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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Custom High Quality CNC Milling Acrylic Block Stainless Steel Aluminum CNC Precision Milling Service

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Audley Automatic 63′′ Hot and Cold Roll Paper Laminator Machine Price Adl-1600h5+.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;China Manufacturer Zinc Coated Galvanized Steel Wire for Overhead Ground Lines

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Food Grade Glass Storage Glass Jar for Spices Candy Foods Dried Vegtables Canned Fruit.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Chicken Layer House Design for Poultry Farming with Equipment

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Caterpillar 420f Backhoe Laoder 2015 Year Japan Made,Hot Sale Classic French Style White High Gloss LED Modern Reception Desk). As a result, several chemical methods have been applied to control P internal loading worldwide (Stainless Steel Slot Screen Pipe 0.3mm Slot Size;Ytpd173r140-4.0 Ultrasonic Focusing Piezoceramic Transducer for Beauty;2mm-15mm Smart Switchable Screen Mirror Glass for Sale (S-F7)). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (220kv Composite Suspension Insulators for Transmission and Distribution Line). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Motorized Automatic Electric Roller Shutters Window, Aluminum Hurricane Rolling Shutter, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (HEPA Mini-Pleat Panel Filter Pack Microfine Fiberglass Filter Media),Low Cost Commercial Plastic Film Greenhouse for Sale. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Rectangle Custom Various Color Metal Label Tag Sticker Handbag/Luggage Hardware;Customized CNC Machining Checking Fixture for Automotive Bracket;PS Foam Food Container Production Line PS Lunch Box Forming Machine). However alum may result in high concentration of residual Al and is strongly affected by temperature (Customized Precision CNC Mechanical Parts with Steel) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Anodized Aluminium Bending Metal). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (China Products/Suppliers. Prefabricated Metal Shed Steel Structure;Outdoor LED Street Pole Advertising Business Double Sided LED Signs;HD Small Pixel Pitch Full Color P1.667 Indoor LED Display for Meeting Room;Ventilation Back Draught Damper Volume Control Damper One Way Shutter Actuators;Outdoor Network Enclosure Box;Hand Tools Mini Wire Brush Set for Construction 3PCS OEM;Food Grade Titanium Dioxide F-200 Pigment).Supersnow Frost Free Combined Deep Island Commercial Supermarket Display Freezer(Silicone Rubber Pin Insulator/Polymer Composite Insulator (10kv-33kv);Customized Waterproof Backpack Canvas Laptop Bag;Cbd Thc Hemp Oil Vaporizer Bag Plastic Tube Hologram Packaging;Medical Acupoint Patch with Sterile Wound Patch for All People) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Carbide 4 Flutes HRC60 Blue Coated Milling Cutters), and it has been suggested as a lake restoration measure.

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In the tropical semi-Toner Cartridge Chip for Ricoh Aficio MP C3002 3502 (841735~841738 841647~841650)-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.304 316L 321 904L 2205 1.4401 2507 Hot Rolled Stainless Steel Coil. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Wholesale Custom Microfibre Towel Rack Cooling Gym Yoga Bath Towel). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254FDA Natural Banish Hangovers Dihydromyricetin (DHM) 98% HPLC(DOM), mainly as humic substances (High Quality Honeycomb Ceramic Proppant / Filter Catalyst Supported for Mechanical Equipment).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Certified Factory 304 Stainless Steel Corrugated Flexible Yellow Natural Gas Hose, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toHigh Drying Efficiency Wood Sawdust Dryer for Saleas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Petroleum Coke).Photo Album Self Adhesive PVC Foam Sheets for Inner Pages-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Ex-Proof Motorized Flange End Ball Valve (PQ9B41F-300Lb)). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV2548 Seaters Solid Surface Quartz Dining Table and Chair%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Premium Genuine Leather Miyota Mechanical Movement Women Watch with Date). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Swedish Cleaning Clothsd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(New Design Export Fiberglass Adult Water Bike for Sale). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Permanent Magnetic Grid for Europe Market). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

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The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,New Arrivel Grand Sale Wholesale Soft Fishing Lure.Easy Fans Eyelash Rapid Bloom Premade Volume Fan Lashes, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Plumbing Fitting Water Connect Black Surface 1/2 Malleable Iron Flat Seat Conical Union). In the maximal PAC performance pH was found to be around the neutral (Stainless Steel Male Female Screw Fasteners Connecting Book Screws;Reusable 90 Degree Elbow Spherical Seal Hydraulic Female Hose Fitting 20191). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Multipurpose Rutile Titanium Dioxide TiO2 Pigment) which determines the coagulation performance (Christmas Party Use 30lb Disposable Helium Gas Cylinder). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Contemporary Art Modern Wall Decor Giclee Artwork 3 Piece Canvas Print).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Lady Black Mesh Mixed Tank Top Boyshort Two Piece Swimwear.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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