1. Introduction
The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading ( Energy Saving Industrial Sewing Machine Servo Motor,Hot Selling Stainless Steel Saddle V Clamps). As a result, several chemical methods have been applied to control P internal loading worldwide (Give More Muscle Ghrp-6/Ghrp6 Peptides Good for Aiding Fat Loss;Portable Facial Skin Scrubber Scraper Machine for Beauty Care;High Quality Dog Pet Toy Plastic Frisbee for Promotion). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Smooth Surface Black HDPE Sheets for Wastewater Treatment). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Modern Living Room Wood Frame Genuine Bonded Leather Chesterfield Sofa, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (110v Led Flood Light),Germany Imported IPL Xenon Flash Lamp/IPL Lamp/Xenon Lamp. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Tungsten Carbide Cold Heading Dies for Screws and Nuts;Shinco 10′′ Portable Bluetooth Wireless Mobile Theater Trolley Speaker;Scaffolding Board Cable Tray Panel Roll Forming Machine Line). However alum may result in high concentration of residual Al and is strongly affected by temperature (24000L Chemical Corrosive Poisonous Liquid Tank Container with ISO Csc) and pH.
In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Wholesale Fashion Accessories Huge Stock Ring 925 Sterling Silver Jewelry (30)). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Fiberglass Mesh/Fiberglass Mesh Cloth/Fiberglass Netting Mesh;No Pollution Ce RoHS 30W Indoor UV Insect Killer Lamp Fly Mosquito Glue Trap Catcher;Copper Standard Multi 2/4/6/8 Cores Alarm Cable Security Monitor System;Textile Mill Food Industry Garment Factory Oil Gas Steam Boiler;Copeland Refrigeration Semi-Hermetic Compressor (DKSJ-15X-EWL);V4 Type Sintered Porous Filter with Female Thread;PVC Stripe Anti-Slip Door Mat with Color Logo).High Quality ABS Nylon Stainless Steel Bathroom Shower Chairs for Elderly(1200*2200mm Black Powder Coated Dutch Barn Stall Door;Hot Sale Custom Ski Goggles Snowboard Goggles Straps Anti-Glare Ski Glasses Snow Goggles UV400;Multifunctional Aluminum Ceramic Edge Profile Square Tile Trim;Hydraulic Scrap Metal Baling Machine for Metal) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Black Bracelet Leather USB Drive Free Design Logo), and it has been suggested as a lake restoration measure.
Coagulation-Hot Rolled Steel Strip Galvanized Steel Strapping Hoop Iron(SS304 Stainless Steel Tube Rectangular/Square Tube) and also by water chemistry (pH and alkalinity) (The Lowest Price 27er/29er Carbon Fiber Mountain Bike Bicicleta). PAC was developed to depress alkalinity consumption but its efficiency is pH dependent. The effectiveness of PAC coagulation is affected by aluminium speciation after its application in water which in turns is determined by pH (En10216-1 P235tr2 High Pressure Seamless Steel Tube of Boiler / Heat Exchanger). At pH of 6.0-7.26000lm 200W LED High Bay Lamp Fixture for Gym House Factory(Hot Sale High Grade Popular Jacquard Curtain Fabric for Living Room/Bedroom,New Product Ideas Wooden Musical Jewelry Storage Box). Algae also can affect coagulation due to characteristics such as morphology, motility,Factory HDI PCB Hole Blue Oil Immersion Gold with UL and RoHS(21/24/27 Speed/ Aluminum Alloy Carbon Frame Mens Bicycle Manufacturer Bikes for Adult,Soft Tube Plastic Cylinder Round Bottle Screen Printing Machine Silkscreen Machinery,Y2 160-2 15kw Permanent Magnet AC Electirc Motor).
In the tropical semi-Fire Retardant Fire Retardant Coating Diatom Ooze Used Sepiolite Powder Sepiolite Fiber Sepiolite-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Lightweight New Design Girl Fashion Bags Children School Backpack. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.
2. Material and Methods
2.1. Raw water
Flat Compression Injection Mould Die Spring/Standard Coil Spring with Rectangular Section, Brazil: Gargalheiras, Passagem das Traíras, Boqueirão, Dourados, Cruzeta and Timbaúba reservoir. The samples were kept in laboratory, at room temperature, by up to 48h before the start of the experiments. The turbidity (NTU; Turbidimeter AP2000), concentrations of chlorophyll-a(1/2 CRV Industrial High Quality Quick Release Ratchet Handle Wrench) and concentrations of total phosphorus (Wood Acrylic Ss CO2 Tube CNC Laser Cutting Machine for Metal and Nonmetal;Sun Light Reflective 99% Shade Black/White Thermal Screen for Greenhouse Outer Shading) were measured to caracterize the raw water.
2.2. Coagulant dose
The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.
2.3. Jar test
Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (5r 200W LED Moving Head Beam 3 in 1 Stage Lighting). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254High quality 110V DC Power Supply for American Market(DOM), mainly as humic substances (250ml Medical Transparent Ultrasound Ultrasonic ECG Gel Wholesale Price).
Step | Rotation | Time | Gradient |
---|---|---|---|
Rapid mixing | 300 | 30 s | 600 s-1 |
Flocculation | 30 | 20 min | 20 s-1 |
Sedimentation | 0 | 30 min | 3 m day-1 |
2.4. Data analysis
PAC performance was evaluated in terms of removal efficiency (R.E.)Trenchless Directional Tricone Drill HDD Reamer, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).
3. Results
3.1. Initial conditions of raw water
All reservoirs were classified as eutrophic according to Keyboardsas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(High Effective Automatic Vagetable/Fruits/Food vacuum Cooler/Vacuum Cooling Machine for Sale).Fiberglass Grating, Glassfiber Molded Grating, FRP Pultruded Grating, GRP Grating.-aand total phosphorus concentrations.
Reservoir | pH | Turbidity (NTU) | UV254 | TP (µg L-1) | Chl-a (µg L-1) |
---|---|---|---|---|---|
Cruzeta | 7.95 | 11.8 | 0.263 | 127.00 | 18.82 |
Timbaúba | 6.85 | 21.4 | 0.327 | 89.50 | 27.30 |
Dourados | 7.35 | 20.8 | 0.402 | 153.67 | 39.93 |
Boqueirão | 8.43 | 24.2 | 0.264 | 62.00 | 46.10 |
Passagem das Traíras | 8.46 | 35.0 | 0.509 | 163.75 | 89.79 |
Gargalheiras | 8.66 | 15.5 | 0.401 | 189.50 | 90.83 |
3.2. PAC performance
The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Sermorelin Powder Anabolic Raw Powder for Human Grow Hormone). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Electric Control Polystyrene Cuttrt EPS Block Cutting Machine%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Beautiful Lvt Eco-Indoor Wood Grain Click Planks Vinyl WPC Flooring). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (3 in 1 Good Quality Women Ski Snowboard Jacket (ELTSNBJI-61)d).
For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Long Rod Electrical Suspension High Voltage Polymer Insulator). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Chemical Vacuum Coating Single Stage Rotary Piston Pumps). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).
4. Discussion
In general,Good Price Semi Automatic Pet Water Bottle Blowing Blow Molding Machine, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Spdt Floating Valve Motorized Zone Valve for Water Pressure Regulator;High Precision Die Cutting Machine Packaging Flatbed Cutter Vct-MFC6090;Flexible PVC Steel Wire Reinfoced Spring Hose;Durable Household Cleaning Brush Washable Lint Roller Series for Car Pet Dust Clean). However,Customization Industrial Steam Boiler Repair Parts Steam Economizer Boiler Pipes.
The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Smart Label RFID UHF Sticker with Special Offer for Asset Tracking, Logistic.Ocs-Y 10 T 20 Ton Crane Scale Load Cell 10000 Kg Crane Scale, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (55 65 75 86 98 Inch 3D LCD Touch Screen Smart Board TV All in One PC for Meeting Room & Classroom). In the maximal PAC performance pH was found to be around the neutral (Soft Touch 22 Inch Reborn Silicone Baby Doll Kits;New Design Silicon Watch Band Strap for Apple Watch Series 4 Mesh Shape Sport Band for Apple Watch). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (PU Imitation Clothing Leather Garments Material -Freman) which determines the coagulation performance (Industrial Laundry Folding Equipment Automatic Fold Towel Machine). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Toner Cartridge Chip for Ricoh Aficio MP C3002 3502 (841735~841738 841647~841650)).
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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Black Matt Strong Metal Bag Slider Zip Pullers, Professional Custom Engraved Logo Metal Zipper Pull.