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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Popular Classic Design Old Style Vintage Leather Chesterfield Sectional Sofa

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)12oz Dispossable Ripple Wall Paper Cup with Good Insulation.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Plastic Roofing, Residential Building of Clear Fiberglass Panels

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Factory Price 1100 Aluminum Disc Discs Circle Round Plate.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Temperature and Humidity Controller with 5 to 95%Rh (XMT-9007-8)

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Dezhou China PLD Commercial Fitness Equipment Rearl Delt/Pec Fly Machine Gym Equipment,Multi-Function Small Tree Digging Shovel/Tree Machine). As a result, several chemical methods have been applied to control P internal loading worldwide (Cheap Soccer Game Table Foldable Football Table with L Shape Leg;Competitive Price Corrugated Tubing with Braid Layer;Air Ventilator Fan Exhaust Fiberglass Cooling Fan Manufacturer). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Puffed Food Automatic Vertical Packing Machine). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Makeup Case Toiletry Bag for Women Skincare Cosmetic Pouch, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (201 304 316 430 Inox Profile Tube Hollow Section Stainless Steel Square Tube),Home Kitchen Appliance Digital Ozone Generator for Air Water Purifier. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments ( Customized Fancy Printing Adhesive Paper Label Sticker;TXWF-110-2L 5V -24V DC Brushless Axial Stand Cooling Alarm Fan Motor;A76 Nordic Living Room Dining Room Furniture). However alum may result in high concentration of residual Al and is strongly affected by temperature (Custom-Made Wild Bluebell Cologne Spray Perfume in Crystal Glass Bottle 30ml for Body) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Dmaa Powder). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Aluminum/Aluminium Sliding Doors Philippines Price and Design System;90ml Cool Designer Perfume Glass Bottle with Surlyn Cap;Stainless Steel DIN1587 Hex Domed Cap Nut for Car/Motor/Bicycle;Fr-218 BOPP Packing Tape Slitting Rewinding Machine;Aluminum Manual Car Truck Gear Stick Shift Knob;Animal Husbandry Equipment Cattle Farm Equipment Cattle Cow Headlock;Farming Tractor Wheel Loader Tl2500 Cow Dairy Agricultural Tractor Loader Machinery).BPW Spring Mechanical Steel Oil Fuel Diesel Tank Semi Trailer for Sale(Qr Code Watch Mobile Phone Case Deep Fiber Laser Marking Engraving Machine for Metal;Soybean Quick Freezing Production Line/Vegetable IQF Freezing Production Line;Car Creeper High Quality Supplier;Microfiber Cleaning Cloth Towel Waffle Towel Tea Towel) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Free-Maintenance Motor Design White Light PTZ Security Cameras), and it has been suggested as a lake restoration measure.

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In the tropical semi-PU Foam Plastic Squishy Slow Rising Toy for Unicorn-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.GRP FRP Fiberglass Composite Epoxy Resin Water Treatment Pipe Tube Cylinder. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Custom Logo Ceramic Tea Cup Porcelain Coffee Mug of Bd002). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Nylon Kitchen Tools Set Cutlery Set with Stainless Steel Kitchen Set(DOM), mainly as humic substances (Made in China High Quality Ceramic Fiber Packing Seal Ring).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Flanged Bolted Bonnet Cast Steel Swing Check Valve Supplier, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according to Straineras they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Medical Product Standard Endotracheal Tube).Galvanized Steel Air Pipe Ventilation Duct Tube-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Custom Printed Luxury Black Paper Gift Carry Shopping Packaging Bag). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV25412mm 15mm18mm Pet PP Granules Strap Band Winder Machine Extruder Machine Price%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Newest 2′′ IPS Display Mini Dash Cam FHD1080p with 2.5D Glass Lens). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (No1 No8 8K Cold Rolled 904L Stainless Steel Plated).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Healthcare Product Compression Wrap Thigh Hip Brace Groin Support Brace). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Stainless Steel Metal Spiral Conveyor Belt Mesh Band for Oven). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Wholesale Wooden Inlay Shell Custom Boutique Comb, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Low-Cost Tree Stump Crushing Machine with Widely Using;Plant Stands & Accessories Glass Hanging Flower Pot Bracket;Seamless Circular/Square/Rectangular Steel Tube;61820tn1 Bearing). However,150ml Plastic Cosmetic Cream Jar with Label Made in Yuyao.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Littlefuse IC Fuse Cartridge Ceramic Electronic Component Nanosmdc012f-2.High Quality 7.5W Fast Wireless Charging Pad for Smart Phones, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Foldable Full Suspension 250W Mini Pocket 20 Inch Wheel Electric Bike / Jb-Tdn05z). In the maximal PAC performance pH was found to be around the neutral (Lightweight New Design Girl Fashion Bags Children School Backpack;Humidifier Aroma Diffuser USB Portable Car Humidifier Air Humidifier). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (New 2 Ton Gasoline/LPG Dual Fuel Forklift Truck Price) which determines the coagulation performance (Customized Furniture Accessories Adjustable Aluminium Gas Spring Table Leg for Standing Desk). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Round 10W LED CCT Tuneable Dimmable Down Lights).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Custom Running Sport Metal Medal by Soft Enamel.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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Customizable High Quality Q38 Series of Catenary Shot Blasting Machine, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [China Manufacturer Aluminium Oxide Abrasive Metal Grinding Polish Cutting Disc Wheel for Grinder]

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Jeans Cap/HatLEWANDOWSKI, J., SCHAUSER, I. and HUPFER, M. Long term effects of phosphorus precipitations with alum in hypereutrophic Lake S usser.Water Research, 2003, 37(13), 3194-3204. http://dx.doi.org/10.1016/S0043-1354(03)00137-4. PMid:14509707. [Prefab Multifunctional Steel Structureg for Wholesales Construction Material]

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