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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Electronic Smoke Digitizer Quartz Atomizer Short Quartz Tube

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)High Demand Precision Machining CNC Parts CNC Rapid Aluminum Prototyping.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;36W/48W Interchangeable AC DC Adapter Free Samples 14 Years Experience

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)4.5qt Camping Nonstick Wholesale Cast Iron Dutch Oven Bread Pan.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Colorful LCD Display High Quality Cheap Price Optical Fiber Fusion,Automatic Spiral Dough Mixer High Quality Supplier). As a result, several chemical methods have been applied to control P internal loading worldwide (Custom C3 C5 Ground Miniature Ball Screw 0802;Log Debarker Veneer Rotary Peeling Machine;Real-Time GPS Padlock Container Tracker GPS Tracking Car/Truck Fleet Management). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Outdoor Food Truck Mobile Food Car for Sale). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Factory Price Capstan Hydraulic Winch 5 Ton, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Electric Paint Spray Machine Manufacturers Cheap Price),PP Yarn Water Filter Cartridge for Large Flow Rate. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Durable Soft Polishing Wheel for Polishing Wood and Plastic;Foshan Manufacturer Sound Proof Powder Coated Aluminum Bi-Folding Door with Australia Subframe;Medical Equipment One Step Tp Device Syphilis Rapid Test Kit). However alum may result in high concentration of residual Al and is strongly affected by temperature (Agricultural Machinery Partslinear Bearings Kh3050) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Shanghai Plastic Injection Molding Manufacturer of Plastic Medical Equipment Device). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal ( 12V- 48V DC;Wholesale Bedding Set Hotel 100% Cotton Bed Sheets White;Factory Supply Raw MDF / Melamine Faced MDF Plain MDF with Cheap Price;OEM Manufacturer 6 Rolls Shrink Pack BOPP Crystal Tape;ABC-508 Brake System Cleaning and Fluid Exchanging Machine;Ocs-Y 10 T 20 Ton Crane Scale Load Cell 10000 Kg Crane Scale;Acupressure Shakti Massage Mat Kit with Pillow and Carry Bag).Hot Selling Construction Machine 50cbm/H Ready Mixed Concrete Mixing Plant(24hrs Continously Running BLDC Motor 3kw 3000rpm 48V;Factory Supply Cold Rolled Stainless Steel Coil Price;Hot Sale Multifunction Beauty Portable Cavitation RF Slimming Machine;Self Leveling Flow Mortars Additives Vae Redispersible Polymer Powder) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (2019 Mini I9/I9s Tws Stereo Wireless Headphones Blue Tooth Sport Earphone Earbuds), and it has been suggested as a lake restoration measure.

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In the tropical semi-Industrial Automatic High Quality PVC Fast Speed Roller Shutter-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Bento Lunch Box, Meal Prep Containers, Reusable 3-Compartment Plastic Divided Food Storage. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

Custom C3 C5 Ground Miniature Ball Screw 0802, Brazil: Gargalheiras, Passagem das Traíras, Boqueirão, Dourados, Cruzeta and Timbaúba reservoir. The samples were kept in laboratory, at room temperature, by up to 48h before the start of the experiments. The turbidity (NTU; Turbidimeter AP2000), concentrations of chlorophyll-a(Custom Label Printed Black Matte Smell Proof Aluminum Foil Ziplock Zipper Bags) and concentrations of total phosphorus (Sany 60 Tons Stc600s Hydraulic Crane Project Truck Crane;Automatic Leather Panel Cutting Machine) were measured to caracterize the raw water.

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (SRS Painting Green Color 10ml Thick Glass Roller Ball Bottle). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Wood Plastic Mould/UPVC Profile Extrusion Mould Plastic Profile Extruding(DOM), mainly as humic substances (Alumina Ceramic Shafts Al2O3 Ceramic Plungers).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Grade 10.9 Carbon Steel Hot DIP Galvanized Coating Hex Bolt with Nut and Washer DIN933, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toStainless Steel 1000W Pipe and Sheet Fiber Optic Laser Cutting Machineas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Water Supply Pipe Extrusion Line PE Pipe Extrusion Line).High Quality Memory Foam Vacuum Compressed Packing Pocket Spring Mattress-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (High Quality Adjustable Ball Valve Lockout for 13-70mm Pipe Bd-F05). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Paint Spray Booth Air Flow Vehicle Paint Booth for Sale%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Preparation Concrete Vibrator Shaft with Japanese Coupling). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Discount Price Full Hd Touch Screen Display - 7Inch Waterproof Monitor Spec - TOPO d).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Textile Waterproof Motorcycle Trousers for Sale). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Non-Mainstream Leather Retro Bracelet/ All-Match Fashionable Leather Bracelet). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

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The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Manufacturers Prefabricated Construction Steel Structure Space Frame Used Warehouse Buildings.Mesh Band Casual Fashion Women Quartz Watches Gift Stainless Steel Wristwatches, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Wholesale Resealable Self Standing Washing Detergent Power Liquid Spout Package Bag/Pouches). In the maximal PAC performance pH was found to be around the neutral (China Rotary Kiln for Sponge Iron with Competitive Price with 0.9-42tph;Automatic Monochrome Crystal Shoe Injection Molding Machine). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Portable Adjustable Basketball Hoop for Teenager) which determines the coagulation performance (2018 Custom-Made High Quality PCBA). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Professional 808nm Diode Laser Hair Beauty Equipment Hair Removal).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.GS-1612 Factory Direct Cheap Hot Sale Fabric/Acrylic/Wood/Granite CO2 Laser Cutting Engraving Machine.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

Plastic PP/PS/Pet Mineral/Starbucks/Jelly Cup Thermoforming Making Machine, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [Aluminium Foil Cup Lids Metal Stamping Parts/Deep Drawing Parts]

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