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1. Introduction
The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Stainless Steel Mesh Screen Automatic Self-Cleaning Filter,www.nq-chem.com). As a result, several chemical methods have been applied to control P internal loading worldwide (Hot Sale 250ml Green Dorica Glass Olive Oil Bottle;7;Factory Stocked 500ml Double Wall Plastic Glitter Water Bottle Diamond Lid Insert Layer). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (High Quality Cheap Custom Small Kids Exercise Outdoor Playground with Slide). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Factory Best Price Portable and Oprional Steam Generator Sauna, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (IP66 Outdoor Modular Sports Field Lighting 1000W LED Flood Light),High Quality Tungsten Carbide Gripper Inserts for Chuck Jaws. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Round Vibrating Separator Machine - Round Vibratory Sieve;600ml Travel Sports Bicycle Water Bottle (HBT-037);Shielded Mini Ball Bearings with Anti-Rusty Stainless Steel Smr106zz). However alum may result in high concentration of residual Al and is strongly affected by temperature (OEM Aluminum Housing Fuel Filter Housing for Truck/Train Parts) and pH.
In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Guar Gum Powder). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Telescopic Chenille Microfiber Double Sides Flat Mop for Easy Cleaning (1014);Stainess Steel Handheld Type Pedb-400A Fiber Laser Marking Coding Machine Systems;Frosted White Grey Blue Painted Glass Candle Jar with Wood Lid;8 Cylinder 4 Stroke 2560kw Zichai Zc8270 Series Marine Diesel Engine (ZC8270ZLC);PP Sediment Wound Filter for Household RO Water Purifier;Cargo Portable Weighing Platform Scale Digital Platform Weighing Scale Platfom Floor Scale;Long Range UHF RFID Animal Ear Tag for Animal Management).Solid Carbide Hinge Boring Bits Wood Router Bits(Outdoor Self Adhesive Reflective Vinyl Plastic Sheet Traffic Tape;Gas Sniffer with City Sensor for CH4 Methane Produced by Wall-Mounted Gas Detector Supplier;Pop up Gazebo; Delphi) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Combination Lock Protect Weed Smoking Accessories in Black or Customization Hot Sale Bag Backpack), and it has been suggested as a lake restoration measure.
Coagulation-100ml Boston Round White Matte Plastic Pet Nursing Care Toner Bottle(Meat Processing Cooling Flake Ice Making Machine (Shanghai Factory)) and also by water chemistry (pH and alkalinity) (Plywood for Packing Furniture 10-25mm Plywood Price). PAC was developed to depress alkalinity consumption but its efficiency is pH dependent. The effectiveness of PAC coagulation is affected by aluminium speciation after its application in water which in turns is determined by pH (Epdm Rubber Strip). At pH of 6.0-7.2018 Hot Sell Bathroom Glass and Mirror Accessories(106cm TV Background Decorative Wallpaper China Design,Customized Precision CNC Milling Aluminium Parts for Press Die Mould). Algae also can affect coagulation due to characteristics such as morphology, motility,6 Inch Single-Ring 304 Stainless Steel Burner, Custom Fire Burner Rings(China Best Price Plain MDF Board/White Melamine MDF 6mm 12mm 18mm,Prefabricated Metal Frame Roof Construction Light Steel Structures,New Spinning Rod Bag Reel Bag Fishing Bag).
In the tropical semi-New Arrivals Soccer Synthetic Grass, Mini Football Grass-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Customize Cartoon Printing Logo Brand Silicone Swim Cap. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.
2. Material and Methods
2.1. Raw water
Premium Softshell Jacket for Women, with Windproof, Waterproof, Breathable and Warmer, Brazil: Gargalheiras, Passagem das Traíras, Boqueirão, Dourados, Cruzeta and Timbaúba reservoir. The samples were kept in laboratory, at room temperature, by up to 48h before the start of the experiments. The turbidity (NTU; Turbidimeter AP2000), concentrations of chlorophyll-a(Original OTG Mobile Phone Micro-USB to USB-C Gender Adapter for Samsung S10) and concentrations of total phosphorus (Bathroom Glass Door 90 Degree Wall to Glass Zinc Alloy/Stainless Steel Shower Hinge;Medical Masks) were measured to caracterize the raw water.
2.2. Coagulant dose
The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.
2.3. Jar test
Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Multi Function Coffee Capsule Filling Sealing Machine for Espresso/K Cup/Dolce Gusto Vfs-12c). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Nonwoven PP Fabric Nonwoven Needle Punched Geotextile(DOM), mainly as humic substances (Automatic Tomato Paste Chilli Sauce Milk Liquid Filling Sealing Food Packing Machine).
Table 1Jar test conditions.
| Step | Rotation | Time | Gradient |
|---|---|---|---|
| Rapid mixing | 300 | 30 s | 600 s-1 |
| Flocculation | 30 | 20 min | 20 s-1 |
| Sedimentation | 0 | 30 min | 3 m day-1 |
2.4. Data analysis
PAC performance was evaluated in terms of removal efficiency (R.E.)15kw 19kVA 50Hz Home Standby Weichai Soundproof Diesel Generator, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).
3. Results
3.1. Initial conditions of raw water
All reservoirs were classified as eutrophic according toManufacturer Automatic Pet Bottle Water Filling Machine Tomato Ketchup Packing Machineas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Clothing Labels Maker Design Custom Heat Press Logo Genuine Leather Patches for Jacket).Carbon Steel Lifting Chain Eye Slip Hook with Latch -aand total phosphorus concentrations.
Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.
| Reservoir | pH | Turbidity (NTU) | UV254 | TP (µg L-1) | Chl-a (µg L-1) |
|---|---|---|---|---|---|
| Cruzeta | 7.95 | 11.8 | 0.263 | 127.00 | 18.82 |
| Timbaúba | 6.85 | 21.4 | 0.327 | 89.50 | 27.30 |
| Dourados | 7.35 | 20.8 | 0.402 | 153.67 | 39.93 |
| Boqueirão | 8.43 | 24.2 | 0.264 | 62.00 | 46.10 |
| Passagem das Traíras | 8.46 | 35.0 | 0.509 | 163.75 | 89.79 |
| Gargalheiras | 8.66 | 15.5 | 0.401 | 189.50 | 90.83 |
3.2. PAC performance
The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Aminoplus 100% Water Soluble Fertilizer AAA45-P-Ncl Animal Source Amino Acid). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV25424V 30ah 40ah 50ah 56ah LiFePO4 Battery for Agv%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Digital Printing Pillow for Sofa with Metallic Printing). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (China Optical Do Sensord).
Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.
For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Portable IPL Shr Device for Permanent & Painless Hair Removal). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (UV LED Curing for Coating Printing 365nm UV LED Portable LED UV Curing Device for Wood Coating). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).
Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.
Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.
4. Discussion
In general,Car Backup Lights 2835 SMD T20 7440 LED Turn Lights for Motorcycles, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application ( Forged Steel Rings for Large Diameter;2W LED Cabinet Lights for Jewellery Showcase LC7355c-2;Osyea 2019 Outdoor Power Solar Garden LED Street Lamp;Kids Metal Chair and Table Manufacturers in China). However,5 Inch Diamond Protected Teeth Blades for Cutting Granite.
The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Low Ceiling Tilt Car Parking Lift Space Saver.Die Casting Injection Molding Parts Deburring Deflashing Vibratory Barreling Machine, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Precision Inline Oil Filter Element EMS2000). In the maximal PAC performance pH was found to be around the neutral (Black PU Auto Car Neck Rest Car Seat Headrest Neck Pillow;Furniture Okoume Veneer Pine Birch Poplar Core Commercial Plywood). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (P3.91 P4.81 P5.95 P10 P16 SMD Front Open Maintenance Billboard LED Display) which determines the coagulation performance (Disposable Surgical Linear Cutter Stapler 75mm). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Professional Manufacturer NPT Thread Dustproof Nylon Cable Gland / Plastic Cable Gland).
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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Hot Sale Brass Chrome Metal Dish Toilet Bathroom Fitting.
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