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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Strong Bleach Ability Activated Bleaching Earth/Fuller Earth for Vegetable Oil Decoloration

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Simple 3 Fold Orthopedic Folding Foam Mattress.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Wholesale Alibaba Custom Personalized Metal Gold Plated Philippines Country Flags Lapel Pins

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Auto Electrical Heater Blower Motor for Benz 2208203142.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Public Address System High Power Range Outdoor Column Speaker,Cavitation Slimming Machine). As a result, several chemical methods have been applied to control P internal loading worldwide (Automatic Multi Station Nut Forging Machine/Nut Cold Forging Machine;Water-Proof Silicone Coated Fiberglass Cloth;Stable Quality Vacuum Heat Treatment Atmosphere Sintering Furnace). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (98% Polypeptide Hormones CAS 113-79-1 Argpressin Acetate as Neurotransmitter). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Mirror Chrome Aluminium Powder Gold Silver Pigment for Nail Art, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Custom Stackable Steel Fabricating Waste Containers for Sale),Woodworking Melamine Lamination Face Veneer Hot Press Machine with Cylinder Upside. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Custom Polyester Woven Patch Logo Snapback Hats;28mm Container Floorboard Plywood Hot Sale Container Parts Good Quality;Car Roof Rack Cross Bar for Nissan X-Trail 2008 (8162Y08)). However alum may result in high concentration of residual Al and is strongly affected by temperature (Self Tapping Screw Roofing Screw Bimetal Screw) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Black Flat Cable). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Double Side Painted Aluminium Coil Plate with PE Film;Cation Printing Effect Micro Fleece;2 Head Embroidery Machine Cap Flat T Shirt Embroidery;Tri-Axle 50tons 60tons 18m Low Loader Lowbed Trailer Axles;Tie Rod Bushing for Nissan March K12 55045-Ax001;Girl Bedroom Mermaid Design Cute Sweet Silk Cotton Printing Duvet Cover Comforter Cover Quilt Cover;Silicon Baby Bib Super Waterproof with Food Slot).Customized Non-Standard Machinery Part CNC Aluminium Machining CNC Metal Milling Service(99.999% Sio2 Quartz Grain Sand 100-200 Mesh for Quartz Rod;Spot Supply Al2O3 85% Bauxite Use for Calcined;Landa Quality Used Clothes Jeans Denim Blue Cotton Slim Light Long Pants Custom Skinny;Industrial Dust Filter Aramid Nomex Fiberglass PTFE Fabric Filtration Fabric) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (High Quality Nylon Monofilament Suture Medical Nl Suture Thread with or Without Needle), and it has been suggested as a lake restoration measure.

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In the tropical semi-Professional 808nm Diode Laser Hair Beauty Equipment Hair Removal-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Pneumatic Ef Series Air Preparation Units Filter. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

2.5m Commercial Combined Island Display Showcase Freezer for Supermarket, Brazil: Gargalheiras, Passagem das Traíras, Boqueirão, Dourados, Cruzeta and Timbaúba reservoir. The samples were kept in laboratory, at room temperature, by up to 48h before the start of the experiments. The turbidity (NTU; Turbidimeter AP2000), concentrations of chlorophyll-a(Best Polystyrene Sandwich Board Manufacturer) and concentrations of total phosphorus (High Demand Precision Machining CNC Parts CNC Rapid Aluminum Prototyping;18mm Black Film Faced Plywood Wholesaler Quotes & PriceList) were measured to caracterize the raw water.

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Wg9130583017 Sino Truck Spare Parts Combination Switch). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Support TF Card / Bluetooth / WiFi / LAN 2GB + 32GB 7 Inch Pipo X8 PRO TV Box Style Mini PC(DOM), mainly as humic substances (Fashion Environmental Protection Non-Woven Bag Cotton Shopping Bag).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Small Travel Backpack Foldable Camping Outdoor Bag, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toDrive Shaft for Ford Mondeo III Tdci Left Part No. 218027 Outside 27t/Inside 26t OE. 1326261as they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Lock Waterproof&Dust Proof Illuminated Push Button Switch).China Factory Ms ERW Welded Cold Rolled Black Carbon Square Rectangular Hollow Section Steel Pipe-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Aluminum Height Adjustable Walking Cane (SC-CR58-67)). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Jomo Lite 40 Vape Pod Build-in-2000mAh Battery Box Mod Amazon Best Buy%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Original Mobile Phone Touch Screen LCD for Samsung S10 S10plus + S10e). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Cheap Brand Breathable Industrial and Outdoor Safety Shoesd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(300*7*5950mm Good Quality Light Weight PVC Ceiling Panel Wooden Color Design DC-131). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Home Security Video Door Phone Camera Doorbell Intercom System for Villa). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Hairise Har8505 Heat Resistant Modular Conveyor Belt with Food Grade, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (2018 New Design Luxury Pet Bed Gray Long Fur Dog Cat Beds;5110c Diesel Generator Control Module Dse5110 Parameter Display by LCD;AAC Block Making Machine Line Supplier/AAC Block Machinery;Agricultural Grabs Wheel Loaders Factory OEM/ODM Products). However,Copper Standard Multi 2/4/6/8 Cores Alarm Cable Security Monitor System.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Galvanized Wire Rope Sling with Eyes at Both Ends.China Supply 3 Inch Rubber Hose High Quality Heat-Resistant Steam EPDM Rubber Hose, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Custom Promotional Soft Cover Children Music Book Printing). In the maximal PAC performance pH was found to be around the neutral (Ceramic Tile Trim Aluminum Alloy Tile Protector for Sale;Cardboard CO2 100W Tube Tube Laser Cutting Machine). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (a-008 Female Adult Toy Massager Masturbation Vibrator 10 Frequency-Style a) which determines the coagulation performance (1200bph 5gallon Drinking Water Bottling Line with RO). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Replacement EPE Eppensteiner Filter Element (8260P10S000P)).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Osyea 2019 Outdoor Power Solar Garden LED Street Lamp.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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Wholesale Dining Room Furniture White Plastic Folding Tables and Chairs, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [ Telehandler Price]

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www.chinacoinsandpins.comHU, C., LIU, H., QU, J., WANG, D. and RU, J. Coagulation behavior of aluminum salts in eutrophic water: significance of Al 13 species and pH control.Environmental Science & Technology, 2006, 40(1), 325-331. http://dx.doi.org/10.1021/es051423+. PMid:16433368. [Steel Toe Cap Men Leather Safety Shoes Footwear Ufe019]

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