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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Alluvial Sand Tin Mining Process Equipment Rollers Electrostatic Separator

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Factory Price Luxury Autism Heavy Duty Weighted Mink Blanket.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Stainless Steel Rectangular Pipes for Balcony Guardrail

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Jbz-22D Automatic High Speed Paper Cup Forming Machine.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Flexible Plastic (PVC) Sheet with RoHS Standards (1mm-10mm)

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Cement Bag Manufacturer Kraft Paper Valve Bag for Cement,Green Landscape Artificial Grass Garden Decorative Artificial Lawn China Factory (LS)). As a result, several chemical methods have been applied to control P internal loading worldwide (Custom Stainless Steel Parts CNC Automotive Device Spare Parts CNC Milling;Popular High Quality Wholesale Felt Christmas Bag Christmas Felt Gift Bag;PC260 3.0-24V 24*27mm 3W DC Motor for Electric Garden Tool). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (LED Dancing Wing Props Halloween Christmas Party Supplies). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Customized Mining Equipment with Drawing Design, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (sanitary napkin),Custom Jewellery 925 Sterling Silver Jewelry Diamond Stud Earrings. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Glass Shower Door Frame Waterproof Seal PVC Seal;2-Channel/4-Channel DC Current Voltage to RS232/RS485 a/D Converter;Cheap Bearing Rotary Fiber Laser Marking Machine Marker Laser Machine for Stainless Steel). However alum may result in high concentration of residual Al and is strongly affected by temperature (12mm Multiwall Green Perforated Hollow Polycarbonate Sheet) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (New 2020 Trending Product Hospital Bed Medical Air Mattress for Patient Bed). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Best Quality Tianeptine Acid / Tianeptine CAS 66981-73-5;Chiller Price Water Cooling System Screw Air Cooled;1.0m 4CH Wireless NVR Alarm Security CCTV Kit with 10 LCD Monitor 1tb HDD; NdFeB Magnet for Motor (N38H);Hydraulic Cylinder Seal Plastic Parts Mould Maker.;15kg Big Payload Unmanned Aerial Vehicle (uav) with Various Camera Payload Optional;2.4GHz WLAN Signal Booster 2.4G Wi-Fi Internet Wireless Signal Amplifier Repeater Booster).Food Quick Freezing Machine Type Industrial Freezer IQF Fruit Freezing Tunnels(Long Sleeve Safety Working Clothes Professional Safety Working Clothes;Customized Ring Die for 560/508/420/350 Pellet Machine;Rubber Tile Spacers;New Slimming Product Grapefruit Weight Loss Capsule) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Safety Belt Polyester for Lifting Sling /Round Sling (NHRS)), and it has been suggested as a lake restoration measure.

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In the tropical semi-Colorful Mobile Phone Accessory Dull Polish Back Cover PC Phone Case for Meizu Note 6-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Women′s Mesh Contrast Pleat Fashion Black Tank Top. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (High Energy Wet Pulverizer and Wet Powder Mill). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Compatible for Nellcor/Neusoft Reusable SpO2 Sensor Adult/Neonatal Finger Clip SpO2 Sensor(DOM), mainly as humic substances (Aerospace Industry Cutter Systems/ Equipment Cutting Plotter CNC Cutting Machine).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Bottle/Cup Electrical Tunnel/ Steam Tunnel for Shrinking Sleeve Labeling Machine, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toOEM Custom 2pieces Car Rims 17 18 19 20inch Forged Car Alloy Wheelsas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Machining Parts).Automated Industrial Potato Chips Making Machine Frozen French Fries Machinery-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (BRT Gasoline Log Splitter 22 Ton Firewood Processor). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Hook Vintage Weathered White Wall-Mounted Wood Coat Rack with Chalkboard Labels%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Fashion in China Tag Watches Men Quartz Water Resistant Stainless Steel Back Dw Watches). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (High Quality Adhesive for PE/Pet Laminated Paperd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Custom Dye Sublimation Printed Phone Lanyard ID Badge Holder with Logo Custom). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Cotton/Polyester/Spandex Interlock for Clothing). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Custom A4 Size Plastic PP Clear File Button Folder, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Cheap CNC Leather Oscillating Knife Cutting Machine Milling Head Knife Head Cutter;Bh36/Dh36/Ah36 Hot Rolled Marine Steel Shipbuilding Plate;Z21 Type High Precision Flexible Locking Coupling Assembly Device;Waterproof Bag 20l). However,Atc Wood CNC Router Linear Type Woodworking Machine with Auto Tool Changer Sign 1325/1530/2030.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,What Is a Membrane Switch Keyboard Professional Manufacturer.High Speed Precision CNC Fiber Laser Marking Machine, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Certified 100% Natural & Pure Organic Basil Herbs Oil). In the maximal PAC performance pH was found to be around the neutral (Class125 Double Disc Wafer Swing Check Valve;Wholesale Ground Vulcan Earth Screw Anchor for Rail and Highways). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Juki Pick and Place 40071585 Head Vacuum Unit Asm for Ke3020 SMT Machine Original New in Stock) which determines the coagulation performance (OEM-CNC-Stainless-Steel-Turning-Parts-Aluminum Ring). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Polyethylene Strap Polypropylene Band Pet Packing Tape Pet Strapping Band Making Machine).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.New Design EEC Approved Electric Scooter Harley City Coco with EEC Approved.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

Flake /Pellet/ Bead /Powder High Quality Road Snow Melting Agent Magnesium Chloride Exported to Japan 46%, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [CCTV 8.0MP 4K Video Security Surveillance IR Dome Ahd Camera]

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