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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Luzhong-700 70HP 2WD Two Wheel Drive Farm Tractor

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Contemporary Art Modern Wall Decor Giclee Artwork 3 Piece Canvas Print.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

7

Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Yidek Sequence Fluctuation Flicker Measuring Analyzer with Internet Connection

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Eco-Friendly Biodegradable Natural Wheat Straw Toothbrush with Bamboo Charcoal Infused Bristles.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Anti-Slip Crazy christmas Cute Funky Cotton Custom Socks

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (OEM Custom Precision CNC Machined Steel Parts,30ton Hydraulic Bottle Jack). As a result, several chemical methods have been applied to control P internal loading worldwide (Professional Supplier of Hot Rolled Steel U Channel;Luxury Recycled Eco-Friendly Decorative Deep Wooden Spc Floor for Shop;Multi-Layer HDPE PE PPR Pipe Production Line). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (400W Vertical Axis Windmill Generator (200W-5kw)). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Steel Frame Fabricated Bird Poultry Broiler Farm Shed Building, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Butt-fusion Fitting Eblow),100 PCS Microscope Cover Glass for Preparation of Specimen for Biological Microscope. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Auto Part PDC Parking Sensor for BMW 66209261595;Precision CNC Auto Spare Machinery Parts for Car-Mounted Mobile Power Bank;Hot Sale Top Quality BPA Free Biodegradable Bamboo Toothbrush). However alum may result in high concentration of residual Al and is strongly affected by temperature (Kfc Macdonald Food Grade Convenient Disposable PE Glove) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Atomizer Perfume Bottle 5ml). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (IN-G084-3 Digital Portable Heart Race Health Care Tensiometer Upper Arm Blood Pressure Monitor;Melt Floor Lamp Copper Standing Lamp Modern Floor Lighting;OEM 2019 Custom Fashion Men Black Embroidered Crew Neck Sweatshirt with Embroidered Rose;Custom Aluminum Steel CNC Machining Mechanical Turning Parts;Chargers Mobile Phone;Private Label Hip Circle Mini Fitness Resistance Elastic Latex Bands;2 Ton Brand New Small Cheap Backhoe Loader for Sale).Professionally Made Aluminum Magnesium Die Casting Die(Galvanized Wire Fence Building Barbed Wire Fence Pictures;Fiber Laser Marking Machinery for Engraving Ribbon Metal Stainless Steel;Ordinary Discount Stainless Steel Hinge - AC1412-S - Zhuohui;Factory Manufacturer CNC Dual Use Combined Metal Sheet Plate & Tube Pipe Fiber Laser Cutter) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (3.0V 4mm Diameter Coreless Mini Strong Vibration Motor with Bracket), and it has been suggested as a lake restoration measure.

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In the tropical semi-Auto Bearing Inch Deep Groove Ball Bearing B45-108-NSK 45X90X17mm-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Different Kinds Butterfly Hot Melt Adhesive Applique Embroidery Patches. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

3 Inch Smooth Corrugated PVC Suction and Discharge Hose, Brazil: Gargalheiras, Passagem das Traíras, Boqueirão, Dourados, Cruzeta and Timbaúba reservoir. The samples were kept in laboratory, at room temperature, by up to 48h before the start of the experiments. The turbidity (NTU; Turbidimeter AP2000), concentrations of chlorophyll-a(High Speed Metal Pipe Automatic ERW Welded Pipe Machine) and concentrations of total phosphorus (DC/CC Aluminum Circle/Disc for Non-Stick Cookware Utensil;Tkf800-Co90 Small Machine Room Passenger Elevator) were measured to caracterize the raw water.

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation ( Skateboard Shoes). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Women 100% Polyamide and 100% Polyester Melange Hoodie Hybrid Vest(DOM), mainly as humic substances (Kids Electric Car with 12V Battery Remote Control).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Simple Design High Quality Cotton Velour Disposable SPA Hotel Travel Slippers with Logo, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according to904L Stainless Steel Press Sheet with Hl Surface Finishas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Sublimated Sports Shirt).Commercial Overhead Automatic Aluminum Insulated Roller Shutter Door for Garage or Workshop-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Single Double Multilayer PCB with High Precision Custom Printed Circuit Boards). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Factory Supply Raw MDF / Melamine Faced MDF Plain MDF with Cheap Price%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Precision Large 3 Axis Bench Metal Milling Machine Lm1450c). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (m.wanyingtools.comd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Direct Steering Gear DC Motor with Low-Speed High Torque Spare Parts). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Continuous Inkjet Printer for Plastic Pipe Printing (EC-JET1000)). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Manufacturing High Precision Ce Horizontal Cutting Band Metal Sawing Machine, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (1/2 Inch Soft Flexible Green Cloth Surface SAE 100 R3 Hydraulic Hose Rubber Hose;High Quality Electrochromic Pdlc Privacy Film;Transparent Single Crystal Alumina Sapphire Jewel Bearing and Components;Storage Sofa Coffee Tables with 1 Drawer Double Shelves). However,Automatic Defrost Supermarket Arc Sliding Island Freezer Horizontal Island Freezer.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Hot Sale Copolymer Coated Aluminum Foil Tape for Cable.Customized Stainless Steel CNC Machining Parts Watch Case, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Water Resistant Rubber Gasket for Industry). In the maximal PAC performance pH was found to be around the neutral (Mirror Chrome Aluminium Powder Gold Silver Pigment for Nail Art;4 Cryo Handles Cryolipolysis Fat Freezing Slimming Machine for Sale). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (OEM/ODM Custom Precision Copper/Aluminum /Bronze /Carbon Steel/Stainless CNC Machining Parts) which determines the coagulation performance (Blank Coated Sublimation Mug with Color Inside - 11oz). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Showbull Professional 5800 Gasoline Wood Cutter Chainsaw Made in China).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Double Side Painted Aluminium Coil Plate with PE Film.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

Professional Double Cup Fully Automatic Coffee Machine, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [Wood Plastic Mould/UPVC Profile Extrusion Mould Plastic Profile Extruding]

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