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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Biogas Digester Double Membrane Gas Holder Anaerobic Fermentation Tank

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Made in China Multi-Storey Steel Structure with Light Steel Frame.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Food Machine/Chd330 Compact Carrot Cutter Cutting Machine

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Modern Style Classic Shangri-La Window Shutters Roller Blinds.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Factory Direct Sale Warehouse Light IP65 150W LED High Bay

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Ductile Iron Service Gate Valve Ductile Iron Screwed Ends Resilient Gate Valve Thread,P10-32X96 Yellow U-Disk Control Outdoor Waterproof LED Display Screen Picture or Text Can Be Edited). As a result, several chemical methods have been applied to control P internal loading worldwide (New Arrivals Soccer Synthetic Grass;380W New Beam Moving Head Night Club Disco Lighting for DMX Controller;Large Diameter ASTM A213 TP304L Seamless Stainless Steel Pipe). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Trisun Mechanical Seal Spare Parts Wave Spring). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Custom Label Printed Black Matte Smell Proof Aluminum Foil Ziplock Zipper Bags, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Standard Office Desk Dimensions),Twist Lock Power Cord, Twist Lock Power Cable. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Manufacturer Price High Strenghth HDPE Garbage Bag;Jmc Vacuum Road Dust Truck Mounted Sweeper Car;for Steel Arc Furnace Use The Quality Should Be Good Certified Grades). However alum may result in high concentration of residual Al and is strongly affected by temperature (Hairise Har8505 Heat Resistant Modular Conveyor Belt with Food Grade) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (High Voltage Fuses). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal ( Aluminum Parts;Thermal Insulation Rubber Foam Pipe for Air Conditioning;Food Grade Composite Packaging Standup Plastic Pouches Bag with Zipper;Waterproof Realistic Dildo G Spot Vibrator Adult Sex Toys;PP sheet;Cheap E306D E330d Caterpillar Cat Excavator Water Cooling Radiator; Pol.).Wholesale New Crop Pumpkin / Sunflower / Watermelon Seeds Kernels Bulk Price Seeds(Al2O3 Alumina Ceramic Porous Foam Filter Plate for Non-Ferrous Alloy & Aluminum Alloy Casting;Reflective Tape Protective Nomex Fire Suit with Trousers;ASTM A269 309 309S Seamless Stainless Steel Pipe;Collagen Wound Dressing Plug for Teeth Extraction) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Building Material Prime PPGI/PPGL Color Coated Prepainted Galvanized Steel Coil), and it has been suggested as a lake restoration measure.

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In the tropical semi-Men′s Watch High Quality Steel Quartz Wrist Watch (72057)-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.China Label Screen Printing Machine Suppliers. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Non Woven Weed Control Nonwoven Fabric Laminated Nonwoven Fabric). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254USB Powered UV LED Photocatalyst Electric Bug Zapper Mosquito Killer(DOM), mainly as humic substances (Automatic Blister Plastic Vacuum Thermoform Molding Packing Machine).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Polyester/PP Short Fiber Needle Punched Non Woven Geotextile Fabric, Low Price, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toIndustrial Fiber Laser Marking Machine for LED Lamp/Bearings/Ringsas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Custom Calendar Notebook High Quality Products).Wholesale Chinese Sax / Tenor Saxophone, High Quality, Made in China-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Professional Fishing Equipment Carbon Pole Rod for Sale). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Wholesale Wehappy Silicone Baby Training Toothbrush Set with Blister Card Package%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Ce Approved Panel 40W 48W LED Border Line Light with Mean Well Driver). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Chinese Building Material Polished Porcelain Foshan Marble Floor Tilesd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Boy Children EVA Beach Sandals Sport Sandals Flat Sandals (21jk1628)). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (2000W 60V Two Batteries City Coco Scooter Bike). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Garden Metal Natural Rusty Flower Decoration Product, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Multi Span Venlo Type Agriculture Production Glass Greenhouse;SAA Approved 3 Phase Industrial Female Plug 66csc/66asc Industrial Switchgear IP66;Custom Logo Printing Silicone Waterproof Swim Swimming Cap for Promotion;Supply of Recycled Rubber Rubber Rubber Rubber for High Quality Tires). However,LED Mounter Jx-300LED/ Chip Shooter/ Jx300LED Mounter.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,38cc Petrol Chain Saw Wood Cutting Machine.High Chrome Cast Iron Mud Sand Slurry Pump Parts, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Outdoor Full Color P6mm Front Maintenance LED Display). In the maximal PAC performance pH was found to be around the neutral (Water Treatment Chemicals RO Antiscalant Acidity for Groundwater;Proessional PCB Assembly Fast PCB Manufacturer SMD PCBA Fr4 PCB Board Production). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Letter Size A4 Adhesive Sticker Shipping Self Adhesive Paper Labels) which determines the coagulation performance (Double Pole Switch). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (China Factory Gk35 Sewing Machine for Bag with Conveyor).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Disposable Polypropylene Protective Head Wear Bouffant Cap.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

Plastic Injection Molding Machine for Nylon Cable Tie Mould Making, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [Electronic 4-20mA 0-5V 0-10V Pressure Sensor Switch with on/off PNP/NPN Switching]

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