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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-120 Grit Sand Blasting Media/Sandblasting Abrasives/Almandite/Garnet Sand 80 for Waterjet Cutting

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)3.0V 4mm Diameter Coreless Mini Strong Vibration Motor with Bracket.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Ampoule Sealer Machine Hydrogen Oxygen Gas Generator

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)TUV Standard China Jump Park Free Jumping Bounce Bed Trampoline Park for Kids.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Ceramic Floor Tile Wear Resistant Tile Non-Slip Floor Tile

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Ceramic Components Applied in Machinery Industry,20kw/25kw 240VDC Without Battery Isolated Transformer Solar Wind Hybrid Inverter). As a result, several chemical methods have been applied to control P internal loading worldwide (EPS100 Nts100 Xns100 Common Rail Injector Test Bench;BS5163 Metal seat non-rising stem cast iron gate valve PN16;12mm Thickness Square Corrugated Cake Board). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Customized EPDM NBR Rubber Bellows Expansion Joint). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Brown Fused Alumina Grain for Abrasive and Refractory, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Juicy Electric Bike),35-70degree 350W Dry Fruit Machine for Household Use. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Tunnel Wall Light IP65 240W Outdoor LED Building Exterior Lighting;Non-Slip Baby Kids Fashion PVC Rain Boots;High Axial Flow Clean Water Submersible Sump Irrigation Pump). However alum may result in high concentration of residual Al and is strongly affected by temperature (Air Bubble Stone as Ozone Diffuser for Air Pump) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Curve Supermarket Rack). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (2019 New Fashion Silicone Hot-Water Bag for Girl;Wholesale Plastic HDPE Foldable Rectangle Folding Wedding Tables;Rigid 94V-0 PCB Fr4 Double-Sided PCB with 1.6mm Thickness 2 Layer;LED Halloween Series Pattern Lantern Scene Decoration Props Skeleton Lighthouse;Julong Amphibious Multi-Function Dredges for River/Swamp/Wetland/Dry Land;OEM CNC Machine Machining Textile Machine Accessories;Simple 3 Fold Orthopedic Folding Foam Mattress).Warm Leather Glove Mink Fur Glove/Leather Palm Rabbit Fur Glove(Wholesale Oil Tanker Trailer 3 Axle 42000L Trailer Fuel Tank Semi Truck Trailer;Factory Price Resin Wedding Chairs for Sale;Factory Direct Custom Cosmetic Tube Square Empty Lipstick Cases;Non-Bladder Single Tube Disposable Thigh NIBP Cuff of 45-56.5cm) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Silica Gel Aerogel Thermal Insulation Materials Felts Fireproof Acoustic), and it has been suggested as a lake restoration measure.

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In the tropical semi-High Automatically Vacuum Hydraulic Oil Filtration Equipment for Oil Recycling-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Pneumatic Rubber Wheel for Wheelbarrow 4.10/3.50-4. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Popular Lifejacket EPE Foam Life Vest for Water Safety Equipment). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Chubont Hot Selling Waterproof Duffel Trolley Bag Size 19/22 Inch(DOM), mainly as humic substances (14G Auto Computerized Collar Flat Knitting Machine).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Professional Effective Shockwave Belly Fat Removal Machine/ Shockwave Slimming, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toPVC Shoe Upper with LED Light for Kids Slide-on Slippersas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Mini Electric Cement Concrete Mixer with Single Phase AC 0.5HP Electric Motor).Top Quality Cleaning Cloth Microfiber Hair Salon Towel-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Handrail Fitting / Stainless Steel Round & Square Tube Connector). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Stainless Steel Pneumatic Three Way Non-Retention Sanitary Ball Valve%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Kitchen Stainless Steel Washing /Wash Double Bowl White Sink). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Flex Pcb Manufactured).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(FRP Insulated PU Foam Composite Panel for Refrigerated Truck Body). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Whole-Sale 25cm Cleanroom M3 Wipes Cleaning Tissue Cellulose Wipers). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,2 Ton Brand New Small Cheap Backhoe Loader for Sale, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Wholesale Brosilicate Glass Smoking with Black Triple Layer /Triple Arm Straight Glass Water Pipe;Stationary Asphalt Mixing Plant From 100tph to 400tph;V9 37kw 220V 380V Various Motor Type Control Flexible and Adaptable AC Drive;Car Wash for Wheel Washing Machine/Truck Wheel Washing System). However,Middle Duty 20 Discs Harrow for 50 HP Tractor.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,OEM Custom Precision CNC Machined Steel Parts.Seamless Steel Tube ASTM A335 P11, High Temperature Boiler Steel Pipe Tube ASME SA335 P22 P 91, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Automatic Non-Woven T-Shirt Bag Making Machine with High Efficient). In the maximal PAC performance pH was found to be around the neutral (Belt Driven Oil Lubricate H-Pump Reciprocating Two-Stage Piston Air Compressor (RT1.5/12.5); Non-Contact Thermometer Gt750). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Personal Skin Care Silicone Sonic Facial Cleansing Brush) which determines the coagulation performance (Smart Disco Light DMX-240b Console 192 Channels Stage Light DMX Controller). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (UV Coating Surface Treatment and Indoor Usage Plastic PVC/WPC/Spc Flooring Extruder Machine).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Double Layer Waterproof and Durable Asphalt Shingle Roof Tile Roofing Shingles.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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Exdiibt4 Explosion Proof Type 10kw Power Inverter Built in Low Frequency Transformer, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [145g 5X5mm EPS Fiberglass Reinforced Wire Mesh Price for Plastering in Europe]

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P6.25 Interactive Dance Floor LED Display Screen, M. and GAWROŃSKA, H. Phosphorus immobilization in Lake Głęboczek following treatment with polyaluminum chloride.Oceanological and Hydrobiological Studies, 2008, 37(2), 99-105. http://dx.doi.org/10.2478/v10009-007-0046-x. [Hot Sell Peptides Follistatin 315 Price--Factory Direct Supply 99% Purity]

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