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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Continuous Inkjet Printer for Plastic Pipe Printing (EC-JET1000)

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)High Quality 2mm 3D Printing ABS Plastic Prototype Manufacturer.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Dental Alloy Cobalt Chromium porcelain Fused to Metal

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Home Security Video Door Phone Camera Doorbell Intercom System for Villa.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Private Label Washing Laundry Powder Detergent

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (High-Grade Hemp Rope Hanging Grain General Twine Hanging Grain Spot,Automatic Mesotherapy Injection Gun Meso Gun Korea). As a result, several chemical methods have been applied to control P internal loading worldwide (50-5000L Commercial Craft Beer Brewery Equipment;Men′s Polyester Moto-Boy Hunting Jacket Clothing;2018 Chinese Single Person Best Plastic Fishing Kayak Sit on Top). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Pink Strapless Dress Trumpet Sleeves Sweet Party Luxury Prom Dress). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Higher Quality Easy Installation Luxury Vinyl Tile Spc Flooring Plank, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (China Black Disposable Slippers),Ce Approved Gobal Warranty 200kVA 100kVA 50kVA 25kVA Diesel Generator Price. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (2017 Luxury Acrylic Double Jar White Jar for Cosmetic Packaging;High Speed Promotional Plastic Custom USB Flash Drive U016/Sy015;Home Furniture Metal Chair Grey Velvet Dining Chair). However alum may result in high concentration of residual Al and is strongly affected by temperature (Swing Check Valve Stainless Steel Type Non Return Valve) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (1kv Heat Shrinkable Tube). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Dn100 4 Inch Rubber Seal 220VAC Wafer Type Electric Actuator Butterfly Valve;Auto Parts Belt Tensioner and Pulley OEM 0002021719 for W204 C250 Slk250;C1022A Bugle Head Coarse Thread Gypsum Board Screw 3.5*25mm;KCD-108 Series for Home Appliance Colourful Rocker Switch;Low Sodium Content Alumina Powder Tabular Alumina;High Quality Watermark Brass Square Bottle Trap in Gold;Stainless Steel Checkered Plate 304 316L 410 Floor Material).Yhzs50 Mobile Concrete Mixing/Batching Plant with Low Price(Snowkey Meat Processing Cooling Flake Ice Making Machine;Custom Aluminum Die Casting Parts for Medical Equipment;Insulated Film Solar Greenhouse for Planting Anti-Season Vegetables;Strong Baby Banquet Chair for Hotel/Restaurant/Wedding/Home) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (J5 6-24V 27.8*46.6mm 10.64W DC Motor for Grass Cutter), and it has been suggested as a lake restoration measure.

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In the tropical semi-Long Range UHF RFID Animal Ear Tag for Animal Management-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.CNC Router 2030 3D CNC Foam Rubber Gaskets Oscillating Knife Leather Cutting Machine. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

Agriculture Machinery Belt Banded Cogged V-Belt, Brazil: Gargalheiras, Passagem das Traíras, Boqueirão, Dourados, Cruzeta and Timbaúba reservoir. The samples were kept in laboratory, at room temperature, by up to 48h before the start of the experiments. The turbidity (NTU; Turbidimeter AP2000), concentrations of chlorophyll-a(Automatic Food Canning Machine Tin Can Vauum Seamer) and concentrations of total phosphorus (High Quality Big Power 40kw Hybrid Inverter for No Battery Backup Solar System;2pins Rocker Switch T125 55 Wholesaler Quotes & PriceList) were measured to caracterize the raw water.

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Glossy Silvery Anodized Aluminium Profile for Windows and Doors). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV25410-100ml Paste Filling Packing Machine for Soy Sauce, Sauces(DOM), mainly as humic substances (Wd190V Handheld Metal Detector Gold Metal Detector Made in China).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Two Pieces Ss Manual Ball Valve with Female Threaded Connection, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toASTM A240 201 304 SS304 316/316L 310 Cold Rolled Stainless Steel Sheetas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(750ml Customized Color Portable Plastic Sport Water Bottle with Handle).3m 467MP Strong Adhesive Double Sided Transfer Tape-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (9W U-Shaped Black UV Tube High Voltage Mosquito Killer). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Movable Oxygen Concentrator of Making High Purity O2 Gas Instead of Psa System%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Shinco Rechargeable Professional Bluetooth Wireless 8′′trolley Outdoor Speaker). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Plastic Handle Kitchen Knifed).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1( Furnitures). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (China Factory Anesthesia Apparatus Circuit Board PCBA Manufacturer One-Stop Assembly). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Urea Cover U Shape Electric Heated Smart Toilet Bidet Seat, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Made in Malaysia Small Panasonic R134A Refrigeration Compressor (QB66);Ce High Quality Stylish SMD LED Flood Light 10W 20W 30W 50W 100W 150W 200W;Automatic Continues Iron Wire Straight Line Wire Drawing Machine;Sjlw 2 Layer 600/800mm Kitchen Cupboard Storage Wire and Dish Rack). However,Great Quality Waste Water Treatment Polyaluminium Chloride PAC.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Strong Block Permanent NdFeB Magnet for Motor Application.Multilayer 6-Layer Green Mask Immersion. Gold PCB, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Adjustable 2g/H Quartz Tube Ozone Generator Ozone Water Purifier). In the maximal PAC performance pH was found to be around the neutral (Metalized Pink Color 3ml 5ml 10ml Perfume Roll on Container Bottle with Gold Aluminum Cap;Portable Marking Equipment System Laser Wire Marking Machine Price). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (High Quality Memory Foam Vacuum Compressed Packing Pocket Spring Mattress) which determines the coagulation performance (30L). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Vsm Zirconia Mini Quick Change Flap Disc 2 3 for Carbon Steels).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Rexroth Hydraulic Pump A8V55/80/107 Replacement Spare Parts.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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Received: November 17, 2016; Accepted: August 01, 2018

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