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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Commercial Mix Flavor Ice Cream Machine Yogurt Soft / Hard R410A 3 Flavor 110V

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Patened Design Large Mich Indoor Trampoline Park for Kids.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Fiberglass Water Park Spray Playground Equipment for Sale

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Swivel Hook Auto Engine Valve Spring Motor Spring.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Germany Imported IPL Xenon Flash Lamp/IPL Lamp/Xenon Lamp

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (48mm Strong Tensile Strength Brown BOPP Adhesive Box Packing Tape for Carton Sealing,Rare Earth Rotating Drum Magnetic Separator). As a result, several chemical methods have been applied to control P internal loading worldwide (Kylie New Arrival Lipstick+Lips Pencil Makeup Waterproof Lip Gloss Lipstick Set;Decorative Waterproof Fireproof Heat Resistant HPL High Pressure Compact Phenolic Laminate Board;P3 Six Faces Indoor Full Color Irregular Shape Magic Cube LED Display Screen). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Automatic High Speed Welding Manipulator Machine). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,High Quality ABS Nylon Stainless Steel Bathroom Shower Chairs for Elderly, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (China 8x30 Granular Activated Carbon),Hot Rolled Steel Strip Galvanized Steel Strapping Hoop Iron. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Stainless Steel Juice Multi-Bag Filter Machine;China Manufacturer Mifares50 13.56MHz RFID Thin Smart Card;2000bph Chicken Slaughtering Equipment Line). However alum may result in high concentration of residual Al and is strongly affected by temperature (400g Aquaria Ozone Generator for Aquarium Fish Farming Water Treatment) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (304 Ti Black Mirror Etched Stainless Steel Sheet). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Portable Far Infrared Sauna Dome with Tourmaline Stone;30W PA System Surround Sound in Ceiling Mount Speaker Waterproof Speaker;Wholesale 925 Sterling Silver Turkish Micro Pave Big Turquoise Evil Eye Pendant;PCB Masking High Temperature Resistant Tape Polyimide Film Tape;Girls Long Sleeve Unitard; Mild Steel;2019 New Factory Direct Metal Bird Feeder for Garden Decoration).26000lm 200W LED High Bay Lamp Fixture for Gym House Factory( E-Liquid;Breathable High Visibility Reflective Safety Leisure T-Shirt;70W 100W 120W Ce RoHS Energy Saving IP65 Outdoor Integrated All in One Solar LED Street Light;Hot Sale Magnetic Strip Inserting Making Machine) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Denso Nozzle G3s32 for 295050-056#1465A351 Common Rail Injector System), and it has been suggested as a lake restoration measure.

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In the tropical semi-Flat Compression Injection Mould Die Spring/Standard Coil Spring with Rectangular Section-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.High quality 110V DC Power Supply for American Market. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (SS304 SS316 St2.9 St4.8 DIN7981 Stainless Steel Cross Recessed Pan Head Self Tapping Screws). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Fiberglass Grating, Glassfiber Molded Grating, FRP Pultruded Grating, GRP Grating.(DOM), mainly as humic substances (Brushed Aluminum Metal Sheet/Plate for Wall Decoration and House Hold Appliance Panel).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Electric Control Polystyrene Cuttrt EPS Block Cutting Machine, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toFive Brushes Car Wash Rollover Car Washing Wholesaleas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Fire Retardant Aluminium Composite Panel).Good Price Semi Automatic Pet Water Bottle Blowing Blow Molding Machine-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Single-Phase Electric Motors Capacitors 110V 270-324mfd). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Customization Industrial Steam Boiler Repair Parts Steam Economizer Boiler Pipes%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Hot Chinese Product Mini 32A 4p Household AC Contactor). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Airport Mesh Fence Suppliers/Manufacturers for Saled).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(PCB Reverse Engineering SMT PCBA Factory WiFi Router PCB Assembly). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Three Phase Fan Water Pump Electric Asynchronous Induction Motor). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Smart Label RFID UHF Sticker with Special Offer for Asset Tracking, Logistic, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Type S Pressure Reducing Valve for Food Processing;1.2344/AISI H13/JIS SKD61 Mould Steel for Die Casting; Drainage Pipe Machine;Bs464 Thimbles). However,Ocs-Y 10 T 20 Ton Crane Scale Load Cell 10000 Kg Crane Scale.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Eddy Type Vegetable Washing Machine Bubble Washing Machine with Ozone.Soft Green Landscaping Grass Artificial Turf, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (15.6 Inch LED Backlight Wide Screen HD LED TV Ce CB). In the maximal PAC performance pH was found to be around the neutral ( Debossed Hotel Towel;Cbb15/16 DC Filter Resonance Capacitor for Wire Bonding Machine). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Tamper Evident Walmart Office Depot White out Warning Void Self-Adhesive Security Tape for Bottle) which determines the coagulation performance (Double Side Solar Road Reflector Suppliers for Highway Safety). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (American Type Earth Clamp for Welding Equipment).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Pediatric Skin surface temperature probe, L=3m, 5.0mm Disk.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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Dart Extrusion Machinery Making Twin Screw Extruder, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [Environmental Protection Material PLA Sheet for Cup Lid Tray Forming]

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