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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Motion Sensor Light Stick Closet Light Wall LED Night Light

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Wholesale Kitchen Cleaning Pot Scourer Galvanized Scourer Ball.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;1064nm 532nm Picosecond Q Switched ND YAG Laser / Laser Removal Tattoo Beauty Machine

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Micro Inch Finishes for High Precision Grinding Lapping Metal Non-Metal Part.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Electroplated Diamond 200mm Circular Saw Blade for Concrete Cutting

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (1.0 Ton Small Backhoe Crawler Mini Excavator Digger Machine for Sale,Double Acting Aluminium Lock Nut Telescopic Hydraulic Cylinders). As a result, several chemical methods have been applied to control P internal loading worldwide (2017 Cheap China Pistol Safe Security Gun Safe Lock;Jq350 Small Electric Vertical Pan Cement Blender Concrete Mixer;Xaja Truck Light Wire Automotive Cable Trailer Wiring Harness). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (En71 Approved Baby Electric Toy Bike Kids Battery Motorcycle). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Solid State Relay, SSR -40va, Ce Proved Solid State Relay, 24-380VAC Single Solid State Relay, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (625 Nickel Pipe),Best Custom Private Label Glass Pillar Paraffin Votive Birthday Flameless Scented Candle with Jar. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Siboasi Best Selling Badminton Shuttlecock Feeder Machine;ISO Linyi Apitong 28mm Marine Plywood Container Spare Parts; medical disposable clothes). However alum may result in high concentration of residual Al and is strongly affected by temperature (Custom Fashion Apple Mobile Wooden Phone Case for iPhone (6/7/8/6s/8s Plus/Xs Max/Xr/Xs/8plus)) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Eglu Chicken Coop). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Pneumatic CNC Router 1325 Multi Heads Pneumatic Furniture Cutting Machine; Welding Parts;PA66+GF Polishing Injection Auto Plastic Parts Mould Manufacturer;High-Class Sld-6121 Paper Sticker High Speed Slitting Machine;Digital Signage Touch Screen Kiosk;Ultrasonic Welding Machine for Cutting Sponge Scouring Pad Scourer;Safety Shoes Anti-Slip Silicone Rubber Crampons OEM Factory).Factory Price of Potassium Hydroxide (KOH) Flakes 90%Min Purity -Qingdao Hiseachem(Outdoor Artificial Wood Plastic Playground Equipment on Promotion (HK-50011B);China Factory Forged Clevis Grab Hook Crane Lifting Hook Made in China;Wholesale Tumble Dry Low Breathable Tigers White Ground Baseball Sportswear;Food Grade Glass Storage Glass Jar for Spices Candy Foods Dried Vegtables Canned Fruit) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (LG936 LG938 Front End Loader Parts Gas Spring 29330011391), and it has been suggested as a lake restoration measure.

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In the tropical semi-Yx35-925 Glazed Tile Roll Forming Making Machine-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.100% Virgin Material PMMA Cast Acrylic Sign Board. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

Good Performance High Precision Thrust Roller Bearing (29292), Brazil: Gargalheiras, Passagem das Traíras, Boqueirão, Dourados, Cruzeta and Timbaúba reservoir. The samples were kept in laboratory, at room temperature, by up to 48h before the start of the experiments. The turbidity (NTU; Turbidimeter AP2000), concentrations of chlorophyll-a(Women′s Stretchy Yoga Training Mesh Leggings with Side Pocket) and concentrations of total phosphorus (Wholesale Promotional Children Painting Apron;2mm thickness 1.2′′astm A53 Grade Greenhouse Structure Galvanized Steel Pipe) were measured to caracterize the raw water.

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Custom High Quality Clear BOPP Adhesive Tape for Carton Sealing). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Good Mechanical Grade B 3240 Epoxy Insulation Fiberglass Sheet(DOM), mainly as humic substances (Automatic Concrete Paving Interlocking Block Brick Making Machine).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)HR/CR/GI High Frequency Longitudinal Seam Tube Mill, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toFish Scale Shaped Waterproof Roof Tile for Roof Tileas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(2019 New Design Hotel Massage Soap Hot Sale Factory Price).Wisdom Brand Top Quality LED Mining Safety Lamp, Miner Lamp-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Wholesale Room Ozone Generator for Fruits and Vegetables). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Extrusion Mould Cemented Tungsten Carbide Wire Drawing Die%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Folding Dinner Table Set in Dining Room Furniture). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (ritecmachine.comd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Anti-Slip Crazy christmas Cute Funky Cotton Custom Socks). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Patterned Shoulder Nozzle Aluminum Tube for Glue/Medical Ointment Packaging). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Creative Stainless Steel Guitar Shape Patch Empty Platinum Bottle Opener, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Fsi 5kw 24VDC Pure Sine Wave Hybrid PV Solar Inverter with High Efficiency MPPT Controller;Mobile Phone Jammer + WiFi / GPS / 4G Jammer 6 Bands;Professional Korea Hifu Focused Ultrasonic Beauty Machine for Wrinkle Removal;Elliptical Trainer Crosstrainer Exercise Upright Bike with Seat). However,Corn Starch Foam Biodegradable Frozen Food Packaging Tray.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Highway Outdoor Road Integrated Solar LED Street Light Price List.Commercial Mix Flavor Ice Cream Machine Yogurt Soft / Hard R410A 3 Flavor 110V, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Durable Life Stainless Steel Knotted Cable Mesh). In the maximal PAC performance pH was found to be around the neutral (Bamboo Rattan Stick / Aroma Rattan Stick/Nature Reed Rattan Stick;Customized Wholesale Waterproof Crossbody Chest Bag Backpack Sling Bag Women Messager Shoulder Bag). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Light Weight FRP XPS Composite Panel for Mobile Home Construction) which determines the coagulation performance (220 T/H Indonesia Coal CFB Boiler for Power Plant). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (OEM Metal Iron/Carbon/Steel Hammer Forging for Cylinder/Raiway Wheels).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Outdoor LED Street Pole Advertising Business Double Sided LED Signs.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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Patened Design Large Mich Indoor Trampoline Park for Kids, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [Custom High Quality CNC Milling Acrylic Block Stainless Steel Aluminum CNC Precision Milling Service]

Auto Starter 0001230002 12V 3.0kw 11t for John DeereCHEN, J. and LUAN, Z. Enhancing phosphate removal by coagulation using polyelectrolytes and red mud.Fresenius Environmental Bulletin, 2010, 19(10), 2200-2204. [Fashion Italian Style Hotel Furniture Wooden Marble Dressing Table]

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