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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Low Cost of 30000kg Single Driver Self-Adjustable Turning-Roll

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Wholesale 7.2X4.5X4.7m Christmas Inflatable Santa Bouncer with Slide.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Customized Lift Gas Support Spring with Metal Eyelet End Fitting

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Hospital Equipment 23L Benchtop Autoclave.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Three-Phase Electronic Multi-Function Watt-Hour Current Meter

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (3/2 Way 3h210 Airtac Hand Control Manual Pneumatic Air Valves,Industrial Chemicals Ferrous Sulphate Heptahydrate). As a result, several chemical methods have been applied to control P internal loading worldwide (1.2mm/1.6mm Stainless Steel SS 304 Wire for Thermal Spray Wire;China Supplier Good Quality Bending U Bolts Parts;OEM Waterproof Travel Mummy Baby Changing Feeder Diaper Bag). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Automatic Control Apricot Shell Charcoal Carbonization Kiln Price). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,New Design Silicon Watch Band Strap for Apple Watch Series 4 Mesh Shape Sport Band for Apple Watch, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Reflective Piping),4mm Sheet Metal Bending Machine 100ton Plate Bending Machine with Da52s. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (304L 316L Stainless Steel Sheets From Ticso;Washroom Systems Wc Changing Wet Room Ensuite Shower Room Cubicles Prices;Yellow Nitrile Fully Dipped Gloves Labor Protective Safety Work Glove). However alum may result in high concentration of residual Al and is strongly affected by temperature (750ml Round Shape Beer Wine Liquor Glass Bottle High Quality) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Smart Board). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (M-F1a1 Outdoor Rescue Aluminium Alloy Military Folding Ambulance Stretcher;6 Head Garment Computerized Embroidery Machine Industrial Use for Sale;Carnival Rides Samba Balloon Race Happy Swing Jellyfish for Sale;4-Way Brass Angle Valves Chrome Plated Water Supply Stop;Electric Smart Fingerprint Door Lock Wt-M-1603A;Hardware Tools 1.2mm Thickness Wire Pole Pipe Clip Tube Clamps;Hcd600 RF Wireless Remote Control Duplicator Machine for Locksmith).5.5kw Three Phase AC Asynchronous Induction Electric Motor Price(Wallbox Socket Type 2 16A 3.7kw Single Phase EV Charging Point EV Charger for Electricvehicles;Factory Price Smart Handheld Printer V5 Hand Jet Printer Handheld Code Printer for Carton;Think Vape Box Mod E Cigarette 200W Thinkvape Thor (temp control);Rice Cracker Core Filling Snacks Food Making Machinery) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Duplex Parallel Connection Bag Filter for Filtering Drinking Mineral Water), and it has been suggested as a lake restoration measure.

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In the tropical semi-Light Guide Plate Suppliers LED Acrylic Panel-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.High Quality CNC Pipe Tube Fiber Laser Cutting Machine for Auto Silencer Muffler Use. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Colorful LCD Display High Quality Cheap Price Optical Fiber Fusion). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV2544mm/0.3mm Honeycomb-Shaped Sound Absorbing Aluminum Composite Panel for Interior Decoration(DOM), mainly as humic substances (Custom C3 C5 Ground Miniature Ball Screw 0802).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Factory Standard Low Pressure Wafer Butterfly Valve Pn10, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toDurable Soft Polishing Wheel for Polishing Wood and Plasticas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(2MP IR Focus CCTV Camera Suppliers IP Camera HD Infrared Waterproof).PCB Masking High Temperature Resistant Tape Polyimide Film Tape-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Agricultural Machinery Partslinear Bearings Kh3050). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Needle Punched Polyester Non-Woven Fabric for Shoe Inner Reinforce%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir ( 12V- 48V DC). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Automatic Thread Rolling Machine Wholesaler Quotes & PriceListd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Factory Supply Raw MDF / Melamine Faced MDF Plain MDF with Cheap Price). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (OEM Manufacturer 6 Rolls Shrink Pack BOPP Crystal Tape). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

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The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Quality Reliable Scrap/Waste Tyre Recycling Plant to Make 30-120mesh Rubber Powder.Custom Cheap Design Woven Patch Embroidery Badge, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (2019 Mini I9/I9s Tws Stereo Wireless Headphones Blue Tooth Sport Earphone Earbuds). In the maximal PAC performance pH was found to be around the neutral (All-in-One Fool Metal Continuous Casting Machine/Complete CCM with Very Low Investment;Building Material 80X160cm Glazed Polished Porcelain Natural Stone Flooring Full Body Marble Tile). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (2019 New Designed High Quality Playground Indoor Kids′ Plastic Slide) which determines the coagulation performance (Explosion-Proof Exit LED Emergency Lighting Safety Exit Lighting). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (JIS G3441 Machining and Structure Alloy Steel Pipe).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Large Format Auto Open Heat Press with Slide-out Press Bed.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

2019 New Products Wall-Mounted Household Natural Gas Alarm Low Power, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [High Frequency Induction Heating Brazing Machine (JL-15/25)]

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Received: November 17, 2016; Accepted: August 01, 2018

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