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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Fiberglass Grating, Glassfiber Molded Grating, FRP Pultruded Grating, GRP Grating.

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Eddy Type Vegetable Washing Machine Bubble Washing Machine with Ozone.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Black Matt Strong Metal Bag Slider Zip Pullers, Professional Custom Engraved Logo Metal Zipper Pull

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Flexible Parameter 48V 300A Controller for 3kw, Customized Available.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Dart Extrusion Machinery Making Twin Screw Extruder

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (18 Inches Double Shafts Driving Xk-450 Rubber Rolling Mill,Immersion Gold PCB for GPS Tracking Module with Green Solder Mask). As a result, several chemical methods have been applied to control P internal loading worldwide (High Drying Efficiency Wood Sawdust Dryer for Sale;Exported Screw Eye Ground Anchor for Electric Fence Using;Contemporary Outdoor Garden Furniture Rattan Wicker Leisure Balcony Sets with Round Bed). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Ex-Proof Motorized Flange End Ball Valve (PQ9B41F-300Lb)). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Australia Rcm Testing and Certification Service for Power Adapter, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (High Quality Luxury Customized Craft Gift Carry Shopping Brown Kraft Paper Bag),Livestock Equipment Dairy Farm Panel Use Cattle Cow Headlock. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Premium Genuine Leather Miyota Mechanical Movement Women Watch with Date;(1.5/2/2.5 /3/4/12 inch) Aluminium Hot Dipped Square Galvanized Pipe for Equipment Machine;New Design Export Fiberglass Adult Water Bike for Sale). However alum may result in high concentration of residual Al and is strongly affected by temperature (Permanent Magnetic Grid for Europe Market) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Sewing Thread Paper Tube Making Machine). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Vibratory Finishing Polishing Machine for Aluminum Brass Metal Steel Parts;Gfd1550-E EDFA Optical Amplifier / 1550nm Erbium Doped Fiber Amplifier;Uncoated Test Liner Fluting Medium Paper for Box Packaging;Carpet Grain UV Coating Eco-Friendly Fireproof Waterproof Spc Flooring1871;Custom Rf Isolator;10m 3.5mm Male to Female Audio Cable for iPhone iPod;Plumbing Fitting Water Connect Black Surface 1/2 Malleable Iron Flat Seat Conical Union).Shoe Mold Metal Engraving Milling CNC Mould Making Machine(Stainless Steel Male Female Screw Fasteners Connecting Book Screws;Reusable 90 Degree Elbow Spherical Seal Hydraulic Female Hose Fitting 20191;m.bmspd.com;Multipurpose Rutile Titanium Dioxide TiO2 Pigment) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Contemporary Art Modern Wall Decor Giclee Artwork 3 Piece Canvas Print), and it has been suggested as a lake restoration measure.

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In the tropical semi-Amazing Quality Oil Wax PU PVC Synthetic Leather for Sofa (898#)-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.10L Diesel/Fuel Injector Industrial Ultrasonic Cleaning Machine. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Antique Bronze Household Furniture Cupboard Shutter Drawer Knobs Pulls Handle). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Light Blue Color Glass Drink Bottle for Beer(DOM), mainly as humic substances (Mt-5113s Digital Textile Sublimation Inkjet Printer Solvent Printer for Transfer Paper Wood).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Complete Wood Pellet Line Sawdust/Straw/Biomass Pellet Plant, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toCheaper Polyester Cord Strap Factory Made in Chinaas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Ultrasonic Flow Meter).Stainless Steel Sanitary Pipeline Three-Stage Emulsion Mixing Pump-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Special Flower Shaped Sterling Silver Cubic Zirconia Earring for Lady Wedding Gift). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254100W 120W 150W COB LED Street Light Housing%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (CNC Machining Part CNC Turning Stainless Steel Parts Aluminum CNC Milling). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Singelmode Simplex St Fiber Optic Adapter/Couplerd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Three Layers ABC Co-Extrusion PP Film Blowing Machine). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Aluminium Silver Lifter 230kg Suction Heavy Duty Suction Cup Hand Tool for Glass). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,15 Years Factory OEM Plastic Injection Molding Kid Learning Machine Parts, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (High Polished Solid Egypt Sunny Beige Marble Columns;Multi-Functional Universal Mount LED Brake/Turn/Tail Lights;Natural Color of 100% 7A Malaysian Human Hair;G5 Beauty Machine). However,Air Bubble Stone as Ozone Diffuser for Air Pump.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Solar PV Detached 30W 12inch Roof Mount Solar Ventilation Attic Vent (SN2014003).Purity Veterinary Pharma Grade Albendazole with Competitive Price, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (49 Electric/Electrical Synchronous AC Gear Motor for Stage Light/Oven). In the maximal PAC performance pH was found to be around the neutral (New Design Brass IP68 LED Underwater Fountain Light;Plastic Nozzle 360 Rotary Kitchen Faucet Shower Head Economizer). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (China Supplier Seamless Carbon Steel Pipe for Motorcycle Parts with 1010) which determines the coagulation performance (Jacquard Machine Needle). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (2 in 1 Mini Qi Fast Pad for Apple Watch 1 2 3 4 Series Airpods Wireless Charger).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Comfortable and Soft Cat Pet Bed Pet Supplies Mini House for Cat.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

Standard Vertical Rotary Automated Smart Tower Car Parking System, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [LED Car Work Light of 51W 6inch with off-Road Spot Beam]

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hnachinaEGEMOSE, S., DE VICENTE, I., REITZEL, K., FLINDT, M.R., ANDERSEN, F.Ø., LAURIDSEN, T.L., SØNDERGAARD, M., JEPPESEN, E., JENSEN, H.S. and PRAIRIE, Y. Changed cycling of P, N, Si, and DOC in Danish Lake Nordborg after aluminum treatment.Canadian Journal of Fisheries and Aquatic Sciences, 2011, 68(5), 842-856. http://dx.doi.org/10.1139/f2011-016. [LSR Injection Mold Tooling for Medical Nipple]

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