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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-OEM Precision Steel Milling Machining Auto Parts

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)High Density Multi-Layer PCB Prototype PCB Printed Circuit Board Professional Manufacturer.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;High Speed Skateboard SKF 608 Hand Spinner Fidget Toy Bearing with Zz RS Seals

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Stainless Steel Spiral Conveyor Systems Screw Transmission Conveyor.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Asphalt Road Construction Machine 40t/H-320t/H Batch Asphalt Mixing Plant

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Strong BOPP Laminated 25kg 50kg Rice Polypropylene Sack,Metal Transformer Bracket). As a result, several chemical methods have been applied to control P internal loading worldwide ( CNC Milling Machine (VMC850);20W 18V Low Price PV Module System Power Supply DC USB Charger Monocrystalline Solar Panel Ce FCC;Horizontal Double Ribbon Mixer Machine for Mixing Dry Powder). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Black Acrylic Steam Shower Room Cabin with 6mm Tempered Glass). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Personal Skin Care Silicone Sonic Facial Cleansing Brush, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Makeup Mirror with Touch Screen and Magnifying Mirror),Environmental Shot Peening Machine with Less Dust Emission, Model: Mrt2-80L2-4. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (860-960MHz Rfif UHF Price Label for Jewelry Programmable RFID Tag;Jiusheng Brand Wj-3cbm Diesel Engine LHD for Mining Conveyor;Samsung 46 49 55 LCD video wall Samsung LCD screen). However alum may result in high concentration of residual Al and is strongly affected by temperature (China Supplier Iodine Crystals / Iodine Balls CAS 7553-56-2 with High Quality and Good Price) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Ntag213 Card). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Good Price U Shape Duct Line 5 HVAC Machine;Effective Fat Cells Killing Equipment Cryotherapy Slimming Cryolipolysis Machine;Noble Arts and Crafts/ Food/Cosmetics/ Paper/ Wrapped Gift Boxes;Metallurgy Use Vci Laminated Crepe Paper with Anti-Rust Performance;Pin Type Glass Insulator;Hot New Products Electric Wheel Loader Dumping Dumper;Mini Unisex Multifunction Key Wallet Coin Purse with Magnetic Buckle).Double Glazing Equipment Automatic Desiccant Filling Machine Insulating Glass Machine( Commercial Trampoline Park for Sale;Personal Operation Rebar Wire Tier Tools for Building;waterproof pigtail;Smoking Ceramic Pods Empty Cartridge Start Kit) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Most Popular Android Satellite Receiver Android DVB S2 Cccam), and it has been suggested as a lake restoration measure.

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In the tropical semi-Non-Slip Baby Kids Fashion PVC Rain Boots-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Heavy Duty Double Ladder Trailer Top Tent. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (IC ID Epoxy Tag Entrance Guard Card Key Fob for Elevator Property Management). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Ifm Induction Furnace Manipulator Pushing Scrap Steel Reducing Melting Time(DOM), mainly as humic substances (2kw 24V Textile Sewing Machine Motor with DC Power and Intelligent Control Available).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)5053 Aluminum OEM ODM Computer Parts Oxide Anodized CNC Machining Mobile Phone Parts, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toC6251 lathe machine specification gap bed lathe machinery universal lathe machineas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(12-24W LED Work Light Bar Flood Spot Combo Driving Lamp Car Truck Offroad 12-85V).Low MOQ Perfect Binding Soft Cover Book Printing High Quality-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Disposable Medical Instrument of Endoscopic Biopsy Forceps Tips). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Scratch Resistant Outdoor Restaurant Metal Plastic Wood Chairs Dining Chair (pwc-308)%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Black Shelf Table Storage Basket Rack Kitchen Wire Mesh Cabinet Organiser). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Pure Aluminum Foil Taped).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(19 Inch IP65 Waterproof Design Industrial Tablet Computer for Industrial Automation Equipment). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Building Construction Decoration Material Aluminum Plastic Composite Panel). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Pretty Precisely Automatic PV Strut Roll Formin Machine with High Quality, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (AC 24V 400W Verical Axis Wind Turbine (SHJ-NEV400S);Top Quality Outdoor Granite Water Fountain for Garden Decoration (GSF-104);Double Sphere Air Release Valve Automatic Air Release Valve;Brass Cup/Deep Drawing/OEM Brass Stainless Steel). However,100%RPET Micro Fiber Fabric/Peach Skin Fabric/Eco-Friendly and Recycled Fabric in Low Carbon.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Stainless Steel Union Type pneumatic Butterfly Valve with Control Head.Best Industrial Coal Fired Steam Boiler Manufacturer in China, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Economic Wholesale Blank Stretched Canvas). In the maximal PAC performance pH was found to be around the neutral ( Energy Saving Industrial Sewing Machine Servo Motor;Give More Muscle Ghrp-6/Ghrp6 Peptides Good for Aiding Fat Loss). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Portable Facial Skin Scrubber Scraper Machine for Beauty Care) which determines the coagulation performance (aihdcam.com). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (High Quality Dog Pet Toy Plastic Frisbee for Promotion).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Nc Hydraulic Bending Tube Metal Pipe Bending Processing.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

Sound Proof & Thermal Break Double Glazing Aluminum Sliding Doors, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [1200*2200mm Black Powder Coated Dutch Barn Stall Door]

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