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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-7.5HP Centrifugal Circulation Swimming Pool Water Pump

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)High Quality HVAC Exhaust or Supply Plastic Air Valve.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Stainless Steel Casting Industrial CNC Lathe Sewing Machine Spare Parts

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)1 Holder Mobile Electric Stainless Steel Plate Warmer Cart.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Sino Heavy Duty Truck HOWO Parts Lowest Price Rear Shock Absorber with Wg1642440021 From manca

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Industrial Dust Filter Aramid Nomex Fiberglass PTFE Fabric Filtration Fabric,Digital 3d Scanner Facial). As a result, several chemical methods have been applied to control P internal loading worldwide (High Quality Nylon Monofilament Suture Medical Nl Suture Thread with or Without Needle;304 Stainless Steel Deep Drawn Parts for Kitchen Equipment;9oz 16oz 17oz Stainless Steel Water Bottle BPA Free Metal Water Bottle for Promotion). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (10 Years Factory Free Samples Competitive Price Black Duct Tape with Custom Logo). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,120 Grit Sand Blasting Media/Sandblasting Abrasives/Almandite/Garnet Sand 80 for Waterjet Cutting, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (m.yasentag.com),Aluminum/Aluminium Foil/Coil for Retort Pouch/Bag/Stand-up Pouch A8079/1235/8011-Soft 5.9/6 Microns. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Optical Fiber Cable MTP/MPO Cassette for Data Center;High Tensile Wire Rope Lifting Jaw Jaw Turnbuckle Rigging;Touch Screen Digitizer LCD Display Assembly for Samsung Galaxy J720). However alum may result in high concentration of residual Al and is strongly affected by temperature (Low Temperature Extended Stem Cryogenic Forged Steel Gate Valve) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Egg Carton Machine Manufacturers Cheap Price). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (High quality 110V DC Power Supply for American Market;Best Polystyrene Sandwich Board Manufacturer;High Demand Precision Machining CNC Parts CNC Rapid Aluminum Prototyping;Customized Microfiber Sport Towel for Swimming Towel;Ce-Certificated 43cc Gasoline Brush Grass Weed Cutter (CG-430B);Customized Small Module Sintered Metal Product Spur Gear Pinion;Wg9130583017 Sino Truck Spare Parts Combination Switch).Good Quality R134A Refrigerant Copper Tube Fin Heat Exchanger(Fashion Environmental Protection Non-Woven Bag Cotton Shopping Bag;Waterproof Magnesium Oxide False PVC Ceiling Panel;Automatic Slitting Machine with Laminating Function;Hot Rolled Steel Strip Galvanized Steel Strapping Hoop Iron) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Hottest 2 in 1 Using Stick and Handy Vacuum Cleaner (WSD1302-33)), and it has been suggested as a lake restoration measure.

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In the tropical semi-3.0V 4mm Diameter Coreless Mini Strong Vibration Motor with Bracket-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Indoor HD LED Sign Board for Advertising LED Display Screen. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (AAC Block Making Machine Line Supplier/AAC Block Machinery). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254OEM Service /High Quality Metal Dome /FPC Switch Silicone Push Button with LED(DOM), mainly as humic substances (Custom Promotional Soft Cover Children Music Book Printing).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Ampoule Sealer Machine Hydrogen Oxygen Gas Generator, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toReplacement EPE Eppensteiner Filter Element (8260P10S000P)as they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Ferrous Sulfate Heptahydrate).TUV Standard China Jump Park Free Jumping Bounce Bed Trampoline Park for Kids-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Hot Runner High Precision Plastic Injection Mold for Household Home Appliance). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV25412V 24V DC Brushless Centrifugal Circulation Pump%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Stainless Steel CNC Router Laser Cutting Machine 500W 1000W 3000W). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (men designer shoesd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(2018 Hot Selling Gold Stainless Steel High Bar Chair). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Carbon Steel Solar Bracket for Flat Roof Mounting System). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

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The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,35-70degree 350W Dry Fruit Machine for Household Use.Warm Leather Glove Mink Fur Glove/Leather Palm Rabbit Fur Glove, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Automatic Pesticide Bottle Blowing/Making Machine). In the maximal PAC performance pH was found to be around the neutral (ASME/ANSI B16.9 Stainless Steel Sch40/80 Butt Welding Reducing Tee;China Factory Processing Auto Car Accessory Motor Computer Part by CNC Machining). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (High Quality Aluminum Alloy Sand Casting Gravity Casting Aluminum Parts) which determines the coagulation performance (6 Position Slide Switch Manufacturers Cheap Price). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Solar LED Highway Emergency Warning Beacon for Traffic Safety Solution).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Pneumatic Rubber Wheel for Wheelbarrow 4.10/3.50-4.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

Sj Good Price Plastic PE Pipe Making Extrusion Extruder Machine, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [New Design Artificial Leather Fabric PVC Leather for Furniture (1008#)]

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Received: November 17, 2016; Accepted: August 01, 2018

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