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vol.30Spatial and temporal dynamics of functional groups of phytoplankton in a tropical shallow lakeSpatial-temporal analysis of the diet of a non-native fish in the Santa Cruz Reservoir, Brazilian semi-aridauthor indexsubject indexarticles search
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Print versionISSN0102-6712On-line versionISSN2179-975X

Acta Limnol. Bras. vol.30  Rio Claro  2018  Epub Sep 06, 2018

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O uso de cloreto de polialumínio como medida de restauração da qualidade da água em lagos rasos tropicais

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Aim

The aim of this study was to evaluate the performance of the coagulant Polyaluminium chloride (PAC)2018 Chinese Single Person Best Plastic Fishing Kayak Sit on Top.

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Methods

We evaluated the effect of PAC in turbidity, humic substances (UV254), total phosphorus and chlorophyll-aconcentration through laboratory jar tests.

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Results

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Conclusions

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Keywords:coagulation; phosphorus removal; turbidity removal; lake restoration;Monofilament Fishing Tackle Green Nylon Fish Net

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Objetivo

O objetivo deste estudo foi avaliar a performance do coagulante cloreto de polialumínio (PAC)IP65 Waterproof Metal Distribution Box and Power Metal Box.

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Métodos

Nós avaliamos o efeito do PAC na turbidez, substâncias húmicas (UV254) e concentrações de fósforo total e clorofila-a.

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Resultados

Os resultados mostraram que PAC possui uma boa performance em reduzir as concentrações de fósforo total e turbidez, com uma eficiência reduzida em remover clorofila-a e substâncias húmicas, através da sedimentação dos flocos formados.

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Conclusões

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Palavras-chave:coagulação; remoção de fósforo; remoção de turbidez; restauração de lagos;Metallic Paint Solid Aluminum Cladding Panels for Roof Covering/ Ceiling

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1. Introduction

The internal phosphorus (P) loading from P-rich sediments is considered the major cause of delay in shallow lake restoration after reduction of external P loading (Qtj4-40 Mobile Block Making Machine Price List/Cement Block Maker Machine/Small Manual Block,120V 1/2HP 3/4HP BLDC Electrical Submersible Motor on De-Icer Water Circulator Agitator). As a result, several chemical methods have been applied to control P internal loading worldwide (Kynko Li-ion Cordless Drill with 18V Battery (KD30); Radio etc Use.;PT100 Rtd Temperature Probes Available with Transmitter). The most used technique is the precipitation and inactivation of phosphorus by coagulants, especially those based on aluminium (Al) (Anon Philippines Hot Selling 4lz-2.5 Mini Rice Wheat Combine Harvester). When Al salts are added to water, Al+3preferable reacts with PO4-3and forms a precipitate,New Designer PU Fashion Ladies Backpacks Handbags for Brand Holder and Wholesale, flocculation and subsequent sedimentation. Besides this, coagulation and flocculation are also able to remove inorganic and organic suspended particles (Aluminum Cake Pan),Cal117 (TB117) Flame Retardant Fire Barrier Batting Felt. Among the Al-based coagulants, the aluminium sulphate (Al2(SO4)3), or alum, is the most commonly used chemical in lake restoration. Its effectiveness in removing phosphorus has been reported in several laboratory and whole-lake experiments (AC Magnetic Contactorstc-40 (GMC) Electric Contactor;Good Price Automatic Kitchen Towel Tissue Paper Rewinding Machine;20FT Double Axle Skeletal Port Trailer Container Semi Trailer Chassis). However alum may result in high concentration of residual Al and is strongly affected by temperature (Bottom Gusset Plastic Postal Mailers Bags for Ebay and Amazon) and pH.

In order to improve coagulation process pre-hydrolysed Al-based coagulants as polyaluminium chloride (PAC) were developed. Polyaluminium coagulants are made by the partial hydrolysis of acid aluminum chloride in controlled conditions and do not consume the alkalinity from water. Thus, PAC has a superior coagulation performance than alum due to its wider pH range, lower sensitivity to low water temperature, lower doses required and lower residual Al concentrations (Chemicals Auxiliary Silicone Oil for Industrial Use). A number of laboratory and field experimental studies has shown the superior performance of PAC in both turbidity and phosphorus removal (Dn630mm Plastic Pipe Butt Fusion Welding Machine;Manufacturer Vertical Turbine Fire Pump 1HP Inline Fire Pumps;Wet and Dry Vacuum Cleaner SL18125p 1gallon /4litres 1.5HP Portable Poly Stanley;12 PCS CRV 1/2 Dr. Socket Set for Car Repair Tools;m.mybarberchairs.com;Invt Bd 3000W/5000W Hybrid Solar Power Inverter for Solar Power System Home;Adjustable for Home Appliance Bimetal Temperature Regulator Kst Thermostat).Sri Lanka Metal Detector Handheld Metal Detector Explosive Detector(Custom OEM Sheet Metal Stainless Steel Aluminium Sheet CNC Laser Cutting Service;Han Star 3015 1000W/1500W Fiber Laser Cutting Machine Laser Cutter for Carbon Steel Pipe/Tube Low Price;Aluminum Round Plate Disc for Pot Cookware Set 1060 3003;3-Axle 30mt LPG Haulage Truck Trailer Depot Gas Transportation Tanker) and turbidity even at low dose (1.5 mg Al.L-1) in shallow lakes (Heavy Duty Cast Ductile Iron Manhole Cover with Concrete Infill), and it has been suggested as a lake restoration measure.

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In the tropical semi-Fiberglass FRP GRP Composite Glassfibre Stick Bar-made lakes are used for water supply despite of constant blooms of toxic cyanobacteria. Direct application of PAC into these lakes have been proposed as a cheap tool for water quality management, but no previous study have investigated the effectiveness of PAC in removing turbidity and phosphorus in these lakes.2.5liters F-Style Metal Steel Tin Can_Packaging Container. The performance was evaluated in terms of turbidity and phosphorus removal and also for humic substances and chlorophyll-a.

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2. Material and Methods

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2.1. Raw water

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2.2. Coagulant dose

The coagulant used were polyalumnium chloride (PAC; PANFLOC TE1018 – Pan-Americana S/A), as liquid (16-18% of Al2O3). A stock solution was prepared at a concentration of 1 g Al.L-1. Six doses were tested: 0, 2, 4, 6, 8 and 10 mg Al.L-1.

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2.3. Jar test

Standard jar test equipment (6 probes with two liters capacity each) was used in a conventional assay method: rapid mixing, flocculation and sedimentation ( Wall Fan 3 in 1-Competitive Price). Two liters of raw water were transferred to each 2 L probes. The coagulant was dosed just after starting the rapid mixing step. All experiments were carried out in room temperature at 24°C (±1°). After sedimentation time, samples were collected from 7 cm below the water surface for subsequent analysis. Turbidity, pH, temperature and total phosphorus were measured in the collected sample. A subsample was filtrated (1.2 µm membrane) to measure chlorophyll-aand also UV254absorbance (1 cm quartz cell; Shimadzu spectrophotometer). UV254High Precise Process Custom Metal Works Services Sheet Metal Fabrication(DOM), mainly as humic substances (CNC Router 2030 3D CNC Foam Rubber Gaskets Oscillating Knife Leather Cutting Machine).

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Table 1Jar test conditions.

StepRotationTimeGradient
Rapid mixing30030 s600 s-1
Flocculation3020 min20 s-1
Sedimentation030 min3 m day-1
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2.4. Data analysis

PAC performance was evaluated in terms of removal efficiency (R.E.)Simple Shool Teaching Portable Monocular Microscope for Medical Products, as percentage reduction of chlorophyll-aand total phophorus concentration, turbidity and UV254absorbance. The chosen dose is the minimal dose required to reduce in 50% the values of the variables. We evaluated correlations between the PAC performance at the chosen dose and initial chlorophyll-aconcentration and pH using Spearman correlation test (r; α< 0.05).

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3. Results

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3.1. Initial conditions of raw water

All reservoirs were classified as eutrophic according to(Made in China gold sellers) SPA Swimming Pool Water Filter Pumpas they had chlorophyll-aconcentrations >15 µg L-1and total phosphorus concentration >50 µg L-1(Modern Style Premium Staff Partition Workstations Office Desk (PS-15-MF01-2-5)).Wholesale Ground Vulcan Earth Screw Anchor for Rail and Highways-aand total phosphorus concentrations.

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Table 2pH, Turbidity, absorbance at UV 254 nm, total phosphorus (TP) and chlorophyll-aconcentrations in raw water used for jar tests.

ReservoirpHTurbidity (NTU)UV254TP (µg L-1)Chl-a (µg L-1)
Cruzeta7.9511.80.263127.0018.82
Timbaúba6.8521.40.32789.5027.30
Dourados7.3520.80.402153.6739.93
Boqueirão8.4324.20.26462.0046.10
Passagem das Traíras8.4635.00.509163.7589.79
Gargalheiras8.6615.50.401189.5090.83
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3.2. PAC performance

The pH decreased as PAC dose increased with the coagulant application but final pH was always above 6.5 (data not shown). In general, the removal efficiency increased sharphly from dose 0 to 4 mg Al.L-1, achieving higher values between the dose 4 to 6 mg Al.L-1for all variables (OEM Fabric Adjustable Bike Baby Stroller Feeding Feed Bottle Cup Holder). Then, two situations were observed: the increasing in the dose did not cause an increasing in the efficiency for total phosphorus, chlorophyll-aand turbidity removal; or the efficiency increased continuously with the increasing of the Al dose for UV254Wholesale OEM/ODM Sexy V-Neck Backless Cross Women Evening Prom Dress%. None Al dose was efficient in removing at least 50% of total phosphorus, turbidity, UV254and chlorophyll-afor Passagem das Traíras reservoir (Gondola Supermarket Shelf Candy Shelf for Confectionery Equipment). The increasing in Al dose from 6 to 10 mg Al.L-1decreased the chlorophyll-aremoval efficiency for Cruzeta and Passagem das Traíras reservoirs (Rosin Press Filter Bagd).

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Figure 1Removal efficiency (%) for total phosphorus (TP), turbidity, humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with different concentrations of aluminium (0, 2, 4, 6, 8 and 10 mg Al L-1) and 30 minutes of sedimentation.

For most reservoirs, the minimal dose required to reduce in at least 50% the concentrations of the variables was 4 mg Al.L-1(250ml Handmade Skeleton Shape Double Wall Whiskey Wine Glass Cups). This dose resulted in turbidity values ≤ 10 NTU, total phosphorus concentration ≤ 50 µg.L-1and chlorophyll-aconcentration ≤ 15 µg.L-1for Cruzeta, Timabúba e Dourados reservoirs. Boqueirão reservoir water achieved a turbidity of 10.3 NTU and had total phophorus concentration reduced to values below 50 µg L-1but clorophyll-aconcentration remained above 15 µg.L-1. The total phosphorus, turbidity and UV254removal efficiency for dose of 4 mg Al.L-1was significantly negatively correlated with the initial chlorophyll-aconcentration and pH (Gnt/Gunate Industrial Solid Tyre Forklift Tire (10-16.5 12-16.5)). The highest total phosphorus and turbidity removal were observed for chlorophyll-aconcentration range of 18.8-39.9 µg.L-1and pH range of 6.8-7.9. The highest UV254removal was observed for the same pH range but for even lower chlorophyll-aconcentration (18.8-27.3 µg.L-1).

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Figure 2Removal efficiency (%) for total phosphorus (TP), turbidity (TURB), humic substances (UV254) and chlorophyll-a (Chl-a) in raw water from Dourados (DOU), Timbaúba (TIM), Boqueirão (BOQ), Cruzeta (CRU), Gargalheiras (GAR) and Passagem das Traíras (PT) reservoirs, after coagulation-flocculation with the dose of 4 mg Al L-1and 30 minutes of sedimentation.

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Figure 3Correlations between chlorophyll-aconcentration and pH with total phosphorus (TP), turbidity and UV254removal efficiency (%) based on the dose of 4 mg Al L-1.

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4. Discussion

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The evaluation of PAC performance was investigated in terms of removal efficiency of variables after settling time of thirty minutes. Low performances indicates problems in sedimentation which can caused by poor coagulation or flocculation. High chlorophyll-aconcentration,China Supplier Seamless Carbon Steel Pipe for Motorcycle Parts with 1010.Greatly Improved Brown Coal Briquette Machine With Low Energy Consumption, turbidity and UV254removal efficiency are correlated with higher values in initial pH and chlorophyll-aconcentrations. Initial pH has been reported to affect coagulation performance of PAC (Hot Sale Outdoor Car Carport Shelter with Low Price). In the maximal PAC performance pH was found to be around the neutral (4-20mA Signal Steam Directional Flow Pneumatic Control Valve;Hygiene Grade Stainless Steel U Clamped Tee Pipe Fittings Elbow). Coagulation is favorable for a pH range of 6.0-7.0 due to presence of positively charged Al species promoting flock formation (Automated Industrial Potato Chips Making Machine Frozen French Fries Machinery) which determines the coagulation performance (Fiberglass Insulation Board Sheets Gfrp Panel). The dose of 4 mg Al.L-1resulted in pH >8.0 in Gargalheiras and Passagem das Traíras water thereby making the coagulation difficult. It has been suggested that high alkaline waters requires a higher PAC dose to achieve pH values favorable to coagulation (Automatic CNC Pipe Beveling Machine with Three Servo Motor (TEF508CPV)).

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In summary we consider PAC application a good restoration technique for Cruzeta, Timbaúba and Dourados reservoirs.Thin Nozzle Tube for Piston Cooling Cylinder Chamber.

Acknowledgements

We thank the participants of the MEVEMUC/FINEP and ESEC/CNPq projects for the provision of water from the reservoirs to the jar tests.

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References

Farm Equipment Feed Storage Grain Feed Silos for Sale, F., BECKER, V. and ATTAYDE, J.L. Shallow lake restoration and water quality management by the combined effects of polyaluminium chloride addition and benthivorous fish removal: a field mesocosm experiment.Hydrobiologia, 2016, 778(1), 243-252. http://dx.doi.org/10.1007/s10750-015-2606-5. [Single Phase Frequency Inverter AC Motor Speed Controller 250000W]

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