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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Four Wheels Portable Electric Mobility Scooter with Lithium Battery

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Foil Induction Sealing Machine for Glass Plastic Bottle Jar.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;CNC Machining Duct Forging Stainless Steel Flange

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Chemical Carbon Plastic Frames V Bank Filter Activated Carbon.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Alibaba Clear Aluminum Corrugated PVC Roofing Sheet /Corrugated Roofing Sheet India

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Hg-Ot-102st Infrared Thermal Imaging Sighting Tracking Night Vision Telescope,Commercial High Performance Composite Steel Fireproof Shutter Door for Sales). As a result, several chemical methods have been applied to control P internal loading worldwide (New Arrival Household Self-Washed Flat Mops Cleaning;Chinese Furniture Outdoor Garden Furniture Aluminum Sofa Sets;Sino Heavy Duty Truck HOWO Parts Lowest Price Rear Shock Absorber with Wg1642440021 From manca). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Breathable Pet Dog Shoes with Reflective Magic Tape Straps). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Fresh Mung Bean Filling Stand-up Pouch Packing Machine, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Auto Frame Installer Pressing Machine),Custom Bracelet USB PVC Segmented Tag Wristbands No Minimum Order. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (2018 Newest 12inch Music Sound Box for Computer;Customized Cutting Tool Solid Carbide Tool Taps (TS-100002);Cyclone Mesh Turbo Diamond Saw Blade for Ceramic Tile). However alum may result in high concentration of residual Al and is strongly affected by temperature (16800mAh 800A Car Emergency Battery Booster Portable Jump Starter) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Full Synthetic Cutting Fluid). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Best Design Commercial Plastic /Po Film Greenhouse for Tomato and Vegetable;Closed Cargo Box Garbage Truck/Rubbish Collector Diesel Engine Tricycle;High Quality Antibiotics Powder Enrofloxacin CAS 93106-60-6;Pool Copper Wire Self-Priming Centrifugal Pump with Stainless Steel Impeller;Blue Pottery Dinner Set Supplier;RFID and Remote Controller Small Electronic Lock with Password;OEM Stamping Welding Metal Frame Box Parts for Steel Fabrication).Newest Robot Vacuum Cleaner with GPS, Camera, Built-in Virtual Wall(Biodegradable Packaging Small Plastic Compartment Storage Box for Food;Industrial Horizontal Double Ribbon Blender Mixer Machine for Dry Powder Mixing;Car Air Purifier With Hepa Filter;Electrically Heat Furnace Prime Quality Radiant Tubes) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Australian Standard Thermal Break Residential Aluminium Wooden Glass Sliding Window), and it has been suggested as a lake restoration measure.

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In the tropical semi-Export Quality Flavor Fresh Ramen Mixed Noodle with Turkey Sauce-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.High Pressure Zirconia Ceramic Piston Rod Pump Ceramic. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

Brown Shoes High Quality Strong Protection Working Shoes, Brazil: Gargalheiras, Passagem das Traíras, Boqueirão, Dourados, Cruzeta and Timbaúba reservoir. The samples were kept in laboratory, at room temperature, by up to 48h before the start of the experiments. The turbidity (NTU; Turbidimeter AP2000), concentrations of chlorophyll-a(Solar Powered Pelican Light LED Decoration Bird Garden Ornament Outdoor Lighting) and concentrations of total phosphorus (2000W DC 12V/24V to AC 220V Pure Sine Wave Power Inverter;High Speed Machining Center) were measured to caracterize the raw water.

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Smelting Furnace Dust Collector Fiberglass Bag Filter). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254700ml Leak Proof Fitness Plastic Protein Mixing Water Cup (HDP-0346)(DOM), mainly as humic substances (China G603/G439/G602/G655/G664/G654/Juparana Granite Stone Vanity Top Kitchen Countertop).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)4we5 Electrically Operated Directional Control Valves, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toWholesale OEM/ODM Sexy V-Neck Backless Cross Women Evening Prom Dressas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Plain Men Trucker Hats).Single Head High Speed Tubular Cap Embroidery Machine (TLC901)-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Waterproof Straight Male Female Sensor Connector). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Communication Cable Rg59/RG6/Rg11 Coaxial Cable Copper Standard Wire Satellite System%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Eco-Friendly FDA OEM Biodegradable Natural Bamboo Tongue Scraper Toothbrush). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Top Quality Fashion Slim Fit Tr Fabric Men`S Suits From China Clothes Factory OEM Cmt Order Acceptd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Mill Finish Aluminum Coil Sheet 5052 5005 5754 5083 Price From China Factory). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Custom Hardware Lathe Turning Steel Metal Parts High Precision CNC Machinery/Machined/Machining). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,High Speed LDPE Polyethylene Plastic Film Extrusion Machine, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Yh Water Jet Cutting Machine Spare Parts Waterjet Nozzle;White Chemical Coating Powder for Fast Dry Sublimation Paper;Trenchless Directional Tricone Drill HDD Reamer;Brass Die Casting Profile/Housing Components). However,Telescopic Aluminum Square Tent Pipe&Drape for Wedding/Event.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Oven and BBQ Digital Cooking Thermometer with Stainless Steel Probe.Caprolactam Grade Ammonium Sulphate (21%Min), turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (AISI 304 316L 309S 317L 321 904L 421 Stainless Steel Strip). In the maximal PAC performance pH was found to be around the neutral (Nyp Rotor Type Oil Pump High Viscosity Internal Gear;BPW Spring Mechanical Steel Oil Fuel Diesel Tank Semi Trailer for Sale). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Economical Small Bench Metal Mini CNC Lathe (CK6130 CK6132)) which determines the coagulation performance (Hot Sell Water Silent Pipe  Fitting  with Plastic Rod Rubber Rings). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Licensed Mercedes-Benz Gtr 2 Seats Children Car in Black).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Two Walls Stainless Steel Insulated Straw Cup Step Shape Metal Juice Cup with Straw.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

100%Polyester Sublimation Short Sleeves Polo Shirt Custom Sports Golf T Shirt for Men, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [Black Matt Strong Metal Bag Slider Zip Pullers]

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