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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Multi Function Baby Bbags Maternity Diaper Backpack for Mom

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)800g ECR Glass Fibre Plain Woven Roving 800GSM for Munal Boats Buildings.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Travel Cutlery Set Fork Spoon Chopsticks Straws Brush Packed in Wheat Box and Pouch

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)3 Axis Vertical CNC Cutting Milling Drilling Machine Tool Center.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Comfort Rubber Cow Stable Stall Rubber Matting/Mattress/Mat with Fabric Insertion,T/C Drill Twill). As a result, several chemical methods have been applied to control P internal loading worldwide (Customized Dummy Animal Teething Toy Design Baby Pacifer;KERONG Electronic Keypad Digital Combination Hardware Glass Locks For Lockers′ Safes;High Purity Calcined Alumina Micro Powder for Ceramics Refractories). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Kids Waterproof Cow Leather Wool Felt Warm Fur Boots for Winter). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,200ml Facial Cleanser Foam Bottle with Silicone Brush, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (New Blast Hole Drilling Machine for Open Mining),Sleeve Block Truss for 290mm/400mm Aluminum Spigot Roof Lighting. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Coating Precision CNC Auto Spare Machinery Parts Turning and Milling Industry;10 Supply Water Pipe Insulation HDPE Outer Pipe;Coms Camera Factory Vari-Focal Lens DVR Camera Web Camera Bullet). However alum may result in high concentration of residual Al and is strongly affected by temperature (Reducer Hydraulic Fitting with Swivel Nut (2D)) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Qtj4-40 Small Manual Earth Block Machine Cement Interlock Brick / Fly Ash Brick Making Machine). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (High Manganese Mn13cr2 Mn18cr2 Jaw Plate Crusher Parts;Colorful Commercial PVC Vinyl Flooring for Office;Auto Air Poppet Valves Cover Plastic Mould / Mold;African Trapezoidal Triangular Pulley Roller for Sliding Gate Door-Silvery;12v 6w Dc Ceiling Fan;High Sensitivity Metal Detector for Security Inspection;High Power/Torque Density 7.5kw 2500rpm AC Servo 3 Phase Motor).Unistrut Type Slotted Steel Strut Channel or C Channel(10W Auto Oval Work Car Light Blue Red LED Forklift Warning Head Lamps;Prefab Multifunctional Steel Structureg for Wholesales Construction Material;Best Quality 4/8 CH Bullet IP Camera WiFi NVR Wireless Kit; Paper Bags) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (A2 Fireproof Inorganic Mineral Material for A2 ACP Panel ACP Sheet), and it has been suggested as a lake restoration measure.

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In the tropical semi-Camlock Coupling Hose Pipe Fittings (Aluminum, brass, stainless steel 316/304, Nylon & PP)-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Electronic Leak Detector Sf6 Gas Leak Detector So2 Analyzer. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Top Quality Polar Wohlenberg Paper Cutting Blade). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Customized China Fabrication Companies Workshop Warehouse High-Strength Steel Structure(DOM), mainly as humic substances (Large Format Auto Open Heat Press with Slide-out Press Bed).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Snowkey Manufacture Best Selling Air/Water Cooling Tube Ice Making Machine, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toWater-Proof Silicone Coated Fiberglass Clothas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Luxury Flip Effect Plastic Business Card 3D Lenticular Playing Card).Women′s Knitted Acrylic Sweater Fashion Dress-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Custom Polyester Woven Patch Logo Snapback Hats). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254304L 316L Stainless Steel Sheets From Ticso%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (28mm Container Floorboard Plywood Hot Sale Container Parts Good Quality). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (13.4L Helium Cylinder for 30PCS of 9′′ Latex Gas Balloond).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Self Tapping Screw Roofing Screw Bimetal Screw). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Double Side Painted Aluminium Coil Plate with PE Film). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Kunlun Paraffin Waxes From Petroleum Made in China, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Tri-Axle 50tons 60tons 18m Low Loader Lowbed Trailer Axles;Girl Bedroom Mermaid Design Cute Sweet Silk Cotton Printing Duvet Cover Comforter Cover Quilt Cover;Silicon Baby Bib Super Waterproof with Food Slot;Eaton Vickers Directional Valve). However,FM200 Automatic Fire Suppression System for Electrical Room.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Stainless Steel Brass Spring Check Valve (VG12.90081).Retract Drill Mining Rock Thread Button Bit, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (99.999% Sio2 Quartz Grain Sand 100-200 Mesh for Quartz Rod). In the maximal PAC performance pH was found to be around the neutral (Spot Supply Al2O3 85% Bauxite Use for Calcined;Industrial Dust Filter Aramid Nomex Fiberglass PTFE Fabric Filtration Fabric). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (High Quality Nylon Monofilament Suture Medical Nl Suture Thread with or Without Needle) which determines the coagulation performance (R699 Titanium Dioxide Rutile). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (304 Stainless Steel Deep Drawn Parts for Kitchen Equipment).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.PP Square Nail Clip Flat Cable Clips White & Black 14mm.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

High Speed China Oric Of6045 UV Flatbed Printing Machine with Dx5 Print Head, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [Wg9130583017 Sino Truck Spare Parts Combination Switch]

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