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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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Thematic Section: Limnology in Brazilian Semi-Galvanized Material Metal Workshop and Warehouse Peb Light Steel Structure

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)ASTM A335 P11 Seamless Ferritic Alloy-Steel Pipe for High-Temperature Service.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Fabric/ Cloth Insertion SBR/ EPDM/ Nitrile/ Neoprene/ FKM/ Natural Anti-Slip Rubber Flooring

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)Luxury Fashion Lady Women Shoulder Tote Bag Leather Evening Handbag.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Wholesale Baby Shoes Kids Boy Wear LED Flashing

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Automatic Food Coating Chocolate Spraying Dk Air Atomizing Nozzle,Mining Electric Hydraulic Mini Excavator with Quick Coupling). As a result, several chemical methods have been applied to control P internal loading worldwide (High Glossy/Matt/Embossed/UV/Natural Wood Veneer Faced Melamine Laminated Colored MDF for Furniture;Different Gauge Hot Dippep Galvanized Purlin Metal Steel Sheet Coil for Roofing Sheet Price;Best Quality Square Mini Takoyaki Grill Pan with Helper Handle). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Simple Shool Teaching Portable Monocular Microscope for Medical Products). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,Stainless Steel 304 316 Railing Fittings Casting Round Tube Plate, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Que Es Spark Supplier & Factory),Non-Smoke E7018 E6018 Welding Rod Carbon Steel Welding Electrodes. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (Hydraulic Metal Chips Block Moulding Machine;Hip-Hop Streetwear Custom Brand Fashion Man Hoodie;20000L Injection Blow Molding Machine Used Extrusion Blow Molding Machine). However alum may result in high concentration of residual Al and is strongly affected by temperature (Biodegradable Sugarcane Bagasse Pulp Takeaway Fast Food Packaging) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Stone Columns). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Hot Sale Jumbo Roll Double Sided Adhesive Tissue Tape for Cars (DTS10G-15);3p 4p Electrical Dual Power 1250A Transfer Switch;High Density Multi-Layer PCB Prototype PCB Printed Circuit Board Professional Manufacturer;Hair Growth Ingredient Biotinoyl Tripeptide-1 CAS 299157-54-3;m.gz-sourcing.com;Professional Palm Handheld Veterinary Ultrasound Diagnostic System;Queene/MID Drive Fat Tire Ebike with LCD Display for Performance Riding MTB).Factory Direct Seal Y14f General Power Relay 5 Pins(Rk Aluminum Exhibition Stage Truss Booth Stand Lighting Truss;Hot Selling Polyresin Garden Dark Blue Birdhouse for Tree Decoration;Microcomputer Control Air Permeability Test Equipment in Test Machine;Marine Salvage and Refloatation Rubber Airbag Roller Bags) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes ( DC Brushless Fan Light PCBA), and it has been suggested as a lake restoration measure.

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In the tropical semi-FRP Fiberglass Underground Septic Tank for Effluent Treatment-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.Pgz1000 Crystal Industry Pneumatic Scraper Bottom Discharge Flat Basket Filter Centrifugal Separator. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation (Granular Fertilizer Potassium Sulphate/NPK/Compound Production Line). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254Solid Carbide Straight Slot Reamer with Inner Cooling Hole(DOM), mainly as humic substances (Pneumatic Vertical Threaded 3-Way Ball Valve).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Balaclava Hood Ski Bike Cycling Face Mask Cap Fleeces Helmet, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according toWater Cooled Vibrating Grate Boiler for Power Plant EPCas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Hdpe Pipeline Factory OEM/ODM Products).Commercial Promotion White Inflatable Party Tent for Exhibition-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (Food Grade Oval Cute Newborn Pacifiers with Soft Soother). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Camping Gas Stove, Outdoor Stove, Table Gas Stove%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Top Quality 40m3/H Small Mobile Mini Twin-Shaft Mixer with Pump). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Brass With Nickel Plated Cable Glandd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(High Quality HVAC Exhaust or Supply Plastic Air Valve). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (High Visibility Reflective Safety Waterproof Outdoor Winter Jacket Softshell Jacket). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

In general,Toroidal Power Transformer for Household Audio, but its efficiency was affected by chlorophyll-aand humic substances concentration. We suggested that 4 mg Al.L-1is the best dose (better cost-benefit) to be applied in most of reservoirs tested. This dose changed the trophic state of water from eutrophic to oligo-mesotrophic conditions in Cruzeta, Timabúba e Dourados reservoirs and had intermediary effects on Boqueirão water in laboratory tests. The efficiency in total phosphorus removal is reported for in-lake PAC application (Transmission Line Steel Monopole Steel Tower; Camera;Industrial Air Cooled Heat Pump Water Chiller in Many Field;Factory Supply Decorative Aluminum Perforated Sheet). However,Mobile Scissor Lift Underground Car Lift/ Hydraulic Car Lift.

The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,Wholesale Fashion Custom Round Neck Mens Tshirts Plain Tshirts for Print.Large Lifting Force Detachable Hydraulic Drilling Rig Machinery for Sale, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (14kw Heating Capacity Evi Air to Water Heat Pump). In the maximal PAC performance pH was found to be around the neutral (1HP Floting Wheel Aerator;48mm Strong Tensile Strength Brown BOPP Adhesive Box Packing Tape for Carton Sealing). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Kylie New Arrival Lipstick+Lips Pencil Makeup Waterproof Lip Gloss Lipstick Set) which determines the coagulation performance (3d Axis Wood Carving Cnc Router). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Decorative Waterproof Fireproof Heat Resistant HPL High Pressure Compact Phenolic Laminate Board).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Ferrite Magnet Used in Motor as Magnetic Strip.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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Large Diameter ASTM A213 TP304L Seamless Stainless Steel Pipe, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [2019 New Factory Direct Metal Bird Feeder for Garden Decoration]

E-LiquidCHEN, J. and LUAN, Z. Enhancing phosphate removal by coagulation using polyelectrolytes and red mud.Fresenius Environmental Bulletin, 2010, 19(10), 2200-2204. [Breathable High Visibility Reflective Safety Leisure T-Shirt]

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