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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)Makeup Case Toiletry Bag for Women Skincare Cosmetic Pouch.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Banbury Rotors 3L Lab Plastic and Rubber Mixer Machine

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)NEMA 17 0.9/1.8 Degree Two Phase Electric Step Stepper Motor with Permanent Magnet Brake.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;GRP FRP Fiberglass Composite Epoxy Resin Water Treatment Pipe Tube Cylinder

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (12.5/80-18 16.9-24 16.9-28 Agriculture Backhoe Loader Tires,Pcb Assembly Led). As a result, several chemical methods have been applied to control P internal loading worldwide ( Digital Thermometer E278;Matching 3kw;Hot Sale Instax Mini Camera Korea Style Photo Album). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Good Price Optical Cylindrical Lens for Laser Light). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Push up Breast Enlargement Bra SGS Test Certificate Backless Adhesive Silicone Bra Transparent, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Graphite Electrode UHP 350mm Diameter for Steel Making),Nylon Kitchen Tools Set Cutlery Set with Stainless Steel Kitchen Set. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Different Kinds Butterfly Hot Melt Adhesive Applique Embroidery Patches;Single Quartz Tube Medium Infrared Carbon Fiber Heater;UV LED Varnish Digital Flatbed Printing Printer Machine for Wood Glass Metal A1). However alum may result in high concentration of residual Al and is strongly affected by temperature (Customized Promotional 100% Cotton 6 Panels Baseball Cap with Printing Logo) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Professional LED Lighting Star Curtain Drape Twinkling for Event). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Vertical Waste Plastics/Cloth/Cardboard Hydraulic Press Waste Paper Baler Baling Machine;Factory Price Capstan Hydraulic Winch 5 Ton;Washroom Water Tap of Hot and Cold Water Mixer;Low Insertion Loss St Upc Singlemode Simplex Fiber Optic Adapter;Potassium Formate Liquid;China Most Professional Factory 316L Stainless Steel Round Seamless Decorative Pipe Tube;Living Room Furniture TV Stand Electric Fireplace with No Heating).Flanged Bolted Bonnet Cast Steel Swing Check Valve Supplier(High Quality 11oz Bone China Color Change Mugs Sublimation Coating Mugs (Matte);Smart Electronic RoHS Weighing Scale PCB Manufacturer with Fast Delivery;2019 Winter New Hot Selling Electronic Heater;Zinc-Plated Carbon Steel Tiger Clamp Spiral Double Bolts Clamp) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Best Electric Roll on Paraffin Wax Heater for Sale), and it has been suggested as a lake restoration measure.

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In the tropical semi-150ml Plastic Cosmetic Cream Jar with Label Made in Yuyao-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Littlefuse IC Fuse Cartridge Ceramic Electronic Component Nanosmdc012f-2. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Miniature Linear Motion Guide Mgn5/Mgn7/Mgn9mgn12/Mgn15 Square Linear Block). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Venlo Hot-DIP Galvanized Steel Frame Glass Greenhouse for Sale(DOM), mainly as humic substances ( Power Unit Pack 3200 Psi Fit for Lift up/Down).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Touch Screen Handheld PDA Barcode Scanner with 4G Bluetooth WiFi Camera GPS, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toYellow Forced Oil Cooling Overband Magnetic Separator for Conveyor Beltsas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Stainless Steel Flat Wire Conveyor Food Mesh Belt).New Design Customized Juice Beverage Canning Machine-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
Alumina

3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Outdoor Basket Hanging Chair Balcony Chair Rattan Swing). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Tb10-30kVA Low Frequency Online UPS High Efficiency UPS with Snmp%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Handle Adjustable Magic High Quality Microfiber Magnet Mop for Home Cleaning 1045). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Fbk600 Ultra-Thin Metal Card Data Recorder Wide-Angle HD Night-Vision 1080Pd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(Hot Selling Waterproof Anti-Slip Vinyl PVC Homogeneous Plastic Roll Floor). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Wallbox EV Charging Station with Ce Approvals). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Custom Running Sport Metal Medal by Soft Enamel, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (CNC Deep Machining Aluminium TV Frame Part with Anodization Surface;50ml 150ml 500ml Glass Aroma Diffuser Bottle;Manufacturer New Design Reusable Clear Lalique Glass Perfume Packaging Bottle;Apparatus Of Fractional Distillation). However,Customizable High Quality Q38 Series of Catenary Shot Blasting Machine.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Blackboard Imprint Unique Glass Drinking Jars for Canning.Handsfree Car Kit Wireless Multipoint Speakerphone with Visor Clip, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Ductile Iron Service Gate Valve Ductile Iron Screwed Ends Resilient Gate Valve Thread). In the maximal PAC performance pH was found to be around the neutral (New Arrivals Soccer Synthetic Grass;380W New Beam Moving Head Night Club Disco Lighting for DMX Controller). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Large Diameter ASTM A213 TP304L Seamless Stainless Steel Pipe) which determines the coagulation performance (Orange Teal Filter). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Trisun Mechanical Seal Spare Parts Wave Spring).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Clear Plastic PVC Window Cmky Full Color Printing Box.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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Solar Energy Battery Storage All-in-One Battery Storage System Output Power Factor PF=1.0, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [Reflective Tape Protective Nomex Fire Suit with Trousers]

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