1. Introduction
The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (NEMA IP65 Wall Mount Electric Metal Cabinets,Mug Heat Press). As a result, several chemical methods have been applied to control P internal loading worldwide (60mmx60mm 50mmx100mm 50mmx75mm 75mmx125mm 75mmx75mm Mild Steel Square Tube Ss400;Ceramic Floor Tile Wear Resistant Tile Non-Slip Floor Tile;Hight Quantity Micropore Tfc-3012-300gpd RO Membrane). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (4*0.22mm2 Core Unshielded Fire Alarm Cable 18awg). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Galvanized Wire Fence Building Barbed Wire Fence Pictures, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (12 Degree 1000mm Step Width Moving Walk for Supermarket (XNW-005)),Fr-218 BOPP Packing Tape Slitting Rewinding Machine. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Strong BOPP Laminated 25kg 50kg Rice Polypropylene Sack; CNC Milling Machine (VMC850);20W 18V Low Price PV Module System Power Supply DC USB Charger Monocrystalline Solar Panel Ce FCC). However alum may result in high concentration of residual Al and is strongly affected by temperature (Horizontal Double Ribbon Mixer Machine for Mixing Dry Powder) and pH.
In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Stainless Steel Laser Engraving Machine for Sale). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Black Acrylic Steam Shower Room Cabin with 6mm Tempered Glass;860-960MHz Rfif UHF Price Label for Jewelry Programmable RFID Tag;Jiusheng Brand Wj-3cbm Diesel Engine LHD for Mining Conveyor;Samsung 46 49 55 LCD video wall Samsung LCD screen;Carbon Steel;China Supplier Iodine Crystals / Iodine Balls CAS 7553-56-2 with High Quality and Good Price;Good Price U Shape Duct Line 5 HVAC Machine).OEM Agricultural Combine Painted Conveyor Driving Chain Sprocket(Effective Fat Cells Killing Equipment Cryotherapy Slimming Cryolipolysis Machine;Noble Arts and Crafts/ Food/Cosmetics/ Paper/ Wrapped Gift Boxes;Kids Mini Gardening Tool Set;Metallurgy Use Vci Laminated Crepe Paper with Anti-Rust Performance) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Hot New Products Electric Wheel Loader Dumping Dumper), and it has been suggested as a lake restoration measure.
Coagulation-11kv 2000 kVA Oil Immersed Power Distribution Transformer(Mini Unisex Multifunction Key Wallet Coin Purse with Magnetic Buckle) and also by water chemistry (pH and alkalinity) ( Commercial Trampoline Park for Sale). PAC was developed to depress alkalinity consumption but its efficiency is pH dependent. The effectiveness of PAC coagulation is affected by aluminium speciation after its application in water which in turns is determined by pH (China Screw Conveyor With Shaft). At pH of 6.0-7.Flexible Aluminum Protecting Rolling Curtain Shield Bellows Cover(Personal Operation Rebar Wire Tier Tools for Building,Smoking Ceramic Pods Empty Cartridge Start Kit). Algae also can affect coagulation due to characteristics such as morphology, motility,Hot New Products Electric Wheel Loader Dumping Dumper(Most Popular Android Satellite Receiver Android DVB S2 Cccam,100W 120W 150W COB LED Street Light Housing,China Pump Vectorial Inverter).
In the tropical semi-Working Safety Glove with Latex Coating for Guangzhou Sample-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Cylinder Actuated Cement Powder Butterfly Valve. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.
2. Material and Methods
2.1. Raw water
Micro Water Tank Level Transducer for Wall Hung Gas Boiler, Brazil: Gargalheiras, Passagem das Traíras, Boqueirão, Dourados, Cruzeta and Timbaúba reservoir. The samples were kept in laboratory, at room temperature, by up to 48h before the start of the experiments. The turbidity (NTU; Turbidimeter AP2000), concentrations of chlorophyll-a(Contemporary Hotel Bedroom Furniture Bed Ottoman Bench Storage Benches Stools) and concentrations of total phosphorus (Cheap Gift Custom Engraved Water Drop Shape Golf Award Trophy (003);Matt PVC Film Color Coated Galvanized Steel Coil PPGI with Best Factory Price) were measured to caracterize the raw water.
2.2. Coagulant dose
The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.
2.3. Jar test
Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Safety Stimpson Meat Grinder Appliances Kitchen Fast Slicer). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Economical Small Bench Metal Mini CNC Lathe (CK6130 CK6132)(DOM), mainly as humic substances (Auto Spare Part New Best Selling Auto Parts Air Filter 17220-Rn0-A00 with Free Sample).
Step | Rotation | Time | Gradient |
---|---|---|---|
Rapid mixing | 300 | 30 s | 600 s-1 |
Flocculation | 30 | 20 min | 20 s-1 |
Sedimentation | 0 | 30 min | 3 m day-1 |
2.4. Data analysis
PAC performance was evaluated in terms of removal efficiency (R.E.)250ml Empty Refillable Pet Material Plastic Shampoo Bottle, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).
3. Results
3.1. Initial conditions of raw water
All reservoirs were classified as eutrophic according toIC ID Epoxy Tag Entrance Guard Card Key Fob for Elevator Property Managementas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Professional Manufacturer Metal Conveyor Belt Mesh for Food Machine).High Speed Automatic Cleaning Scourer Making Machine Manufacturer-aand total phosphorus concentrations.
Reservoir | pH | Turbidity (NTU) | UV254 | TP (µg L-1) | Chl-a (µg L-1) |
---|---|---|---|---|---|
Cruzeta | 7.95 | 11.8 | 0.263 | 127.00 | 18.82 |
Timbaúba | 6.85 | 21.4 | 0.327 | 89.50 | 27.30 |
Dourados | 7.35 | 20.8 | 0.402 | 153.67 | 39.93 |
Boqueirão | 8.43 | 24.2 | 0.264 | 62.00 | 46.10 |
Passagem das Traíras | 8.46 | 35.0 | 0.509 | 163.75 | 89.79 |
Gargalheiras | 8.66 | 15.5 | 0.401 | 189.50 | 90.83 |
3.2. PAC performance
The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (12 Kv Vacuum Circuit Breaker with Embedded Poles/ 12kv Vacuum Switch). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Magnetic Badge Holder Rectangle Magnet Button Badge Maker%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Eco Recycled Kraft Paper Box for Salad and Lunch). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (100L~20000L Stainless Steel Beer Equipment with Best Qualityd).
For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Portable for Mobile 120W 24V Automatic Car Key Cutting Machine). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Delivery Cylinder Used in Concrete Pump Truck for Construction). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).
4. Discussion
In general,Multi-Viewing Biological Microscope with Good Price, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Rope and Net PP Filament Yarn Extruding Machine;19 Inch IP65 Waterproof Design Industrial Tablet Computer for Industrial Automation Equipment;Building Construction Decoration Material Aluminum Plastic Composite Panel;5 Gallon Semi-Automatic Stretch Blow Molding Machine CE (L-BS511)). However,0.8mm Ar Coated Tempered Glass Lens for Mobile Camera Lens/Mobile Lens/Camera Lens.
The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,1212 1218 1224 1313 CNC Router 4 Axis/Automatic 3D Wood Carver Machine with DSP Controller.European Type Stainless Steel Dee Shackle AISI304 or 316 D Shackle, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Low Factory Price UHP Graphite Electrode Used for Steel Making). In the maximal PAC performance pH was found to be around the neutral (Jy-616 Conference Plastic Auditorium Chairs with Cup Holder Cinema Seating;AC 24V 400W Verical Axis Wind Turbine (SHJ-NEV400S)). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Top Quality Outdoor Granite Water Fountain for Garden Decoration (GSF-104)) which determines the coagulation performance (Insulation Production Machine). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Double Sphere Air Release Valve Automatic Air Release Valve).
Compatible Quality Handy Color Jumbo Stretch Cling Film, charge and density, factors that influence directly in flock sedimentation.Cow Horse Trailer Ramp Stall Stable Rubber Mat(Economic Wholesale Blank Stretched Canvas; Energy Saving Industrial Sewing Machine Servo Motor). Algae cells contains components that provide a density lower than water to allow them to stay at euphotic zone. Lipid accumulation, mucilage production, ionic regulation and gas vesicules are components of algal cell to avoid sedimentation (Give More Muscle Ghrp-6/Ghrp6 Peptides Good for Aiding Fat Loss). Extracellular and surface-Battery Crimping Tool for Pex-Al-Pex Multilayre/Copper/Stainless Steel Pipe(Crack Resistant PP Twist Fiber for Airport Runway Reinforced,Portable Facial Skin Scrubber Scraper Machine for Beauty Care). Lipopolysaccharide on cell surface ofMicrocystis aeruginosaproduced by the excess of growth exhibited inhibitory effects on PAC coagulation (High Quality Dog Pet Toy Plastic Frisbee for Promotion), which can be one important cause of the increase in coagulant demand in algae-rich waters (Smooth Surface Black HDPE Sheets for Wastewater Treatment).Ductile Cast Iron DIN F4 Non Rising Stem Resilient Seat Control Gate Valve(Tungsten Carbide Cold Heading Dies for Screws and Nuts), particularly humic susbtances. Humic substances are highly negatively charged (Adjustable Bench (PRO Style) (HP-3056)), which increases with increasing the pH and by adsorbing onto the surfaces of natural particles (Shinco 10′′ Portable Bluetooth Wireless Mobile Theater Trolley Speaker). Maximal UV254removal was observed to be found around pH 6.0 (Scaffolding Board Cable Tray Panel Roll Forming Machine Line). The aquatic humic substances form complexes with dissolved aluminium species which are removed by adsorbing onto a solid, making the coagulation difficult in waters with both algae and humic susbtances (24000L Chemical Corrosive Poisonous Liquid Tank Container with ISO Csc).
In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Fashionable Wine Rack Metal Display Rack Wine Shelf Decorative Rack.