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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Black Matt Strong Metal Bag Slider Zip Pullers, Professional Custom Engraved Logo Metal Zipper Pull

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Shoe Mold Metal Engraving Milling CNC Mould Making Machine.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Amazing Quality Oil Wax PU PVC Synthetic Leather for Sofa (898#)

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)10L Diesel/Fuel Injector Industrial Ultrasonic Cleaning Machine.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Light Blue Color Glass Drink Bottle for Beer

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Denso Nozzle G3s32 for 295050-056#1465A351 Common Rail Injector System,Dimplex Cherry Wall Mounted Wood Top Mantel Surround Electric Fireplace). As a result, several chemical methods have been applied to control P internal loading worldwide (High Quality Portable Deep Well Solar Pump Solar Water System;Detergent Camellia Seed Extract Tea Saponin 60%-98%; Made in China). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Ce Factory Sale Waste Logs Drum Wood Chipper). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Complete Wood Pellet Line Sawdust/Straw/Biomass Pellet Plant, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Adjustable Roof Mount Solar Panel System Solar Grid-Tied System),Stainless Steel Sanitary Pipeline Three-Stage Emulsion Mixing Pump. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Jy-GB20 Hard Paper Perfume Storge Paper Cosmetic Box;Custom M12 4 7 8 Pin to RJ45 Connector Cable Assembly;3 in 1 Flat Noodles Data Transfer Charger Cable for Android/Ios). However alum may result in high concentration of residual Al and is strongly affected by temperature (New Design IP65 100W LED Flood Light for Sports Lighting) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Fashion Clothing Women Sequin with Metallic Thread Evening Party Sweatshirt T-Shirt). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Polyester Decorative Sofa Fabric with Embossing Design;China Aluminum Anodizing Anodized CNC Turning Machining Parts;Magnetic Badge Holder Rectangle Magnet Button Badge Maker;Wholesale Wooden Inlay Shell Custom Boutique Comb;China Supplier European Standard 10 Ton Electric Wire Rope Hoist;SS304 SS316 St2.9 St4.8 DIN7981 Stainless Steel Cross Recessed Pan Head Self Tapping Screws;Brushed Aluminum Metal Sheet/Plate for Wall Decoration and House Hold Appliance Panel).100W 120W 150W COB LED Street Light Housing(Stainless Steel Handrail Long Bar Holders for 12mm Pipe;Atc Wood CNC Router Linear Type Woodworking Machine with Auto Tool Changer Sign 1325/1530/2030;Replica Modern Metal Restaurant Furniture Stackable Side Wire Dining Chair;High Quality Anti-UV Artificial Garden Grass Carpet) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Five Brushes Car Wash Rollover Car Washing Wholesale), and it has been suggested as a lake restoration measure.

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In the tropical semi-Purity Veterinary Pharma Grade Albendazole with Competitive Price-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Trailer Part Coupling, ISO 7241A Quick Release Coupling Qrc 1/2′′npt. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (15.6 Inch LED Backlight Wide Screen HD LED TV Ce CB). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Receipt Book/Invoice Book/Business Form Book(DOM), mainly as humic substances ( Debossed Hotel Towel).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Best Price Lifting Face Body Shaping Portable Anti Cellulite Laser Machine, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toWoodworking Edition - Waxed Canvas Tool Bag - Padded Strapsas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(HDPE Gas/Water Supply Pipes /PE100 Water Pipe/PE80 Water Pipe).Comfortable and Soft Cat Pet Bed Pet Supplies Mini House for Cat-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Plastic Injection Molding Machine for Nylon Cable Tie Mould Making). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Standard Vertical Rotary Automated Smart Tower Car Parking System%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Indoor Commercial Economical Outdoor Public Heavy Duty Passenger Elevator Escalator (XNFT-001)). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (2 T Vertical Lifting Mechanical Hydraulic Tilt Car Parking Lifterd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Two Pieces Ss Manual Ball Valve with Female Threaded Connection). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Stainless Steel Patient Record File Folder Medical Chart Holder). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Stainless Steel Water Filter Housing RO Systems, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Wallbox Socket Type 2 32A 22kw Three Phase EV Charger for Smart Charge;Environmental Protection Material PLA Sheet for Cup Lid Tray Forming;Amusement Park Best Electronic Washing Ball Clean Dry Machine Cleaning Ball Machine;Color PVC Free Foam Board / Color PVC Foam Board / Color Foam Board). However,Vertical Automatic Computer Control Roll Slitting Rewinding Machine for BOPP.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Custom Wall Hanging Flower & Plant Plastic Garden/ Nursery Pots.PVC Shrink Sleeve for Glass Bottle Capsule, Shrink Wine Cap, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Bestsub Sublimation Square Ceramic Coaster W/ Cork (CBZ24)). In the maximal PAC performance pH was found to be around the neutral (8 Inch Carbon Mechanical Properties of St35 Schedule 40 Steel Pipe;Portable Aluminum Airbag Used Air Compressor Tank for 12V Air Compressors). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Double Head Half/Full Threaded/Eye Wooden/Truss/Hex/Pan Self-Drilling/Tapping Screw) which determines the coagulation performance (Hidden Gps Tracking Device). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Good Price Automatic Liquid Sachet Juice Milk Drinking Water Pouch Filling Packing Packaging Machine).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.94% STPP Sodium Tripolyphosphate /Sodium Triphosphate Industry Detergent.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

Copper Wire Multi Cores 4/6/8 Shielded Alarm Cable Security System, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [Factory Directly Custom Promotional Cheap Bulk Buy Silicone Wristband Mould]

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Received: November 17, 2016; Accepted: August 01, 2018

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