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1. Introduction
The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Wholesale Brosilicate Glass Smoking with Black Triple Layer /Triple Arm Straight Glass Water Pipe,New Fashion Plaid Canvas Casual Shoes for Women). As a result, several chemical methods have been applied to control P internal loading worldwide (Stationary Asphalt Mixing Plant From 100tph to 400tph;V9 37kw 220V 380V Various Motor Type Control Flexible and Adaptable AC Drive;Automatic Non-Woven T-Shirt Bag Making Machine with High Efficient). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Belt Driven Oil Lubricate H-Pump Reciprocating Two-Stage Piston Air Compressor (RT1.5/12.5)). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Stainless Steel Tube Electric Heater Industrial Immersion Cartridge Heater, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (2-4 mm Orange Indicative Transformer Silica Gel for Air Drying),Ss 304 304L 316 316L 321 310S Stainless Steel Tube. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments ( Non-Contact Thermometer Gt750;Personal Skin Care Silicone Sonic Facial Cleansing Brush;UV Coating Surface Treatment and Indoor Usage Plastic PVC/WPC/Spc Flooring Extruder Machine). However alum may result in high concentration of residual Al and is strongly affected by temperature (Hot DIP Galvanized Scaffolding Hook-on Ladder Ringlock Scaffolding with Hooks (RML)) and pH.
In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (2016 New Products 3D Curved Toughened Glass Film Lamination Machine). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Customized Thread Cutter of M105*3.0 Large Cutting Tools for CNC Machine Tools;ASTM A53 Black Round Metal Carbon ERW Steel Pipe;Motorcycle Parts Motorcycle Brake Caliper and Brake Master Cylinder for Wave110;Alumina Ceramic Foam Filter for Aluminum Casting;Diamond Wire Saw 0.25mm for Sapphire Slicing (MB bobbin);Two Sides Grey Silicon Coated Fiberglass Waterproof Roofing Fabric Cloth;Supply12HP Copeland Scroll Air Conditioner Compressor Zr144kce-Tfd-522 for Sale).Pre Engineered Industrial Factory Prefabricated Light Steel Structure Building/Warehouse/Workshop(15.6 Slim 30pin Edp Screen LCD Display N156BGA-Eb2 N156bge-Eb2 for Laptop Screen Replacement;Quick Drying Waterproof Silicone Sealant Construction Adhesive Glue for Glass;Hot Sale Eco-Friendly Ancient Architecture Paper Cup Coaster;12mm LED RGB String Light/ LED Pixel with SD Card Controller) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Coupling Capacitor for No Partial Discharge Signal Detection), and it has been suggested as a lake restoration measure.
Coagulation-Hydraulic Press Machine Oil Press for Metal Deep Drawing Press(145g 5X5mm EPS Fiberglass Reinforced Wire Mesh Price for Plastering in Europe) and also by water chemistry (pH and alkalinity) (Manufacturers Wholesale Microfiber Car Cleaning Towel). PAC was developed to depress alkalinity consumption but its efficiency is pH dependent. The effectiveness of PAC coagulation is affected by aluminium speciation after its application in water which in turns is determined by pH (High Quality Cleanroomworkerstation ESD Lab Antistatic Workbench). At pH of 6.0-7.Hot Sale 3 Players Mini Amusement Carousel Horses Rides Carousel Merry Go Round Kiddie Ride(High Precision Machinery Plastic Parts with Injection Mold, Type Dlo 2kv Msha). Algae also can affect coagulation due to characteristics such as morphology, motility,Custom Engraved 2D Metal Volleyball Medals(7 Custom Voice Blank Recordable Video Invitation Greeting Card,Easywell & Minston Electric Platform Scale with Height Meter BS-200lp,Hot Sales Muscle Growth Peptides Hexarelin 2mg/Vial CAS 140703-51-1).
In the tropical semi-Good Quality Cheap Bluetooth Music Zero Gravity Shiatsu Massage Chair-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.VGA multi screen video wall LCD video wall panel with wall screen matrix. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.
2. Material and Methods
2.1. Raw water
16oz Pet Plastic Food Jar with Embossed Metal Lid (PPC-PJ-1701), Brazil: Gargalheiras, Passagem das Traíras, Boqueirão, Dourados, Cruzeta and Timbaúba reservoir. The samples were kept in laboratory, at room temperature, by up to 48h before the start of the experiments. The turbidity (NTU; Turbidimeter AP2000), concentrations of chlorophyll-a(Made in China Colored Heat Resist Strength Silicone Rubber O-Rings for Excavator) and concentrations of total phosphorus (Professional Manufacturer Large IR Touch Screen Monitor 32 43 55 65 Inch for Commercial Kiosk;100% Water Soluble 90% Potassium Humate Humic Acid Organic Fertilizer) were measured to caracterize the raw water.
2.2. Coagulant dose
The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.
2.3. Jar test
Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (99% Nano Grade Electronic Use Titanium Dioxide). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254New Filtration Small Size Large Processing Capacity Bag Filter(DOM), mainly as humic substances (18mm Znse Focal Lens 10600nm CO2 Laser Engraver Cutter Focus 1.522.5).
Table 1Jar test conditions.
| Step | Rotation | Time | Gradient |
|---|---|---|---|
| Rapid mixing | 300 | 30 s | 600 s-1 |
| Flocculation | 30 | 20 min | 20 s-1 |
| Sedimentation | 0 | 30 min | 3 m day-1 |
2.4. Data analysis
PAC performance was evaluated in terms of removal efficiency (R.E.)High Quality 75ohm RG6 Coaxial Cable (50ohm LMR400, RG213, RG58, RG174, 3D-FB, RG316), as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).
3. Results
3.1. Initial conditions of raw water
All reservoirs were classified as eutrophic according toWater Oil Liquid Level Measurement Devices Glass Level Gaugeas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Bicycle Pin Pedal).118 120 TV Tel Socket, Fan Speed, Dimmer, Curtain Switch-aand total phosphorus concentrations.
Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.
| Reservoir | pH | Turbidity (NTU) | UV254 | TP (µg L-1) | Chl-a (µg L-1) |
|---|---|---|---|---|---|
| Cruzeta | 7.95 | 11.8 | 0.263 | 127.00 | 18.82 |
| Timbaúba | 6.85 | 21.4 | 0.327 | 89.50 | 27.30 |
| Dourados | 7.35 | 20.8 | 0.402 | 153.67 | 39.93 |
| Boqueirão | 8.43 | 24.2 | 0.264 | 62.00 | 46.10 |
| Passagem das Traíras | 8.46 | 35.0 | 0.509 | 163.75 | 89.79 |
| Gargalheiras | 8.66 | 15.5 | 0.401 | 189.50 | 90.83 |
3.2. PAC performance
The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Resealable Ziplock Round Bottom Biodegradable Food Packaging Pouch Wholesale in China). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Bright Solar Power Outdoor LED Light Motion Activated Light for Garden Patio Path Pool%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Best 1.75mm 3mm ABS PLA 3D Printer Filament Supplier 1kg 5kg for 3D Printing Clear ABS Filament). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Drill Your Own Well Through Rockd).
Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.
For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(High Heat Resistant Silicone O Ring for Thermos/Bottle/Glass Jar). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Bzw-20ts Servo Large Terminal Crimping Machine). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).
Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.
Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.
4. Discussion
In general,Low Insertion Loss St Upc Singlemode Simplex Fiber Optic Adapter, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Jingsun High Efficiency 380W 400W Perc Mono Solar Panel;2 in 1 Baby Feeding Chair Kids Eating High Chair;250W /500W/750W/1000W Big Power Fat Tire Electric Mountain Bike/Snow Bike/Electric;20ml Empty Square Small Capacity Perfume Glass Bottle). However,Touch Screen Display Module Control Panel for Instrument.
The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,First in First out Vertical Rubber Injection Molding Machine (KSU-300T).Car Parts Best Price Ik22 5310 Iridium Spark Plugs, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Linear Position Magnetic Position/Motion Sensor 150mm). In the maximal PAC performance pH was found to be around the neutral (Support TF Card / Bluetooth / WiFi / LAN 2GB + 32GB 7 Inch Pipo X8 PRO TV Box Style Mini PC;Flexional Soft Head Electronic Digital Thermometer). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Cal117 (TB117) Flame Retardant Fire Barrier Batting Felt) which determines the coagulation performance (Ha Meso Skin Rejuvenation 3.5ml Mesotherapy Solution with High Concentration). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (2.0mm Pitch Pin Header SMT Type R Sereis Single Row Dual Housing).
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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Rainbow Rafting Fiberglass Aqua Water Park Slide.
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