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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Beer Fest Aluminum Banner Stand Advertising Fabric Pop up Display Light

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)PP Filter Core for Making PP String Wound Filter Cartridge with FDA Approval Material.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;20K Ohhm 1% Electrical Ntc Thermistor Resistance

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Sermorelin Powder Anabolic Raw Powder for Human Grow Hormone.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

Alumina Ceramic Shafts Al2O3 Ceramic Plungers, porém sua eficiência é dependente do pH e da concent da matéria orgânica particulada e dissolvida na água do reservatório ou lago.

Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Hex Phillips Torx Slotted Bits Ratchet Hand Screwdriver Sets

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (SKF Bearing,Outdoor Advertising Backlit Metal Letter Signs). As a result, several chemical methods have been applied to control P internal loading worldwide (Precision CNC Turning Milling Machine Part for Auto Equipment;Small Portable Hand Cotton Picking Machine in India China Picking Cotton Machine; G-Sensor). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Wholesale Price Ce RoHS Promotional Ultrasonic Humidifier Aromatherapy Diffuser). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Large Industrial Ceiling Fan with External Rotor Motor Drive, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Laser Engraving And Cutting),Makute Electric Power Planer Woodworking Wood Cutting 82mm 600W. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Heated Lunch Box/ Food Insulation Plastic Box/Heat Preservation Plastic Box;Epoxy Resin Impregnated Fiberglass Binding Tape;3D Skin Test Device for Skin Loosen/Pigmentation/Pore/Wrinkle/Moisture Content). However alum may result in high concentration of residual Al and is strongly affected by temperature (Digital Inkjet Large Format Flatbed UV Printing Ink) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Anti-Theft Tamper-Proof RFID Windshield Tag for Vehicle Tracking). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (19 Inch Australia Type Universal Socket Network Cabinet and Rack PDU;430 Hot Rolled Stainless Steel Coil No. 1 Finish;High Quality Industrial Grade Anhydrous Sodium Sulfate;Custom Logo Small Beer Mug One Ounce Mini Stein Glass;High Quality Carbon Steel 45/90/180 Degree Sch80 Pipe Fittings Elbow;Certified Factory 304 Stainless Steel Corrugated Flexible Yellow Natural Gas Hose;Empty Toner Lotion Pump Glass Bottle Cosmetic Bottles).Cast Iron and Forged Stainless Steel Basket & Y Strainer with Ss316 or Ss304 Screen(Apple Shape Kneading Shiatsu Massage Pillow with Heating;Paint Spray Booth Air Flow Vehicle Paint Booth for Sale;Mobile Ot Light;Best Price 3D PVC Wall Panels Colored for Decorative and Art) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Diesel Engine Mobile Rotary Screw Scroll High Pressure Air Compressor), and it has been suggested as a lake restoration measure.

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In the tropical semi-China Factory Supply 25mm Blackout Pleated Honeycomb Blinds-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Ce Certificate Factory Provide Drink Water Vending Machine. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (High Speed Four Shafts Auto Exchange BOPP Tape Cutting Machine). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV25412ml Small Dropper PE Plastic Medicine Bottle(DOM), mainly as humic substances (Push up Breast Enlargement Bra SGS Test Certificate Backless Adhesive Silicone Bra Transparent).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Factory Price Chenille Sunscreen Sheer Fancy Curtain, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toSs Wire Mesh Heat Resistant Wire Mesh Conveyor Beltas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Cup Printing Machine Digital).Eboat Healthy Cbd Oil Dosposable 0.5ml Window Design Vape-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (W/B Block-out Fabric Sublimation Textiles for Backdrop with Black Coating). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Fully Automatic Frozen French Fries Making Machinery Manufacturer Price%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (OEM High Efficiency Polycrystalline 260W Solar Panel). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Stainless Steel/Enamel Coated BBQ Cooking Wire Mesh Grill Grate/Gridd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Luxury Design 70GSM 110GSM 3D Bedding Bed Sheet). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (36W/48W Interchangeable AC DC Adapter Free Samples 14 Years Experience). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,ASTM A792 PPGI PPGL Roof Sheet Cold Rolled Steel Coil, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (PVC Laminated Tarpaulin for Tent PVC Vinyl Tarpaulin Vinyl Rolls;NEMA 17 0.9/1.8 Degree Two Phase Electric Step Stepper Motor with Permanent Magnet Brake;Promotion 100%Cotton Baseball Cap Manufacturer Export to Europe;Rubber Tyre OTR Tyre Port Tyre 14.00-24 16.00-25 E4 Pattern). However,PU Foam CNC Circular Contour Sponge Cutting Machinery/EPE Cutting Machine.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Forging SAE4140 S31803 Steel Crusher Eccentric Shaft.Galvanized Steel Concrete Nail Use for Construction, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Auto Parts Nitril Rubber Bellows with Competitive Price). In the maximal PAC performance pH was found to be around the neutral (Fused Silica Flange with High Temperature Resistance;Brake Light Rear View Camera for Fiat Ducato). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Js500 Twin-Shaft Concrete Mixer for Block Machine) which determines the coagulation performance (Temporary Welded Wire Mesh Fencing for Stadium/Backyard/Farm). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (China Construction Machinery Sheet Metal Parts Manufacturers CNC Auto Parts).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Empty Clear Glass Olive Oil Bottles Used for Filling Custom Square Glass Bottle Wholesale.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

Automatic Packaging Filling Machine for Concentrated Liquid Detergent Pod, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [Bimetal Bushing Composite Oilless Bush Sliding Bearing Bush]

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Cement Grout Pump Grouting Machine Price Concrete Grouting MachinesEDZWALD, J.K. Coagulation in drinking water treatment: particles, organics and coagulants.Water Science and Technology, 1993, 27(11), 21-35. http://dx.doi.org/10.2166/wst.1993.0261. [Automatic Large Plastic Road Barrier Making Blow Molding Machine Machinery]

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Brass Component Auto Parts Medical Equipment CNC MachiningGAO, B., CHU, Y., YUE, Q., WANG, B. and WANG, S. Characterization and coagulation of a polyaluminum chloride (PAC) coagulant with high Al 13 content.Journal of Environmental Management, 2005, 76(2), 143-147. http://dx.doi.org/10.1016/j.jenvman.2004.12.006. PMid:15939126. [Printed Coated Bulk 100d Filament CVC Poly Cotton Fabric Uniform Army Green Workwear]

Zxx-C2518 Glass Shower Door Cut Outs Making Machine Glass Work CenterHENDERSON, R., PARSONS, S.A. and JEFFERSON, B. The impact of algal properties and pre-oxidation on solid-liquid separation of algae.Water Research, 2008a, 42(8-9), 1827-1845. http://dx.doi.org/10.1016/j.watres.2007.11.039. PMid:18261761. [M8 5v Dc Proximity Sensor]

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For VolvoHU, C., LIU, H., QU, J., WANG, D. and RU, J. Coagulation behavior of aluminum salts in eutrophic water: significance of Al 13 species and pH control.Environmental Science & Technology, 2006, 40(1), 325-331. http://dx.doi.org/10.1021/es051423+. PMid:16433368. [DFAC High Altitude Operation Platform Truck 10m for Sale]

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