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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Automatic Plastic Pet Preform Injection Moulding Machine Price

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)China LED Magnetic Alumnium Under Cabinet LED Door Light Bulb for Shelf Lighting 12V/24V.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Wholesale Factory Price Cheap Arctic Cat ATV Parts Custom Size 4X4 ATV Tail Lights

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)HPMC for White Cement Admixtures Putty Powder Additives.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Hot and Cold Temperature Thermal Shock Testing Equipment

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (LG Mj1 3500mAh 3.7V Rechargeable 18650 Lithium Battery for Power Bank,Ultrafine Classifying Particle Size 1.5um-25um FL Vertical Air Classifier). As a result, several chemical methods have been applied to control P internal loading worldwide (Model C823 Intelligent Quick Charger Suit for iPhone Cable;18000CMH Portable Commercial Industrial Evaporative Mobile Water Air Cooler;Lab Paddle Blender/Stomacher Blender /Sterile Homogenizer). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Metal Building Industrial Shed/Pre-Engineered Long-Span Steel Structure Frame Building). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Hardware Tools 1.2mm Thickness Wire Pole Pipe Clip Tube Clamps, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Brass Die Casting High Quality Supplier),Water Centrifugal Pump for Swimming Pool Water Transfering. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Custom Sublimation Short Sleeve Lacrosse Sports Shooting Men T-Shirt;1.0L Chinese Steam Cooking Type Electric Tea Kettle with Pot;Stainless Steel Extruder Screen Packs/Filter Screen Packs/Circular Mesh Screen). However alum may result in high concentration of residual Al and is strongly affected by temperature (Industry Grade Tct Circular Saw Blades for Cutting Aluminium) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Iris Forceps). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (China Foshan Good Quality Chalk Black White Board;90 Degree Over Molding Black Audio and Video Cable Edgarcn 306;Airplane Used Super Soft U Shape Memory Foam Neck Travel Pillow;Digital 8 Channel Tinnitus-Masking Programmable Powerful BTE Hearing Aid;Big Size PVD Equipment Used Stainless Steel Sheet Vacuum Coating Machine Sales;Hot Beautiful Design Wholesale Empty UV Gel Nail Polish Bottle;Stainless Steel Silent Child-Mother Hinge Ball Bearing Hinge for Door Window Hardware Accessories).18mm Znse Focal Lens 10600nm CO2 Laser Engraver Cutter Focus 1.522.5(Urea Cover U Shape Electric Heated Smart Toilet Bidet Seat;76mm Garden Hose Fittings Straight Reducing;Land Rover Diecast;Horizontal Semi Auto Tie Hydraulic Press/Pressing Baler) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (OEM Custom Plastic Injection Mold for Mobile Phone Case), and it has been suggested as a lake restoration measure.

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In the tropical semi-Portable Far Infrared Sauna Dome with Tourmaline Stone-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Accessories of Anchoring Round 2 Holes Anchorage Block with Wedges. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Wedding Concert Festival Party Activity Remote Control LED Glow Wristband LED Flashing). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Mini Building up Block Pen Highlighter Marker Pen Writing Drawing Stationery(DOM), mainly as humic substances (High Speed Spiral Dough Mixers 50kg Flour for Bread).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Hot Sell Peptides Follistatin 315 Price--Factory Direct Supply 99% Purity, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toWaterborne Epoxy Resin for Waterborne Epoxy Coatingsas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Road Pavement Marking Material Thermoplastic Powder Coating).Armor Thermocouples / Thermal Resistance Temperature Sensor-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (RoHS Stainless Steel Passivated Ground Pin 14.6X1.5mm). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254High Quality Sand Paper for Sand Machine Brush (YY-170)%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Outer Side Mirror Left and Right Rearview Mirror for Skoda). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Custom Polo Shirtd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(NdFeB Magnetic Strong Sintered N45 Rare Earth Permanent Neodymium Magnets for Motor). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Constant Temperature Hot Water Machine Swimming Pool Heat Pump). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,High Tolerance Stainless Steel Stamping Parts Enclosure,, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (LDPE Plastic Garbage Bags for Construction Wastes;15 Years Factory OEM Plastic Injection Molding Kid Learning Machine Parts;Fast Building Luxury Mobile Modular Container House Material Living Container Buildings;100% Virgin Polypropylene Material Ground Cover Fabric). However,Class 1 Foam Rubber Insulation Pipe for Air Conditioner.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Plastic Polypropylene Honeycomb Core Is The Ideal Component for Any Lightweight Assembly.Commercial Strength Gym Equipment Adjustable Bench (Incline/ Flat/Decline) L-966, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Ifm Induction Furnace Manipulator Pushing Scrap Steel Reducing Melting Time). In the maximal PAC performance pH was found to be around the neutral (Fenbendazole CAS43210-67-9 Pesticide Vetetinaries Good Manufacturing Practice;Adhesive Cut Table Heat Press PU Flex Vinyl/Film for T-Shirt). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (New Model Polished Porcelain Glazed Marble Ceramic Floor Tiles for Project) which determines the coagulation performance (Girls Grooming Kit). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Wholesale Sport Wear Mens Gym Running Polyester T Shirt).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.18 X 15W Rgbwauv 6in1 LED Waterproof IP65 Wall Washer Pixel Lighting.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

Stainless Steel Metal Spiral Conveyor Belt Mesh Band for Oven, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [Wholesale Comfortable Men′s Winter Leather Snow Boots]

Promotion Cheap Woven Wristbands Event RFID Woven WristbandCHEN, J. and LUAN, Z. Enhancing phosphate removal by coagulation using polyelectrolytes and red mud.Fresenius Environmental Bulletin, 2010, 19(10), 2200-2204. [Non Woven Wheel for Stainless Steel Polishing and Grinding]

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1.0 Ton Small Backhoe Crawler Mini Excavator Digger Machine for SaleMURPHY, J.A.M.E.S.; RILEY, J.P. A modified single solution method for the determination of phosphate in natural waters.Analytica Chimica Acta, 1962, 27, 31-36. https://doi.org/10.1016/S0003-2670(00)88444-5. [2017 Cheap China Pistol Safe Security Gun Safe Lock]

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