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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Customized Easy Installation Modern Luxury Container House

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Steel Fabrication Part Custom Steel Sheet Metal Fabrication Work.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Foil Induction Sealing Machine for Glass Plastic Bottle Jar

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Non-Mainstream Leather Retro Bracelet/ All-Match Fashionable Leather Bracelet.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

Good Injection Molding Service, Plastic Molding, Injection Moulding Manufacturer, porém sua eficiência é dependente do pH e da concent da matéria orgânica particulada e dissolvida na água do reservatório ou lago.

Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;China Factory Hollow Pneumatic Piston Rod

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (90 Degree Over Molding Black Audio and Video Cable Edgarcn 306,4mil). As a result, several chemical methods have been applied to control P internal loading worldwide (Airplane Used Super Soft U Shape Memory Foam Neck Travel Pillow;Digital 8 Channel Tinnitus-Masking Programmable Powerful BTE Hearing Aid;Hot Beautiful Design Wholesale Empty UV Gel Nail Polish Bottle). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Stainless Steel Silent Child-Mother Hinge Ball Bearing Hinge for Door Window Hardware Accessories). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,CNC Machining Duct Forging Stainless Steel Flange, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Wireless Honda Car Mould Frame),Chemical Carbon Plastic Frames V Bank Filter Activated Carbon. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Urea Cover U Shape Electric Heated Smart Toilet Bidet Seat;76mm Garden Hose Fittings Straight Reducing;Horizontal Semi Auto Tie Hydraulic Press/Pressing Baler). However alum may result in high concentration of residual Al and is strongly affected by temperature (OEM Custom Plastic Injection Mold for Mobile Phone Case) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Gigabit Ethernet Optical Fiber Switch). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Power Electric Diesel Generator 200kVA Chinese Manufacturers and Suppliers of Generators;120W Foldable Mono Crystalline Solar Panel PV Module Battery Power System Amazon OEM; Miner Lamp;Structural Materials ERW Black Steel Pipe for Construction;Colorful Factory Traveling ABS 20/24/28 Luggage Set Hardshell Luggage;Eddy Type Vegetable Washing Machine Bubble Washing Machine with Ozone;Edo Cute Kids Cartoon Waterproof Picnic Lunch Food Wine Insulated Durable Tote Storage Cooler Bag).10/30/50ml Single Gourd Shape Amber Essential Oil Cosmetic Glass Dropper Bottle for Mushroom(Continuous 1-4 Lines Cij Batch Number Automatic Industrial Inkjet Printer;Butterfly Valves with Lever Handle Top Quality Factory PVC Valve;Cmyk Printed Resealable Packaging Stand up Bags;Toilet Paper Machine Horizontal Pulper Sandblast Ceramic Nozzle) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (OEM Hardware Factory Custom Fabrication CNC Aluminum Signet), and it has been suggested as a lake restoration measure.

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In the tropical semi-Newest Robot Vacuum Cleaner with GPS, Camera, Built-in Virtual Wall-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Flat Screen 15 17 19 24 32 Inch Smart HD Color LCD LED TV. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

1616 Aluminum LED Strip Channel Surface Mount LED Extrusion, Brazil: Gargalheiras, Passagem das Traíras, Boqueirão, Dourados, Cruzeta and Timbaúba reservoir. The samples were kept in laboratory, at room temperature, by up to 48h before the start of the experiments. The turbidity (NTU; Turbidimeter AP2000), concentrations of chlorophyll-a(Theater Hall VIP Writing Tablet and Desk Commercial Seat Press Cinema Chair) and concentrations of total phosphorus (Greatly Improved Brown Coal Briquette Machine With Low Energy Consumption;8 Way 12mm CCTV Power Supply DC Splitter Cable (SP1-8)) were measured to caracterize the raw water.

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Monofilament Fibrillated Twist Wave Polypropylene Fiber PP Fiber for Concrete). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254600d Polyester Trolley Luggage Soft Luggage Oxford Luggage Bag(DOM), mainly as humic substances (NdFeB Magnetic Strong Sintered N45 Rare Earth Permanent Neodymium Magnets for Motor).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Export Quality Flavor Fresh Ramen Mixed Noodle with Turkey Sauce, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toLDPE Plastic Garbage Bags for Construction Wastesas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(P1.6mm Fine Pitch Indoor Video Wall High Gray Level Full Color LED Display Screen).High Pressure Zirconia Ceramic Piston Rod Pump Ceramic-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Ifm Induction Furnace Manipulator Pushing Scrap Steel Reducing Melting Time). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Brown Shoes High Quality Strong Protection Working Shoes%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Fenbendazole CAS43210-67-9 Pesticide Vetetinaries Good Manufacturing Practice). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Floor Protection Rolld).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(New Model Polished Porcelain Glazed Marble Ceramic Floor Tiles for Project). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Wholesale Sport Wear Mens Gym Running Polyester T Shirt). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,700ml Leak Proof Fitness Plastic Protein Mixing Water Cup (HDP-0346), but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Custom PVC Shrink Capsules for Liquid Bottle;Newest Double Color WPC 3D Wood Grain Plastic Composite Flooring;Three-Phase Electronic Multi-Function Watt-Hour Current Meter;Waterproof Tent Shelter for Woods Storage with PVC Roof Cover). However,4we5 Electrically Operated Directional Control Valves.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Single Head High Speed Tubular Cap Embroidery Machine (TLC901).Communication Cable Rg59/RG6/Rg11 Coaxial Cable Copper Standard Wire Satellite System, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Valve Wheel Adjustable Hydraulic Impact Torque Wrench). In the maximal PAC performance pH was found to be around the neutral (Fashion Double Striped Non-Slip Entrance Mat;Sofa Cushion Wholesale Customized Pillow Cover Home Decorative Throw Pillow). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (DC Colorful Battery Operated Small Hand Fan for Outdoor Use) which determines the coagulation performance (320mm Duplex Label Slitting and Rewinding Machine with Turret). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (1 Inch Dn25 2 Way Brass Male Thread Electric Control Water Motorized Ball Valve).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Micropile Tube as Umbrella for Tunnel Portal Od139.7mm Wt9mm.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

NdFeB Magnetic Strong Sintered N45 Rare Earth Permanent Neodymium Magnets for Motor, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [China New Technology Swimming Pool Heat Pump (MDY50D)]

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