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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Pressure Sensor Water Level Pressure Transmitter.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Empty Clear Glass Olive Oil Bottles Used for Filling Custom Square Glass Bottle Wholesale

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Automatic Packaging Filling Machine for Concentrated Liquid Detergent Pod.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Granular Fertilizer Potassium Sulphate/NPK/Compound Production Line,Vertical Type Automatic Box Erector Machine). As a result, several chemical methods have been applied to control P internal loading worldwide (Pneumatic Vertical Threaded 3-Way Ball Valve;Pure Hyaluronic Acid Powder with Reasonable Price;3D Finish Soundproof Movable Partition Wall for Meeting Room). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Factory Standard Low Pressure Wafer Butterfly Valve Pn10). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,ERW Welding Black Steel Tube for Construction/ Structure / Building, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Base Glass Clamps),Auto Car Parts Good Quality 16620-0s010 Tensioner Pulley. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Water Cooled Vibrating Grate Boiler for Power Plant EPC;Non-Smoke E7018 E6018 Welding Rod Carbon Steel Welding Electrodes;Lovol Rice Combine Harvester-Small Tank with Two Hoppers). However alum may result in high concentration of residual Al and is strongly affected by temperature (Food Grade Oval Cute Newborn Pacifiers with Soft Soother) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Snf-B/Fdn-B/ Sodium Naphthalene Formaldehyde/ Water Reducing Admixture). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Top Quality 40m3/H Small Mobile Mini Twin-Shaft Mixer with Pump;Permanent Magnetic Separator for Conveyor Belts;High Quality HVAC Exhaust or Supply Plastic Air Valve;High Visibility Reflective Safety Waterproof Outdoor Winter Jacket Softshell Jacket;Compressed Air Storage;Customized Stainless Steel Cut Wire Shots Sand Blasting Grit;Custmoized High- Quality Decoration Mirror Stainless Steel Curtain Wall).Woodworking Machinery Acrylic Plywood Cutting 2000*6000mm CNC Router Machine(Transmission Line Steel Monopole Steel Tower; Camera;Medical Disposable Oxygen Mask Nebulizer Mask;Industrial Air Cooled Heat Pump Water Chiller in Many Field) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (14kw Heating Capacity Evi Air to Water Heat Pump), and it has been suggested as a lake restoration measure.

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In the tropical semi-ASTM A242 A588 Corten Steel Plate/Sheet/Coil/ Corten a/B/ SPA-H / B480-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.P810 Indoor & Outdoor Single Color Vehicle LED Display Module. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Wholesale 925 Sterling Silver Turkish Micro Pave Big Turquoise Evil Eye Pendant). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254High Quality Rogers Athletic PRO Squat Equipment(DOM), mainly as humic substances (PCB Masking High Temperature Resistant Tape Polyimide Film Tape).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)CNC OEM ODM Customized Car Housing Parts Machining Parts, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toBreathable High Visibility Reflective Safety Leisure T-Shirtas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Mini Acrylic Paint Roller (red & grey stripe white base)).4 Seat Lead Battery Powered Electric Beach Buggy Cart (DN-4)-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (High Quality Portable Deep Well Solar Pump Solar Water System). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Free-Maintenance Motor Design White Light PTZ Security Cameras%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Detergent Camellia Seed Extract Tea Saponin 60%-98%). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Newest Design Heart Key Shape Necklace Natural Shell Plated Gold Necklace for Womend).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Ce Factory Sale Waste Logs Drum Wood Chipper). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Jy-GB20 Hard Paper Perfume Storge Paper Cosmetic Box). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,High Speed HDMI to HDMI Cable 1.4 Version 1080P 3D Standard 2.0, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (New Design IP65 100W LED Flood Light for Sports Lighting;Polyester Decorative Sofa Fabric with Embossing Design;China Aluminum Anodizing Anodized CNC Turning Machining Parts;Highly Competitive Composite Brake Shoes for Train Freight Wagons). However,ISO3821 Certified Grade R 1/4′′ 50FT Rubber Twin Welding Hose.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Custom High Quality Men′s Fashion Plain Cotton Polo T-Shirt.IP65 60W Solar LED Street Light with WiFi Camera, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Magnetic Badge Holder Rectangle Magnet Button Badge Maker). In the maximal PAC performance pH was found to be around the neutral (Wholesale Wooden Inlay Shell Custom Boutique Comb;SS304 SS316 St2.9 St4.8 DIN7981 Stainless Steel Cross Recessed Pan Head Self Tapping Screws). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Brushed Aluminum Metal Sheet/Plate for Wall Decoration and House Hold Appliance Panel) which determines the coagulation performance (Anatase TiO2 Coloring White Masterbatch for PVC Pipe). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Stainless Steel Handrail Long Bar Holders for 12mm Pipe).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Good Sale Lfc Sand Preparation and Casting Molding Line.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

High Glossy/Matt/Embossed/UV/Natural Wood Veneer Faced Melamine Laminated Colored MDF for Furniture, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [Pn10]

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