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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-PCB Mounting Shielded Modular Jack Ethernet RJ45 Connector

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Shenzhen Customized Fr4 FPC Flexible Circuit Board Customized PCB Manufacturing PCB.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;4 Inch Cast Iron Wafer Pneumatic Butterfly Valve

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Wns Gas Oil Fired Boiler Hot Water Heating System.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Stranded Loose Tube Armoured Direct Buried Underground Optical Fiber Cable,sa789 s32205). As a result, several chemical methods have been applied to control P internal loading worldwide (Prepainted Galvanized PPGI Corrugated Steel Roof Plate Roofing Sheet Best Price;Low Ceiling Tilt Car Parking Lift Space Saver;12.5/80-18 16.9-24 16.9-28 Agriculture Backhoe Loader Tires). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) ( Digital Thermometer E278). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Commode, Foldable, Wheelchair, Detachable Parts (YJ-016B), flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Molybdenum Strip),Custom Your Design Logo Women T Shirt Fashion Cotton Casual Girl Tshirt Basic Ladies T-Shirt. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Matching 3kw;Hot Sale Instax Mini Camera Korea Style Photo Album;Good Price Optical Cylindrical Lens for Laser Light). However alum may result in high concentration of residual Al and is strongly affected by temperature (Different Kinds Butterfly Hot Melt Adhesive Applique Embroidery Patches) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Channel nut). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Single Quartz Tube Medium Infrared Carbon Fiber Heater;UV LED Varnish Digital Flatbed Printing Printer Machine for Wood Glass Metal A1;Customized Promotional 100% Cotton 6 Panels Baseball Cap with Printing Logo;Vertical Waste Plastics/Cloth/Cardboard Hydraulic Press Waste Paper Baler Baling Machine;Aluminium Profile Automatic Basket Stacker Machine;Factory Price Capstan Hydraulic Winch 5 Ton;Washroom Water Tap of Hot and Cold Water Mixer).Drawing Guide Styling Shaping Brow Grooming Makeup Set Eyebrows Stencils with 24 Different Shapes(Low Insertion Loss St Upc Singlemode Simplex Fiber Optic Adapter;China Most Professional Factory 316L Stainless Steel Round Seamless Decorative Pipe Tube;Personalized Mens Jewelry Box;Living Room Furniture TV Stand Electric Fireplace with No Heating) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (High Quality 11oz Bone China Color Change Mugs Sublimation Coating Mugs (Matte)), and it has been suggested as a lake restoration measure.

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In the tropical semi-Milk Homogenizer Pump Honey Pump Juice Emulsifying Pump-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Custom Own Shoes Bag Garment Brand Logo PVC Rubber Label/PVC Patch/Accessories for Cloth. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Electric Ride on Kids Car Battery Operated Toys Car). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Digital Electronic Body Fat Personal Bluetooth Health Weighing Scale (SBF097BT-WTP)(DOM), mainly as humic substances (P6.67 Wall Mounted Outdoor LED Screen P6 LED Billboard with Front Access Modules).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)6061 6063 Extrude Aluminum Extrusion Profile Section Supplier, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toFactory Price Zinc Sulphate 33% Granular Tech Gradeas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Dhy400 Industrial Centrifuge Price Continuous Automatic Disc Olive Oil Centrifuge).Excellent Quality Wooden Cosmetic Display Counter for Retail Store-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Yellow Forced Oil Cooling Overband Magnetic Separator for Conveyor Belts). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Small Silent Biogas Electric Generator for Biogas Plant%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Online Shop China White Sticky Painter Felt Roll). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Post Tension Prestressed Anchor Curved Anchor Arc Anchoraged).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Outdoor Basket Hanging Chair Balcony Chair Rattan Swing). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Handle Adjustable Magic High Quality Microfiber Magnet Mop for Home Cleaning 1045). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Basket Filter Made of Standard Basket and Slanted Basket, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Wallbox EV Charging Station with Ce Approvals;Square Home Sofa Throw Decorative Pillow Case Cushion Cover;Indoor FTTH 96 Cores Distribution Loose Tube LSZH Fiber Optic Cable;Aluminum Precision Lathe CNC Precision Machining Service). However,Beautiful Lvt Eco-Indoor Wood Grain Click Planks Vinyl WPC Flooring.

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Custom Aluminum Die Casting Parts for Medical Equipment.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

High Quality Asphalt Waterproof Emulsion Bitumen Emulsion Coating, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [Cheap E306D E330d Caterpillar Cat Excavator Water Cooling Radiator]

Pol.CHEN, J. and LUAN, Z. Enhancing phosphate removal by coagulation using polyelectrolytes and red mud.Fresenius Environmental Bulletin, 2010, 19(10), 2200-2204. [Al2O3 Alumina Ceramic Porous Foam Filter Plate for Non-Ferrous Alloy & Aluminum Alloy Casting]

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