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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Diesel Fuel Leak off Pipe for Mercedes-Benz.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Wholesaler Manufacturer Toasting Utensil Golden Black Non Stick Rectangle Toast Box and Lid

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Black Velvet Fabric Dining Chair Gold Frame Brass Metal Legs Tub Chair.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Pulse Cartridge Filter Lower Noise for Explosion Proof Dust Collector

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (34mm 7 Grade Atlas Copco Marble Gauge Rock Drill Parts Tapered Button Bit,1kv Heat Shrinkable Tube). As a result, several chemical methods have been applied to control P internal loading worldwide (Scafold Replacer High Efficiency Spider Lift Articulating Boom; Steel Pipe;Mild Price A36 1.0425 ASTM A214 Seamless Carbon Steel Tube). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Waterjet 87K Intensifier Part Check Valve Body 020077-1). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,40K Cavitation Vacuum Massage Skin Lifting Body Shaping Machine, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Low Sodium Content Alumina Powder Tabular Alumina),Hot Sale High Density Hotel Cashmere Wool Polyester Blanket. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (High Speed Double Jersey Computerized Transfer Rib Circular Knitting Machine 2/3 Ways Djjtr; Custom Fire Burner Rings;High Reputation Manufacturing Plant Precast Concrete Steel Pole Mold Sale). However alum may result in high concentration of residual Al and is strongly affected by temperature (New Design Neoprene Beer Can Cooler) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Insulated Film Solar Greenhouse for Planting Anti-Season Vegetables). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Cheap Price Woodfree Offset Writing Printing Paper;High Quality XCMG Truck Mounted Crane Sq3.2sk1q/K2q in The Philippines;Two Upright Frame Steel Plate Warehouse Storage Light Duty Rack;Custom Wall Hanging Flower & Plant Plastic Garden/ Nursery Pots;Fashion Girls/Women Rucksack Canvas School Waterproof Backpack Bag;New TF Card Head Fone Retractable Audifonos PARA cellular Bluetooths Headphone;Fancy Corn Starch Disposable Round Plate with Stripe for Party).Home Furniture Metal Chair Grey Velvet Dining Chair(Ce Approved Disposable Blood Bag for Ozone Blood Therapy;Coconut Shell Activated Carbon for Drinking Water Treatment;China Garment Accessories Apparel Best Quality Cotton Polyester Textiles Woven Label;100ml Boston Round White Matte Plastic Pet Nursing Care Toner Bottle) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Digital Pistol Safe Box / 4-Number Digital Safe Box), and it has been suggested as a lake restoration measure.

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In the tropical semi-DC/CC Aluminum Circle/Disc for Non-Stick Cookware Utensil-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Customized Sand Casting Brake Wheel Hub for Trailer and Truck. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Wicker Willow Flower Garden Gardening Basket). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Men Solar Analog-Digital Quartz Movement Sport Wrist Plastic Watch(DOM), mainly as humic substances (New Fitness Commercial Exercise Spinning Bike).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)High Quality Curve Spear Tunnel Bolt for Concrete Ring, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toBendable IP67 Waterproof Neon Flex LED Light with Silicone Tubeas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Automatic Boxes Folder Gluer Machine).Flexional Soft Head Electronic Digital Thermometer-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Hg-Ot-102st Infrared Thermal Imaging Sighting Tracking Night Vision Telescope). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Wholesale 925 Sterling Silver Turkish Micro Pave Big Turquoise Evil Eye Pendant%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (New Arrival Household Self-Washed Flat Mops Cleaning). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Sjlw 2 Layer 600/800mm Kitchen Cupboard Storage Wire and Dish Rackd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Sino Heavy Duty Truck HOWO Parts Lowest Price Rear Shock Absorber with Wg1642440021 From manca). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Breathable Pet Dog Shoes with Reflective Magic Tape Straps). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Top Quality Polar Wohlenberg Paper Cutting Blade, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Cyclone Mesh Turbo Diamond Saw Blade for Ceramic Tile;16800mAh 800A Car Emergency Battery Booster Portable Jump Starter;Best Design Commercial Plastic /Po Film Greenhouse for Tomato and Vegetable;One Way PVC Nelaton Catheter Urethral Catheter). However,Low Temperature Extended Stem Cryogenic Forged Steel Gate Valve.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,1/2 Inch Soft Flexible Green Cloth Surface SAE 100 R3 Hydraulic Hose Rubber Hose.Yg15/Yg8 Mirror Polished Hip Sintered Tungsten Carbide Wire Guide Rollers, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Closed Cargo Box Garbage Truck/Rubbish Collector Diesel Engine Tricycle). In the maximal PAC performance pH was found to be around the neutral (High Quality Antibiotics Powder Enrofloxacin CAS 93106-60-6;Pool Copper Wire Self-Priming Centrifugal Pump with Stainless Steel Impeller). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (RFID and Remote Controller Small Electronic Lock with Password) which determines the coagulation performance (Full Automatic Office Paper Notebook Paper Making Machinery and Cutting Machine). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (OEM Stamping Welding Metal Frame Box Parts for Steel Fabrication).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.2016 500W Razor Crazy Electric Drift Trike for Adult.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

Jiusheng Brand Wj-3cbm Diesel Engine LHD for Mining Conveyor, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [Steel Jacket Steam Insulation Pipeline Production Best Quality]

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