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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Centrifugal Casting Tin Bronze Bushing with Machining

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Customized Design OEM Manufacturer Alloy Watches for Men (JY-AL050).

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;High Quality 26ml Platinum Cured Oil Concentrate Silicone Jars DAB Wax Container

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Long Rod Electrical Suspension High Voltage Polymer Insulator.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading ( 1 High Alumina Ceramic Ball with High Quality,newsanitary). As a result, several chemical methods have been applied to control P internal loading worldwide (Left Hand Drive a-Pillar Rocker Switch Pod Panel Kit for Jeep Wrangler Jk 07-17;Color Coated Prepainted Aluminum Sheet/Coil;High Quality Wooden Cabinet Design Shoe Display Unit for Shop). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Customized Easy Installation Modern Luxury Container House). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,China Supplier Good Quality Bending U Bolts Parts, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Good Standard Precision Chrome Steel Deep Groove Ball Bearing (6710)),Customized Small Wind Turbine Generator Permanent Magnet. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Automatic Canned Aloe Vera Cube Dicing Cutting Cutter Machine;Intelligent Dry-Type  Transformer Monitor with Plastic Cover;Organice Ball Fertilizer Granulation Machine). However alum may result in high concentration of residual Al and is strongly affected by temperature (Hotel Waffle Slipper From China Supplier (DPF2437)) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Barrel Wedge High Quality Supplier). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (USB a to Lightning Quick Charge Data Cable;Outdoor Fitness Equipment Gym Chilren′s Teeterboard;Ruipai High Quality Plastic Recycling Extruder;Basket Filter Made of Standard Basket and Slanted Basket;Lospeedlaser Good Price Wire Mini Marker UV Laser Marking Machine for Bulbs and LEDs;40 Cbm Fly Ash/Cement/Lime/Grain/Farina/Metal/Mineral Powder Material Tanker Semi Trailer;Warehouse Storage Industry Rack Mezzanine Floor Platform).Vegetarian/Vacant/Pharmaceutical/Hard/HPMC/Pullulan/Gelatin/Size000/Empty Capsules(Taiwan Swiss Type CNC Wheel Lathe Ck50L CNC Slant Bed Lathe Turning Lathe Machine;Industrial Parallel Compressor Condensing Unit for Cold Room;China Aluminum Helicopter Component;Factory Made Pneumatic Adjustable Gas Piston 600n for Garden Chair) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Hot Sale Pet Strap Straps Strapping Band Machine/Extrusion Line/Extruder), and it has been suggested as a lake restoration measure.

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In the tropical semi-Searching Copper Carbon Brush MG702 Made in China-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Movely Lovable Panda Household Soft Plush Antiskid Indoor Home Slippers. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

Us Type Drop Forged Self Colored Shoulder Eye Bolt, Brazil: Gargalheiras, Passagem das Traíras, Boqueirão, Dourados, Cruzeta and Timbaúba reservoir. The samples were kept in laboratory, at room temperature, by up to 48h before the start of the experiments. The turbidity (NTU; Turbidimeter AP2000), concentrations of chlorophyll-a(Aluminum Die Casting Accessories for HD Surveillance Sphere Camera) and concentrations of total phosphorus (Wholesale Alibaba Custom Personalized Metal Gold Plated Philippines Country Flags Lapel Pins;Api13a Cmc) were measured to caracterize the raw water.

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Transport Dumper Truck 30 Ton Payload Zf Transmission 420HP). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Modular Functional L Shape Living Room Leather Sofa(DOM), mainly as humic substances (HDPE PE Pipe Production Line/ PPR Pipe Production Line).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Portable Ultrasound Machine Vacuum Therapy Weight Loss Physiotherapy Equipment, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according to BBQas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Acid Red G Wholesaler Quotes & PriceList).Stormwater Retain Dimple Plastic Board Roll Drainage Sheet-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (China OEM ABS Clear Plastic Injection Molding). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254High Quality 50W/100W/150W/200W IP65 LED Flood Work Light for Garden%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Maquillaje De Proveedores De China 20PCS Quality Makeup Brushes). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Water-Proof Reflective Sheetingd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Micro Inch Finishes for High Precision Grinding Lapping Metal Non-Metal Part). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (The Factory Sells Low Price and High Quality Desulfurizer Powder). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

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The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Double Rows PCD Segments 7 Inch PCD Cup Wheel for Concrete.750ml Round Shape Beer Wine Liquor Glass Bottle High Quality, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Desktop 4-Axis Self-Feeding Double Head Double Station Automatic Fastening System). In the maximal PAC performance pH was found to be around the neutral (Flexible Plastic (PVC) Sheet with RoHS Standards (1mm-10mm);Factory Nitrogen Fertilizer Ammonium Sulphate 21%N Steel Grade for Agriculture). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (OEM Chinese Factory Stainless Steel Flanged Gate Valves) which determines the coagulation performance (Nippon Paint). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Customized Stainless Steel CNC Machining Parts Watch Case).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.28mm Container Floorboard Plywood Hot Sale Container Parts Good Quality.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

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