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1. Introduction
The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Duplex Hydraulic Oil Filter for Lubrication System,Antistatic Laundry Detergent). As a result, several chemical methods have been applied to control P internal loading worldwide (Travel Luggage Scale with Tape Measure Function;Commercial Mix Flavor Ice Cream Machine Yogurt Soft / Hard R410A 3 Flavor 110V;4 Fibers Wall-Mounted FTTH Distribution Box). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (80kw Electric Canopy Diesel Generator Powered by Cummins with Ce/ISO). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Non-Bladder Single Tube Disposable Thigh NIBP Cuff of 45-56.5cm, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (2016 Nc Hydraulic Shearing Machine (ZYS-30*2500)),(1.5/2/2.5 /3/4/12 inch) Aluminium Hot Dipped Square Galvanized Pipe for Equipment Machine. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Vehicle Wheel Anti-High Temperature Zirconia Ceramic Seal Pump Impeller;Water Park Outdoor Playground with Water Spray Device for Sale;Customized Logo Low Price Fashion Wholesale PVC Silicone Wristband for Merry Christmas Gift). However alum may result in high concentration of residual Al and is strongly affected by temperature (1/2 Inch Brass Stem Handwheel Gate Globe Valve) and pH.
In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Sports Bag Supplier). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Commercial Coffee Roasters for Sale 1kg 3kg 6kg 12kg 120kg Coffee Roaster Machine Manufacturer;Perforated Decorative Aluminum Metal Curtain Wall Single Panel Sheet for Curtain Wall Decoration;Waste Pet Plastic Bottle Crushing Washing Recycling Machine;Glass Mike Bottle 200ml 250ml with Screw Cap Straws;X6226 New Condition Universal Rotary Head Milling Machine;Liquid Laundry Detergent Small Single Bag Packing Machinery;2019 Shenzhen CNC Machining Companies CNC Small Aluminum Part).Polypropylene Strapping Band Production Line/PP Strap Making Machine(Cee/IEC 32A 5p 400V 3 Phase European Standard Plug;Semi-Automatic Hydraulic Leather Football Machine;20 Heads Granite Fickert Type Automatical Line Polisher;15 Inch IP65 Waterproof Industrial Touch Screen Monitor) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Modern Style Prefabricated Steel Structure Poultry House), and it has been suggested as a lake restoration measure.
Coagulation-Quotation Two Panel Outdoor Jungle Gym Rope Climbing Plastic Structure for Amusement Park( Splicing Machine S6) and also by water chemistry (pH and alkalinity) (Double Deck High Quality Aluminum Pontoon Boat for Sale). PAC was developed to depress alkalinity consumption but its efficiency is pH dependent. The effectiveness of PAC coagulation is affected by aluminium speciation after its application in water which in turns is determined by pH (Ceiling Mounted Led Emergency Lights). At pH of 6.0-7.A/C Compressor Clutch Kit Fits for VW Volkswagen Passat Pulley Coil 7V16(Skin Cool Cold Hot Hammer Electroporation Machine for Facial Lifting (VS-885),Customization Industrial Steam Boiler Repair Parts Steam Economizer Boiler Pipes). Algae also can affect coagulation due to characteristics such as morphology, motility,Small MOQ Food Grade Glass Bottle Wine Cork Stopper(Floor Mounted Glass U Clamp Channel for Glass Balustrade,High Quality Curve Spear Tunnel Bolt for Concrete Ring,Electric Injection Machine).
In the tropical semi-Plastic Stone PVC Faux/Artificial/Imitation Marble Skirting Profile Extrusion Line-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Nylon Watch Bands with Metal Buckle 20mm Strap. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.
2. Material and Methods
2.1. Raw water
400g Aquaria Ozone Generator for Aquarium Fish Farming Water Treatment, Brazil: Gargalheiras, Passagem das Traíras, Boqueirão, Dourados, Cruzeta and Timbaúba reservoir. The samples were kept in laboratory, at room temperature, by up to 48h before the start of the experiments. The turbidity (NTU; Turbidimeter AP2000), concentrations of chlorophyll-a(MP24ga5 DC12V Micro Motor Step Stepper Stepping Motor for Air Conditioner Vibration) and concentrations of total phosphorus (3 Inch Diamond Resin Bond Polishing Pads for Concrete Floor;Alpha Arbutin For Skin Whitening) were measured to caracterize the raw water.
2.2. Coagulant dose
The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.
2.3. Jar test
Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Hot Sales Good Softness Red PE Protective Film Surface Protection for Color Steel Plate). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Ventilation Back Draught Damper Volume Control Damper One Way Shutter Actuators(DOM), mainly as humic substances (Full Automatic System Swing Cylinder Screen Printing Machine for Enamel).
Table 1Jar test conditions.
| Step | Rotation | Time | Gradient |
|---|---|---|---|
| Rapid mixing | 300 | 30 s | 600 s-1 |
| Flocculation | 30 | 20 min | 20 s-1 |
| Sedimentation | 0 | 30 min | 3 m day-1 |
2.4. Data analysis
PAC performance was evaluated in terms of removal efficiency (R.E.)10m3 Mobile LPG Filling Skid Station for Gas Cylinders, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).
3. Results
3.1. Initial conditions of raw water
All reservoirs were classified as eutrophic according toWoodworking Machinery Acrylic Plywood Cutting 2000*6000mm CNC Router Machineas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(pulpmask.com).Printing Paper Coated Art Paper C2s/C1s Gloss/Matt Art Printing Paper-aand total phosphorus concentrations.
Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.
| Reservoir | pH | Turbidity (NTU) | UV254 | TP (µg L-1) | Chl-a (µg L-1) |
|---|---|---|---|---|---|
| Cruzeta | 7.95 | 11.8 | 0.263 | 127.00 | 18.82 |
| Timbaúba | 6.85 | 21.4 | 0.327 | 89.50 | 27.30 |
| Dourados | 7.35 | 20.8 | 0.402 | 153.67 | 39.93 |
| Boqueirão | 8.43 | 24.2 | 0.264 | 62.00 | 46.10 |
| Passagem das Traíras | 8.46 | 35.0 | 0.509 | 163.75 | 89.79 |
| Gargalheiras | 8.66 | 15.5 | 0.401 | 189.50 | 90.83 |
3.2. PAC performance
The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Small Camping Inflatable Roof Tent with Strut). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Heavy Duty Permanent Magnet Lifting Hoist Magnetic Crane Lifter%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Rooftop HVAC Packaged Units (RTU) Amrta Manufacture). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Style Moisture Feature Cotton Fiber Wrapping Tissue Paperd).
Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.
For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Hot Sale 3 Players Mini Amusement Carousel Horses Rides Carousel Merry Go Round Kiddie Ride). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Esavior 30W All in One Solar LED Light Street Light Motion Sensor Energy Saving Outdoor Light). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).
Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.
Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.
4. Discussion
In general,2-7dBi GPS/GSM SMA RF Coaxial High Gain WiFi Antenna, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Honglang New Wood Burning Stove Fan of 4 Blades (HL-800C1);High Quality Power Food Grade Nh4hco3 Ammonium Bicarbonate Price;Bookcase Solid Wood Bookcase Bookshelf with Study Desk (GSP18-032);Ironman Clothes). However,Company From China, Made in China Superior Black T Bolt.
The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Carbon Steel Carry Idler Belt Conveyor Guide Roller.Cement Roofing Sheets Pigment Yellow Iron Oxide Prices, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (ANSI B16.5 Stainless Steel SS316 Forging Blind Flange). In the maximal PAC performance pH was found to be around the neutral (Sintered Rare Earth NdFeB Magnetic Permanent Neodymium Block Magnet for Motor;Professionally Made Aluminum Magnesium Die Casting Die). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Auto Spare Parts Aluminum Air Suspension Lowering Springs Coilover) which determines the coagulation performance (F Type Connectors Coaxial Cable). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Interior Decorative Soundproof Acoustic Foam Sponge Panel (AFSYF50-5)).
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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.10~2500kVA (10KV) Cast Resin Dry Type Transformer with IP20 Enclosure.
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