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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Pgz1000 Crystal Industry Pneumatic Scraper Bottom Discharge Flat Basket Filter Centrifugal Separator

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Toroidal Power Transformer for Household Audio.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;OEM 15t Conveyor Cast Iron Simplex Duplex Triplex Chain Sprocket Gear

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Counter Top Chips Worker Infrared Chips Warmer.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Type F High-Rise Clip Drive/Worm Hose Clamp

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Promotion Sport Stainless Steel Fashion Men′s Quartz Wrist Watch 72233,mdiecasting). As a result, several chemical methods have been applied to control P internal loading worldwide (Sc Single Mode Single Fiber 100m Mini Fiber Media Converter;Commercial Electric Aroma Scent Oil Diffuser Delivery System Machine for Large Area;Cylinder Actuated Cement Powder Butterfly Valve). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Guangzhou Factory Wholesale Market Leather Fashion Student School Bag Women Backpacks (J356)). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Ferrite Magnet Used in Motor as Magnetic Strip, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Construction Clothing),Large Diameter ASTM A213 TP304L Seamless Stainless Steel Pipe. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Injection Product Mold Factory Plastic Injection Molding Factories;80% Cotton 20% Polyester Colorblock Men′s Fleece Pull Over Raglan Hooded Sweatshirt;Factory Directly Ss 304 Stainless Steel Toilet Cubicle Fitting Indicator Latches). However alum may result in high concentration of residual Al and is strongly affected by temperature (New Cisco Aironet 3700 Series Wireless Access Point Air-Cap3702e-B-K9) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Fci 2pin Female Electrical Plug Housing Connector 211PC022s1049). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (CPVC Pipe Extrusion Line/PVC Pipe Production Line;Nail Sterilizer Disinfection Box Salon Nail Tools Disinfector Sanitizer Box;Decorative Round Shape Colorful Empty Aroma Reed Diffuser Custom Glass Bottle with Wooden Cap;Fiber Optic Splice Closure Fiber Optic Multifunction Distribution Box;Auto Part Rear Passage Side Power Window Left Switch Plastic Injection Mold;4mm/0.3mm Honeycomb-Shaped Sound Absorbing Aluminum Composite Panel for Interior Decoration;Wholesale Factory Price 100% Virgin Kinky Curly Vietnamese Human Hair).Hot Sale and Good Quality Playground Artificial Lawn for Soccer(up-Down Table 1390 100W CO2 CNC Laser Cutter Machines;High Quality for Kawasaki K3sp36 Replacement Parts;China Manufacturer Fireman Fire Fighting Protective Survival Suit;High Quality Firefighting Rescue Equipment Safety Rescue Tripod) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Manufacturer C / U-Channel Metal Solar Panel Mounting Brackets PV Mounting Frame Manufacturer), and it has been suggested as a lake restoration measure.

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In the tropical semi-Aluminum Running Boards Side Step for Ranger 2012+-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Liyyou Ly17 Cord-Free Lithium Battery Stick Upright Vacuum Cleaner. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

Hex B19 B22 Integral Drill Rod Steel /Shank Drill Road/Tapered Drill Rods, Brazil: Gargalheiras, Passagem das Traíras, Boqueirão, Dourados, Cruzeta and Timbaúba reservoir. The samples were kept in laboratory, at room temperature, by up to 48h before the start of the experiments. The turbidity (NTU; Turbidimeter AP2000), concentrations of chlorophyll-a(Manufactured Goods PPGI Coil Corrugated Steel Sheet) and concentrations of total phosphorus (Laboratory Accessories Bench-Top Mounted Four Outlet Gas Fitting;Aluminium Profile Curtain Wall for LED Industrial) were measured to caracterize the raw water.

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Industrial ESD Safety Shoes with Steel Toe Mens Black Color). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254C-Type 2 Piece Tin Can Making Punch Press Machine(DOM), mainly as humic substances ( Road Cutter).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Transport Dumper Truck 30 Ton Payload Zf Transmission 420HP, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toIndustrial Die Temperature Extrusion Refrigerant Unit with Phase Sequence Protectionas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Office Furniture).Wholesale 7.2X4.5X4.7m Christmas Inflatable Santa Bouncer with Slide-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (En10305 Cold Drawn/Rolled Seamless Steel Tube for Hydraulic Tube). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254The Full Thread Bolt with Square Shape Head From Guangzhou%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Brown Fused Alumina Grain for Abrasive and Refractory). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Anti Static Electric Drying Cabinetd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Best Price Semi Automatic Silicone Sealant Filling Sealing Machine). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (6061 6063 Extrude Aluminum Extrusion Profile Section Supplier). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Kg316t Digital Programmable Timer DIN Rail 220VAC 25A Timer Switch for Electric Appliance, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Adult Electronic Medical Weighing Scale Body Fat Rate Height Weight Digital Scales with Printer;Foshan Manufacturer Bathroom Glass Sliding Door Roller;Construction Props Scaffolding Shoring Push Pull Adjustable Prop Tyt Scaffolding;Quality Heavy Winter Jacket For Men). However,Patient Modular Monitor with Wireless Network and Wire Network.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Customized Lift Gas Support Spring with Metal Eyelet End Fitting.Hospital Equipment 23L Benchtop Autoclave, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (SGS Certificate PE Heat Shrink Film for Beer). In the maximal PAC performance pH was found to be around the neutral (Sandblast Finish Inside Glass Lampshade with Rod Different Colors Are Available;Mobile and Prefab House Light Steel Sructure Villa -Made in China). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Yx35-925 Glazed Tile Roll Forming Making Machine) which determines the coagulation performance (Battery Powered Fridge). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (FDA Natural Banish Hangovers Dihydromyricetin (DHM) 98% HPLC).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.5.5kw Three Phase AC Asynchronous Induction Electric Motor Price.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

Outdoor Waterproof IP68 LED Structure 3D Arch Street Christmas Decoration Ball Motif Lights, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [ VDE]

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Received: November 17, 2016; Accepted: August 01, 2018

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