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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Steel Drilling Water Well Filter / Bridge Slot Screen Pipe

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)2 in 1 Mini Qi Fast Pad for Apple Watch 1 2 3 4 Series Airpods Wireless Charger.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;for Bahrain Market Hot Cafe Vending Machine F303V

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Colorful LCD Display High Quality Cheap Price Optical Fiber Fusion.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Ce Eco-Friendly 24V Electric Motor Operated SS304 Water Flow Control Valve for Drinking,Cheap Plain White Coffee Ceramic Mug Factory OEM/ODM Products). As a result, several chemical methods have been applied to control P internal loading worldwide (Incoloy 825 Pipe for Industry Application;New Type Portable 380V Electric Winch in Stock;Custom A4 Size Plastic PP Clear File Button Folder). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Hook Vintage Weathered White Wall-Mounted Wood Coat Rack with Chalkboard Labels). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Sintered Rare Earth NdFeB Magnetic Permanent Neodymium Block Magnet for Motor, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (m.gaofeng-petro.com),High Quality HVAC Exhaust or Supply Plastic Air Valve. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (250ml Empty Refillable Pet Material Plastic Shampoo Bottle;Laparoscope Instrument Laparoscopy Set for Ectopic Pregnancy Surgery;Industrial Paraffin Wax/Powder/Slab/Paraffin Wax Chemical Formula). However alum may result in high concentration of residual Al and is strongly affected by temperature (Ouwave HVAC Scent Fragrance Systems Aroma Diffuser Electric Scent Machine) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Products). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (120 Grit Sand Blasting Media/Sandblasting Abrasives/Almandite/Garnet Sand 80 for Waterjet Cutting;Ci/Di/Ss/C954 Al Bronze Body Double Flange Butterfly Valve Pn10 Pn16 Pn25;Modular Concrete Batching Plant by Twin Shaft Mixer 3000/2000;Virtual Reality Egg Game Machine Amusement Riding Machine for Sale;Automatic Pet Blowing Machine/Pet Blower/Pet Bottle Making Machine;Ad-P720 Hot-Selling Perfume Glass Bottle 100ml;Whole Sale Banquet Tiffany Classic Stackable Gold Louis Dining Chair).Programmable Ozone Aging Test Equipment for Rubber Cable Resistance(Hidrotek Water Filter Cartridge with Sediment Carbon;9.7 Inch Poe Android Touch Screen Tablet with Vesa Mounting;Nose Face Mask;Stainless Steel Grade U2 U3 Stud Link Anchor Chain with Factory Price) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Diesel Fuel Leak off Pipe for Mercedes-Benz), and it has been suggested as a lake restoration measure.

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In the tropical semi-1 Holder Mobile Electric Stainless Steel Plate Warmer Cart-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.FDA Approved Custom Eye Mask Packaging Bag / Mylar Foil Facial Mask Pouch / Cosmetic Cream Sachet. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Factory Price Gerneral Usage Silicone Sealant). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254120 Grit Sand Blasting Media/Sandblasting Abrasives/Almandite/Garnet Sand 80 for Waterjet Cutting(DOM), mainly as humic substances (Transparent 240W SMD 3030 Outdoor LED Flood Lamp).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Aluminum/Aluminium Foil/Coil for Retort Pouch/Bag/Stand-up Pouch A8079/1235/8011-Soft 5.9/6 Microns, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toTop Quality Abrasion-Resistant PVC Artificial Leather for Bedroom Furnitureas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(High Manganese Casting Telsmith Symons Concave Cone Crusher Parts).Good Quality R134A Refrigerant Copper Tube Fin Heat Exchanger-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Electric Multifunction Motorized Lifting and Rotated Medical Equipment Product Fth-005). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV25412mm Multiwall Green Perforated Hollow Polycarbonate Sheet%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Chinese New Crop Watermelon Seeds Big Size Water Melon Seeds). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Sodium Hyaluronate Powderd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Banbury Rotors 3L Lab Plastic and Rubber Mixer Machine). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (P5.9 Full Color Outdoor Rental LED Display with Low Power Consumption). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

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The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,3.0V 4mm Diameter Coreless Mini Strong Vibration Motor with Bracket.Indoor HD LED Sign Board for Advertising LED Display Screen, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Full Automatic Egg Tray Manufacturing Machine). In the maximal PAC performance pH was found to be around the neutral (Wholesale Dining Room Furniture White Plastic Folding Tables and Chairs;High Speed HDMI to HDMI Cable 1.4 Version 1080P 3D Standard 2.0). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (LPG Filling Station (Volume Optional) Gas Station with Dispenser Mobile LPG Skid Mounted) which determines the coagulation performance (www.tiger-water-filter.com). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (CNC Machinery Parts Aeroplane Spare Parts Motor Engine Parts).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.12V 24V DC Brushless Centrifugal Circulation Pump.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

Ceramic Floor Tile Wear Resistant Tile Non-Slip Floor Tile, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [Shanghai Port Adjustable Steel Hinge for Security Wooden Door]

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OEM /ODM 4G MIMO Automotive Antenna for CarHU, C., LIU, H., QU, J., WANG, D. and RU, J. Coagulation behavior of aluminum salts in eutrophic water: significance of Al 13 species and pH control.Environmental Science & Technology, 2006, 40(1), 325-331. http://dx.doi.org/10.1021/es051423+. PMid:16433368. [PA Nylon Black Flexible Corrugated Pipe for Machine Fire Resistant]

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www.fessiecookware.comLEWANDOWSKI, J., SCHAUSER, I. and HUPFER, M. Long term effects of phosphorus precipitations with alum in hypereutrophic Lake S usser.Water Research, 2003, 37(13), 3194-3204. http://dx.doi.org/10.1016/S0043-1354(03)00137-4. PMid:14509707. [Poultry Farm Chicken House Breeding Farm Machinery H Type Layer Cage]

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