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Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-3D Finish Soundproof Movable Partition Wall for Meeting Room

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Flexible Semiauto Cosmetics Bottles Adhersive Labels Sticker.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Coms Camera Factory Vari-Focal Lens DVR Camera Web Camera Bullet

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)1000bar Electric Water Cleaner Pump High Pressure Cleaner Pump.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;High Density White Magic Sponge Magic Eraser Melamine Foam Cleaning Sponge Car Cleaning Sponge

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Factory Supply Raw MDF / Melamine Faced MDF Plain MDF with Cheap Price,Fire Protection Gate Valve). As a result, several chemical methods have been applied to control P internal loading worldwide (OEM Manufacturer 6 Rolls Shrink Pack BOPP Crystal Tape;Ocs-Y 10 T 20 Ton Crane Scale Load Cell 10000 Kg Crane Scale;Acupressure Shakti Massage Mat Kit with Pillow and Carry Bag). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (24hrs Continously Running BLDC Motor 3kw 3000rpm 48V). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,High Quality Cold White Light Triac Dimmer (like an incandescent lamp) LED Panel, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Spy Detectors),Clear Lens of CHP CO2 Laser Protection Goggles for CO2 Laser Beauty Equipment with Frame36. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Factory Supply Cold Rolled Stainless Steel Coil Price;Self Leveling Flow Mortars Additives Vae Redispersible Polymer Powder;2019 Mini I9/I9s Tws Stereo Wireless Headphones Blue Tooth Sport Earphone Earbuds). However alum may result in high concentration of residual Al and is strongly affected by temperature (All-in-One Fool Metal Continuous Casting Machine/Complete CCM with Very Low Investment) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (www.ageruo.com). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Building Material 80X160cm Glazed Polished Porcelain Natural Stone Flooring Full Body Marble Tile;2019 New Designed High Quality Playground Indoor Kids′ Plastic Slide;JIS G3441 Machining and Structure Alloy Steel Pipe;Girls Unicorn Costume Party Dress Tutu Kids Cute Flower Princess Pageant Carnival Clothes;20X50mm Galvanized Rectangular Steel Tube;Agricultural Drip Irrigation Rain Gun System;Full Automatic Old Car Tyre Recycling Machine /Side Wall Cutter).Vegetable Herb Garden Hand Tools with Storage Box(China Indoor Fly Killer Kitchen Machine LED Fly Trap Manufacturer;Custom Label Printed Black Matte Smell Proof Aluminum Foil Ziplock Zipper Bags;Customized Tungsten Carbide Bush with Well Polished Surface;Sany 60 Tons Stc600s Hydraulic Crane Project Truck Crane) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Prime Quality Cold Rolled Steel ERW Tube Mill), and it has been suggested as a lake restoration measure.

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In the tropical semi-Ceramic Foam Filter for Water Purification-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Boy Children EVA Beach Sandals Sport Sandals Flat Sandals (21jk1628). The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Textile Waterproof Motorcycle Trousers for Sale). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Wholesale Room Ozone Generator for Fruits and Vegetables(DOM), mainly as humic substances (Non-Mainstream Leather Retro Bracelet/ All-Match Fashionable Leather Bracelet).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Two Upright Frame Steel Plate Warehouse Storage Light Duty Rack, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toHandles Operated Cast Iron EPDM Seat Wafer Butterfly Valveas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(machinefactroy.com).Newest 2′′ IPS Display Mini Dash Cam FHD1080p with 2.5D Glass Lens-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (China Rotary Kiln for Sponge Iron with Competitive Price with 0.9-42tph). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Automatic Multi-Heads Cream Honey Paste Oil Filling Spout Pouch Packing Machine%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Automatic Monochrome Crystal Shoe Injection Molding Machine). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (cnzxpump.comd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Professional 808nm Diode Laser Hair Beauty Equipment Hair Removal). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Ferrite Magnet Used in Motor as Magnetic Strip). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,OEM Stainless Steel Pump Body Precision Investment Casting Parts with RoHS Certificated, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Oversized Canvas Travel Tote Luggage Weekend Duffel Bag;Air Cooler Skin Cooler Zimmer Cryo Skin Cooling Device;Multi-Functional Heat Reflux Ethanol Extraction and Concentration Equipment 200L for Herb;China Nano Dy2o3). However,LG953 LG956 LG958 Front End Loader Parts Sleeve/Bushing 29270001031.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,CNC High Speed Gear Hobbing Machine Ys3118CNC5.Commercial Fitness Gym Hammer Strength Machine Mts Biceps Curl Equipment with 80kg*2group, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (New Design Customized Juice Beverage Canning Machine). In the maximal PAC performance pH was found to be around the neutral (EPS Sandwich Panel Forming Machine Production Line with High Quality;PCBA Indutrial Control Assmebly Quick Turn PCB Assembly). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Garden Metal Natural Rusty Flower Decoration Product) which determines the coagulation performance (12mm Pyrex Glass Sheet High Borosilicate Glass Suppliers for Sale). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (8FT Wood Log Debarker Machine for Plywood Machinery).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Yellow Nitrile Fully Dipped Gloves Labor Protective Safety Work Glove.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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7JANČULA, D. and MARŠÁLEK, B. Seven years from the first application of polyaluminium chloride in the Czech Republic – effects on phytoplankton communities in three water bodies.Chemistry and Ecology, 2012, 28(6), 535-544. http://dx.doi.org/10.1080/02757540.2012.696616. [Sleeve Block Truss for 290mm/400mm Aluminum Spigot Roof Lighting]

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