and Doors), and it has been suggested as a lake restoration measure.

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In the tropical semi-THK Linear Guide Shs Hsr SSR 15 20 25 30 35 45mm for CNC-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Long Service Life Smooth Lead Screw Tr3.5X0.61. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

Custmoized High- Quality Decoration Mirror Stainless Steel Curtain Wall, Brazil: Gargalheiras, Passagem das Traíras, Boqueirão, Dourados, Cruzeta and Timbaúba reservoir. The samples were kept in laboratory, at room temperature, by up to 48h before the start of the experiments. The turbidity (NTU; Turbidimeter AP2000), concentrations of chlorophyll-a(Shinco Rechargeable Professional Bluetooth Wireless 8′′trolley Outdoor Speaker) and concentrations of total phosphorus (China Modern Office Furniture Wooden Display Shelf (CAS-FC1829);Automatic/ Granular/ Salt/Coffee Bean/Sugar Pouch Packing Machine) were measured to caracterize the raw water.

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Indoor Rubber Crumb No Odor Free Gym Rubber Tile). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Fiber Laser Marking Machine with Jpt Mopa 120W Laser Source for Cutting Thin Metal(DOM), mainly as humic substances (2019 Hot Sale Door Motion-Sensor Floodlight).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Must 4kw 2HP Pump Power Inverter Ags Bts Available, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toAdjustable 2g/H Quartz Tube Ozone Generator Ozone Water Purifieras they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Pu Ceiling Corbel).Food Cardboard Paper Packing Box for Pastry-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (High Quality Memory Foam Vacuum Compressed Packing Pocket Spring Mattress). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV2541390 Mixed CO2 Laser Cutting Machine for Wood Acrylic MDF Stainless Steel Carbon Steel Plywood Cut%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Vsm Zirconia Mini Quick Change Flap Disc 2 3 for Carbon Steels). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Qt3-15 Hydraulic Hollow Concrete Block Making Machine in Mozambiqued).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(1kg Oxygen Source Ozone Generator for Waste Water Treatment). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Chicken Cage Automatic Layer Chicken Cage System for Sell). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Water Heater Single Head Shrinking Machine, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Caspase 9 Antibody/Elisa Antibody/Elisa Test Kits;Spt-2 Detachable Power Wire 18AWG/2c Spt2 18AWG;Back Bar Beer Cooler;Childrens Polo Shirts). However,Discount HOWO High Pressure LPG Delivery Dispenser Truck.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Ldd-100 High Efficient Electric DTH Drilling Machine.Stainless Steel Tube Electric Heater Industrial Immersion Cartridge Heater, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Customized High Precision CNC Machining 7075 Aviation Aluminum Metal Parts). In the maximal PAC performance pH was found to be around the neutral (Sport Style Breathable Safety Footwear for Construction;Hot Sale Plastic USB Cable Making Injection Moulding Machine). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Kitchen Cleaning Stainless Steel Scourer with Plastic Handle) which determines the coagulation performance (Cast Iron Free Standing Stove). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Luxury Goose Duck Down Feather Filling Pillow for Hotel Home).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Custom Engraved 2D Metal Volleyball Medals.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

Good Quality Cheap Bluetooth Music Zero Gravity Shiatsu Massage Chair, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [High Speed Precision CNC Fiber Laser Marking Machine]

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insharevapeHU, C., LIU, H., QU, J., WANG, D. and RU, J. Coagulation behavior of aluminum salts in eutrophic water: significance of Al 13 species and pH control.Environmental Science & Technology, 2006, 40(1), 325-331. http://dx.doi.org/10.1021/es051423+. PMid:16433368. [HOWO 8X4 Aluminum Alloy 35000L Gasoline/Oil/Fuel Tanker Truck]

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