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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-New Type Portable 380V Electric Winch in Stock

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)High-Top Men′s Casual Sports Shoes Athletic Shoes Sneaker Shoes (FFXXY1228-1).

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Taizhou Huangyan Laboratory Room 60 mm Plastic Injection Petri Dish Mould

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Ce Certificated Acm-60 PTFE Powder Grinding Mill.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Original Germany Bitzer Brand Compressor 4hc-1.2y

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Anti-Slip Bath Slipper Folding Travel Slippers Slippers Disposable,Red Agate). As a result, several chemical methods have been applied to control P internal loading worldwide (Masturbators Adult Sex Toys Japanese Love Doll;Top Quality Poultry and Livestock Automatic Manure/Organic Fertilizer Composting System;Chinese High Quality Plastic Spice Jars for Vinegar and Sugar Jam Organizer). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Reinforced Stainless Steel 306L Wire Wrap Johnson Type Strainer Screen). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Prefab Prefabricated Lightweight Steel Structure Construction Processing Plant Metal Workshop, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Bemo Roof Standing Seam Roof Panel Roll Forming Machine/Standing Seam Roofing Sheet Machine),Customized CNC Machining Checking Fixture for Automotive Bracket. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (172X150X38mm Axial Ventilation Cooling Fan for Electric Cabinet (TXA38S-172);4 Drawer Steel Office Vertical Filing Cabinet;Colorful Electric Bike Folded E Bike Foldable Scooter Motorcycle Folding Frame All Ai Alloy). However alum may result in high concentration of residual Al and is strongly affected by temperature (CO2 Gas Shielded Stainless Steel Welding Wire (ER308L)) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Oscillating Vibrating Knife Leather Cutting Machine for Genuine Natural or Artificial PU Leather). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Recyclable Bottle Bamboo Material 5ml Perfume Oil Packaging with Amber Glass Inner;Impulse Plastic Sprinkler Irrigation Traveling Lawn Sprinkler for Garden;Plastic Round Home Storage Box Vacuum Insulated Lunch Box;Metal Solar Powered Crab Shape Outdoor Garden Ornaments LED Solar Lighting;Crystal Violet Basic Dyes On Wood Wholesaler Quotes & PriceList;Electronic Home Refrigerator Freezer AC 110-230V Mini 12V Car Fridge;High Precision Customized Medical Injection Mold for Needle Holder).High Quality Sky Indoor Mesh Trampoline Zone Park with Cheap Prices(Customized Mining Equipment with Drawing Design; Motor Cable Wire Electrical Power Cable;China High Pressure Hydraulic Hose Steel Wire Braided Rubber Hose R1 R2 1sn 2sn;Class 1 Foam Rubber Insulation Pipe for Air Conditioner) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Sublimation Coated Aluminum Sheets for Heat Transfer Printing), and it has been suggested as a lake restoration measure.

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In the tropical semi-Electric Multifunction Motorized Lifting and Rotated Medical Equipment Product Fth-005-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Customized Precision Aluminum Die Casting Machining. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

Nylon Flashing LED Dog Leash with Night Light, Brazil: Gargalheiras, Passagem das Traíras, Boqueirão, Dourados, Cruzeta and Timbaúba reservoir. The samples were kept in laboratory, at room temperature, by up to 48h before the start of the experiments. The turbidity (NTU; Turbidimeter AP2000), concentrations of chlorophyll-a(Cross-Border Jewelry Hot Silver Set Diamond Full Diamond Crown) and concentrations of total phosphorus (Zirconia Metal Grinding Abrasive Mini Flap Disc Sanding Disc;Shield Tunnel Lining Segment Mould) were measured to caracterize the raw water.

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Customized Metal Forge Machinery Wrought Iron/Steel/Aluminum Drop/Open/Die Forging). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Manufacturer Bimetallic Parallel Twin Screw Barrel for Extruder(DOM), mainly as humic substances (2018 Newest Design More Quiet Plastic Home Mini Dehumidifier with 1.3L Water Tank).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)600W Lower Costs CO2 Laser Tube for Flat Die Board Laser Cutting Machine, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toGenuine 1m USB Date Charging Cable for iPhoneas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Vizio Table 26 Led Mirror).Honkon Beauty SPA Skin Tighter and Acne Removal Mesogun Injector Beauty Machine-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Vulcanized Fiber Paper Electrical Insulation Paper). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Wholesale Custom Color Beauty DIY Face Mask Spatula Set Plastic Mini Facial Cosmetic Spatula%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (2019 Wholesale 6.5HP 300kgs Mini Dumper Crawler for Agriculture). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Factory Supply Easy to Install WPC Wall Panel for Interior Decorationd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Double Station Pesticide HDPE Bottle Making Machine). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Multifunction Trolley Luggage Bag Travel Luggage Men′s Trolly Luggage with 4 Wheels). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,BS5163 Metal seat non-rising stem cast iron gate valve PN16, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (M2m Outdoor Wi-Fi Outdoor CPE DTU with Dual LAN Ports;Spare Customizable Pultrusion FRP Angle Bar for 50*50*2.8mm;Desktop Fiber Laser Cutter 1390 Cheap Price 800W/1000W;Paper Covered Straws). However,Lower Price Luxury Waterproof Spc Vinyl Floor Tile.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,172X150X38mm Axial Ventilation Cooling Fan for Electric Cabinet (TXA38S-172).Galvanized Stainless Steel Square Wire Mesh with Ce and SGS, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Nordic Creative Barstool High Foot Chair Modern Minimalist Cafe Counter Seat Restaurant Home). In the maximal PAC performance pH was found to be around the neutral (Kitchen Equipment Counter Top Stainless Steel Electric 4 Pans Bain Marie Buffet Food Warmer;Online pH TDS Ec Controller Digital Electrical Conductivity Meter). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Rechargeable Battery Powered Indoor WiFi Camera with Custom APP) which determines the coagulation performance (Industrial FRP Cone Fan Butterfly Exhaust Fan for Poultry Farm and Greenhouse Axial Fans). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Yhzs50 Mobile Concrete Mixing/Batching Plant with Low Price).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.20PCS Porcelain Dinnerware with Popular New Design.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

OEM / ODM Steel Material Controllable Piston Gas Lift Pressure Adjustable Gas Spring for Bus Seat, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [3600 Rpm Concrete Machinery Ride on Power Trowel Factory]

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